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Acta Cryst. (2005). E61, m1863-m1865  [ doi:10.1107/S1600536805023676 ]

catena-Poly[[aquadipyridinezinc(II)]-[mu]-benzene-1,4-dioxyacetato]

X.-L. Hong, Y.-Z. Li and J.-F. Bai

Abstract: In the title compound, {[Zn(C10H8O6)(C5H5N)2(H2O)]}n, the coordination geometry around the ZnII atom is distorted square-pyramidal, and the Zn-OH2 bond at the apical position lies on a twofold axis. The bis-monodentate benzene-1,4-dioxyacetate ligand has inversion symmetry and acts as a bridge to link Zn atoms to form an infinite zigzag chain. Hydrogen bonds between the coordinated water molecule and the free carboxylate O atoms link the chains along the b axis into a two-dimensional layer.

Online 27 July 2005


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