Acta Cryst. (2005). E61, m1787-m1788  [ doi:10.1107/S1600536805025407 ]

catena-Poly[[aqua(cis-syn-cis-dicyclohexyl-18-crown-6)lead(II)]--thiocyanato-²N:S-[dithiocyanatopalladium(II)]--thiocyanato-²S:N]

Y.-M. Sun, F.-Y. Dong, J.-M. Dou, X.-K. Gao, D.-C. Li and D.-Q. Wang

Abstract: The title polymeric complex, [PbPd(NCS)₄(C₂₀H₃₆O₆)(H₂O)]_n or {[Pb(DC18C6-A)(H₂O)][Pd(SCN)₄]}_n (DC18C6-A = cis-syn-cis-dicyclohexyl-18-crown-6), has been synthesized by the reaction of dicyclohexyl-18-crown-6 with PdCl₂ and Pb(SCN)₂. The SCN groups bridge [Pb(DC18C6-A)(H₂O)]²⁺ complex cations and [Pd(SCN)₄]^2- complex anions to form infinite polymeric chains.

Online 17 August 2005

Copyright © International Union of Crystallography
IUCr Webmaster