Acta Cryst. (2005). E61, m1978-m1980  [ doi:10.1107/S1600536805028059 ]

Aqua(2,2'-diamino-4,4'-bi-1,3-thiazole-²N,N')(thiodiacetato-³O,S,O')cobalt(II) dihydrate

B.-X. Liu, J.-Y. Yu and D.-J. Xu

Abstract: The title Co^II complex, [Co(C₆H₆N₄S₂)(C₄H₄O₄S)(H₂O)]·2H₂O, assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate dianion (TDA) and a water molecule. The TDA dianion chelates to the Co^II atom with a facial configuration. Within the chelating DABT ligand, the two thiazole rings are twisted with respect to each other [dihedral angle = 12.04 (9)°].

Online 14 September 2005

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