Acta Cryst. (2005). E61, i216-i217  [ doi:10.1107/S1600536805029211 ]

Hydrazinium nitrate

M. S. Grigoriev, P. Moisy, C. Den Auwer and I. A. Charushnikova

Abstract: The monoprotonated hydrazinium cation in the title compound, N₂H₅⁺·NO₃^-, forms several types of hydrogen bonds. Stronger ones, in which the H atoms attached to the protonated N atom take part, link cations and anions into layers. Less strong hydrogen bonds, with participation of H atoms attached to the non-protonated N atom, link the layers into a three-dimensional structure. In addition to hydrogen bonds, short contacts of 2.8607 (10) Å have been found between O and N atoms of neighbouring nitrate anions. Such contacts can correspond to a weak intermolecular interaction similar to that in organic compounds containing nitro groups.

Online 17 September 2005

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