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Acta Cryst. (2005). E61, m2039-m2041 [ doi:10.1107/S1600536805029041 ]
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-3-hydroxypropanolato-di--methoxo-bis[tricarbonyltungsten(0)]Abstract: In the crystal structure of the title compound, (C8H20N)3[W2(CH3O)2(C3H7O2)(CO)6], obtained from a ligand substitution reaction of (Et4N)3[W2(OMe)3(CO)6], the trianion sits across a mirror plane such that one W(CO)3 group is unique and the two methoxy groups and all but the middle C atom of the 3-hydroxypropanolate ligand lie on the mirror plane. One and a half molecules of the tetraethylammonium cation are present to balance the charge in the asymmetric unit. The half molecule is situated with its N atom on a mirror plane and is disordered.
Online 21 September 2005
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