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Acta Cryst. (2005). E61, m2036-m2038  [ doi:10.1107/S1600536805029193 ]

Bis(acetato-[kappa]O)tetrakis(1H-pyrazole-[kappa]N1)nickel(II)

B. Papánková, I. Svoboda, H. Fuess and K. Sintálová

Abstract: The title mononuclear complex, [Ni(C2H3O2)2(C3H4N2)4], has been prepared and characterized by X-ray structure analysis. The molecule contains a six-coordinate NiII atom displaying distorted octahedral coordination geometry defined by the four pyrazole N atoms in the equatorial plane and two O atoms of the carboxylate groups in trans-apical positions. The Ni-N(pyrazole) distances range from 2.074 (2) to 2.097 (2) Å and the Ni-O(acetate) distances are 2.060 (2) and 2.072 (2) Å.

Online 17 September 2005


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