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Acta Cryst. (2005). E61, m1988-m1990 [ doi:10.1107/S1600536805028436 ]
![[mu]](/logos/entities/mu_rmgif.gif)
2-hydroxo-di-3-oxo-hexakis(1,4,7-triazacyclononane-![[kappa]](/logos/entities/kappa_rmgif.gif)
3N,N',N'')octairon(III) octabromide octahydrateAbstract: The title compound, [Fe8(3-O)2(2-OH)12(C6H12N3)6]Br8·8H2O, which crystallizes as an octahydrate, has a different arrangement of cations, anions and water molecules from the known nonahydrate [Wieghardt, Pohl, Jibril & Huttner (1984). Angew. Chem. Int. Ed. Engl. 23, 77-78.]. In the present phase, the cluster is generated by inversion symmetry and the bromide ions display substantial positional disorder.
Online 14 September 2005
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