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Acta Cryst. (2005). E61, m1946-m1947  [ doi:10.1107/S1600536805027698 ]

trans-Bis(isoquinoline-3-carboxylato-[kappa]2N,O)bis(methanol-[kappa]O)zinc(II)

N. Okabe, Y. Muranishi and O. Mamiko

Abstract: In the crystal structure of the title complex, [Zn(C10H6NO2)2(CH3OH)2], the Zn atom at a center of inversion has distorted octahedral coordination geometry and is bonded to two quinoline N atoms, two carboxylate O atoms and two methanol O atoms. Two isoquinoline-3-carboxylate ligands lie in trans positions, forming the equatorial plane, and the two methanol ligands occupy the axial positions. The complex molecules are linked together by O-H...O hydrogen bonds between the methanol ligands and neighboring carboxylate groups.

Online 14 September 2005


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