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Acta Cryst. (2005). E61, m2086-m2087  [ doi:10.1107/S1600536805029892 ]

Tetraaquabis[2,3-bis(5-methyl-1,3,4-thiadiazol-2-ylsulfanylmethyl)quinoxaline]nickel(II) bis(perchlorate) acetone disolvate

Y.-B. Xie, X.-J. Wang and D. Wang

Abstract: In the centrosymmetric, mononuclear title complex, [Ni(L)2(H2O)4](ClO4)2·2C3H6O [L = 2,3-bis(5-methyl-1,3,4-thiadiazol-2-ylsulfanylmethyl)quinoxaline, C16H14N6S4], the NiII center adopts a slightly distorted octahedral coordination geometry, formed by two N atoms from two distinct ligands and four O atoms from water molecules. Only one N atom of L takes part in coordinating to the NiII atom.

Online 28 September 2005


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