Acta Cryst. (2005). E61, m2097-m2099  [ doi:10.1107/S1600536805029880 ]

[Bis(diphenylphosphino)amine-²P,P'][1,3-bis(diphenylphosphino)propane-²P,P']platinum(II) dichloride dichloromethane solvate

S. Irisli and A. Sen

Abstract: The title complex, [Pt(C₂₄H₂₁NP₂)(C₂₇H₂₆P₂)]Cl₂·CH₂Cl₂ or [Pt(dppa)(dppp)]Cl₂·CH₂Cl₂, where dppa is bis(diphenylphosphino)amine and dppp is 1,3-bis(diphenylphosphino)propane, has two different chelate rings. The Pt^II atom has a distorted square-planar geometry. The six-membered chelate ring of dppp has a chair conformation. There is a hydrogen bond between the dppa N-H group and a Cl^- counter-ion.

Online 28 September 2005

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