Acta Cryst. (2005). E61, m2379-m2381  [ doi:10.1107/S1600536805033568 ]

Chloro[hydrotris(pyrazol-1-yl)borato]oxo(1H-pyrazole)vanadium(IV)

C. C. McLauchlan and K. J. McDonald

Abstract: The title compound, [V(C₉H₁₀BN₆)ClO(C₃H₄N₂)] or TpVOCl(pzH), exists in the solid state as discrete molecules with V^IV in a psuedo-octahedral coordination geometry. The complex has three pyrazole units of the Tp ligand bound to one `face' of the vanadium center and chloro, oxo and pyrazole ligands bound to the other face. Bond lengths and angles are typical of structurally characterized complexes of known complexes of vanadium with substituted Tp ligands.

Online 27 October 2005

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