Download citation
Download citation
link to html
The steroid ring B of the title compound, C22H32O, is in a half-chair conformation. The five-membered ring is in an inter­mediate form between the envelope and half-chair conformations.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805034641/bt6770sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805034641/bt6770Isup2.hkl
Contains datablock I

CCDC reference: 289664

Key indicators

  • Single-crystal X-ray study
  • T = 150 K
  • Mean [sigma](C-C)= 0.002 Å
  • R factor = 0.049
  • wR factor = 0.131
  • Data-to-parameter ratio = 11.5

checkCIF/PLATON results

No syntax errors found


No errors found in this datablock

Computing details top

Data collection: COLLECT (Hooft, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO; program(s) used to solve structure: SHELXS86 (Sheldrick, 1985); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: PLATON.

17-isopropyl-3-methoxy-13-methyl-7,8,9,11,12,13,14,15,16,17-decahydro- 6H-cyclopenta[a]phenanthrene top
Crystal data top
C22H32OF(000) = 688
Mr = 312.48Quoted _cell_measurement_* data items refer to the initial cell determination. The cell parameters as reported in _cell_* are based on the complete data set.
Monoclinic, P21/cDx = 1.168 Mg m3
Hall symbol: -P 2ybcMo Kα radiation, λ = 0.71073 Å
a = 21.260 (6) ÅCell parameters from 457 reflections
b = 6.1189 (10) Åθ = 2.0–20.0°
c = 13.662 (3) ŵ = 0.07 mm1
β = 90.35 (1)°T = 150 K
V = 1777.2 (7) Å3Plate, colourless
Z = 40.30 × 0.30 × 0.07 mm
Data collection top
Nonius KappaCCD area-detector
diffractometer
2308 reflections with I > 2σ(I)
Radiation source: Rotating AnodeRint = 0.097
Graphite monochromatorθmax = 26.0°, θmin = 1.9°
Detector resolution: 18.4 pixels mm-1h = 2626
φ scans and ω scans with κ offsetk = 77
37859 measured reflectionsl = 1616
3508 independent reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.049Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.131Only H-atom coordinates refined
S = 1.03 w = 1/[σ2(Fo2) + (0.0479P)2 + 0.13P]
where P = (Fo2 + 2Fc2)/3
3508 reflections(Δ/σ)max < 0.001
304 parametersΔρmax = 0.18 e Å3
0 restraintsΔρmin = 0.18 e Å3
Special details top

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F2 for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The observed criterion of F2 > σ(F2) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
O30.03148 (5)0.44570 (18)0.39750 (8)0.0387 (4)
C10.15613 (8)0.6826 (3)0.25448 (12)0.0349 (6)
C20.11231 (8)0.6494 (3)0.32635 (12)0.0355 (6)
C30.07350 (8)0.4669 (3)0.32188 (12)0.0328 (5)
C40.07901 (8)0.3217 (3)0.24508 (12)0.0332 (6)
C50.12333 (7)0.3567 (2)0.17145 (11)0.0312 (5)
C60.12619 (9)0.1939 (3)0.08869 (13)0.0379 (6)
C70.16213 (9)0.2740 (3)0.00066 (13)0.0402 (6)
C80.22270 (8)0.3832 (3)0.03118 (12)0.0354 (5)
C90.21009 (8)0.5834 (3)0.09453 (12)0.0331 (5)
C100.16321 (7)0.5383 (3)0.17555 (11)0.0311 (5)
C110.27142 (8)0.6908 (3)0.12807 (13)0.0382 (6)
C120.31603 (9)0.7407 (3)0.04348 (13)0.0361 (6)
C130.32896 (8)0.5406 (3)0.02089 (11)0.0324 (5)
C140.26444 (8)0.4495 (3)0.05349 (12)0.0346 (5)
C150.27932 (10)0.2851 (3)0.13368 (13)0.0426 (6)
C160.33746 (9)0.3820 (3)0.18388 (13)0.0399 (6)
C170.35897 (8)0.5827 (3)0.12255 (12)0.0347 (6)
C180.36832 (10)0.3723 (3)0.03650 (14)0.0423 (7)
C200.42979 (9)0.6228 (3)0.13130 (13)0.0404 (6)
C210.45357 (10)0.8113 (3)0.06817 (16)0.0463 (7)
C220.44717 (11)0.6682 (4)0.23811 (15)0.0500 (7)
C300.00588 (9)0.2510 (3)0.39983 (15)0.0411 (6)
H10.1816 (8)0.814 (3)0.2577 (12)0.0420*
H20.1078 (8)0.756 (3)0.3802 (12)0.0430*
H40.0524 (8)0.191 (3)0.2398 (12)0.0400*
H6A0.0834 (9)0.148 (3)0.0713 (12)0.0460*
H6B0.1468 (8)0.057 (3)0.1144 (12)0.0460*
H7A0.1705 (8)0.152 (3)0.0473 (13)0.0480*
H7B0.1356 (8)0.392 (3)0.0366 (13)0.0480*
H80.2470 (8)0.271 (3)0.0744 (12)0.0420*
H90.1892 (8)0.688 (3)0.0504 (12)0.0400*
H11A0.2917 (8)0.595 (3)0.1773 (13)0.0460*
H11B0.2617 (8)0.829 (3)0.1650 (13)0.0460*
H12A0.3545 (8)0.809 (3)0.0702 (12)0.0430*
H12B0.2955 (8)0.859 (3)0.0007 (12)0.0430*
H140.2422 (8)0.577 (3)0.0859 (11)0.0420*
H15A0.2445 (9)0.269 (3)0.1800 (14)0.0510*
H15B0.2888 (8)0.131 (3)0.1051 (13)0.0510*
H16A0.3300 (8)0.426 (3)0.2541 (13)0.0480*
H16B0.3733 (9)0.273 (3)0.1878 (13)0.0480*
H170.3365 (8)0.712 (3)0.1478 (12)0.0420*
H18A0.3770 (9)0.242 (4)0.0033 (14)0.0630*
H18B0.3452 (9)0.327 (3)0.0998 (16)0.0630*
H18C0.4115 (10)0.435 (3)0.0561 (14)0.0630*
H200.4508 (8)0.487 (3)0.1110 (12)0.0480*
H21A0.4302 (10)0.953 (3)0.0834 (15)0.0690*
H21B0.4991 (11)0.844 (3)0.0829 (14)0.0690*
H21C0.4485 (9)0.784 (3)0.0026 (17)0.0690*
H22A0.4332 (10)0.551 (4)0.2809 (16)0.0750*
H22B0.4944 (11)0.688 (3)0.2437 (15)0.0750*
H22C0.4248 (10)0.815 (4)0.2614 (15)0.0750*
H30A0.0359 (9)0.250 (3)0.3388 (15)0.0620*
H30B0.0319 (9)0.263 (3)0.4600 (15)0.0620*
H30C0.0217 (9)0.116 (3)0.4014 (14)0.0620*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
O30.0434 (7)0.0378 (7)0.0349 (7)0.0049 (5)0.0020 (5)0.0029 (5)
C10.0405 (10)0.0302 (9)0.0340 (10)0.0025 (8)0.0046 (8)0.0033 (8)
C20.0441 (10)0.0331 (10)0.0292 (9)0.0013 (8)0.0040 (8)0.0048 (8)
C30.0352 (9)0.0337 (9)0.0294 (9)0.0033 (8)0.0032 (7)0.0010 (7)
C40.0360 (10)0.0284 (9)0.0352 (10)0.0010 (8)0.0066 (8)0.0004 (8)
C50.0354 (9)0.0272 (9)0.0308 (9)0.0018 (7)0.0070 (7)0.0002 (7)
C60.0438 (11)0.0317 (10)0.0383 (10)0.0074 (8)0.0019 (8)0.0062 (8)
C70.0475 (11)0.0361 (10)0.0369 (10)0.0054 (9)0.0021 (9)0.0083 (8)
C80.0436 (10)0.0299 (9)0.0327 (9)0.0027 (8)0.0027 (8)0.0034 (8)
C90.0392 (10)0.0281 (9)0.0320 (9)0.0003 (7)0.0048 (8)0.0013 (7)
C100.0344 (9)0.0279 (9)0.0308 (9)0.0015 (7)0.0062 (7)0.0003 (7)
C110.0436 (11)0.0351 (10)0.0358 (10)0.0039 (8)0.0008 (8)0.0074 (8)
C120.0399 (10)0.0329 (10)0.0354 (10)0.0039 (8)0.0015 (8)0.0053 (8)
C130.0396 (10)0.0281 (9)0.0294 (9)0.0018 (7)0.0023 (7)0.0006 (7)
C140.0423 (10)0.0300 (9)0.0315 (9)0.0005 (8)0.0038 (8)0.0029 (7)
C150.0562 (12)0.0373 (11)0.0343 (10)0.0026 (9)0.0003 (9)0.0066 (8)
C160.0505 (12)0.0378 (10)0.0314 (10)0.0051 (9)0.0002 (8)0.0019 (8)
C170.0408 (10)0.0285 (9)0.0349 (10)0.0052 (8)0.0016 (8)0.0012 (8)
C180.0486 (12)0.0404 (11)0.0378 (11)0.0063 (9)0.0021 (9)0.0049 (9)
C200.0444 (11)0.0352 (10)0.0416 (11)0.0059 (8)0.0016 (8)0.0006 (8)
C210.0425 (12)0.0466 (12)0.0497 (12)0.0022 (9)0.0028 (9)0.0040 (10)
C220.0540 (13)0.0497 (13)0.0464 (12)0.0005 (11)0.0083 (10)0.0015 (10)
C300.0431 (11)0.0388 (11)0.0414 (11)0.0054 (9)0.0023 (9)0.0010 (9)
Geometric parameters (Å, º) top
O3—C31.376 (2)C6—H6A0.980 (19)
O3—C301.432 (2)C6—H6B1.008 (18)
C1—C21.373 (2)C7—H7A1.010 (18)
C1—C101.403 (2)C7—H7B1.047 (18)
C2—C31.390 (3)C8—H81.041 (18)
C3—C41.380 (2)C9—H90.983 (17)
C4—C51.399 (2)C11—H11A0.989 (18)
C5—C61.508 (2)C11—H11B1.007 (18)
C5—C101.399 (2)C12—H12A0.987 (17)
C6—C71.511 (3)C12—H12B1.037 (18)
C7—C81.507 (3)C14—H141.013 (18)
C8—C91.525 (3)C15—H15A0.976 (19)
C8—C141.518 (2)C15—H15B1.040 (18)
C9—C101.519 (2)C16—H16A1.008 (18)
C9—C111.528 (2)C16—H16B1.014 (19)
C11—C121.530 (3)C17—H170.986 (18)
C12—C131.533 (3)C18—H18A0.98 (2)
C13—C141.544 (2)C18—H18B1.04 (2)
C13—C171.554 (2)C18—H18C1.03 (2)
C13—C181.539 (3)C20—H200.983 (18)
C14—C151.522 (3)C21—H21A1.020 (19)
C15—C161.536 (3)C21—H21B1.01 (2)
C16—C171.554 (3)C21—H21C0.99 (2)
C17—C201.531 (3)C22—H22A0.97 (2)
C20—C211.525 (3)C22—H22B1.02 (2)
C20—C221.533 (3)C22—H22C1.06 (2)
C1—H10.970 (18)C30—H30A1.05 (2)
C2—H20.988 (17)C30—H30B1.00 (2)
C4—H40.982 (18)C30—H30C1.013 (19)
O3···O3i3.1817 (18)H8···H18B2.14 (3)
O3···C30i3.380 (2)H9···H6Bvi2.59 (3)
O3···C6ii3.397 (2)H9···H7B2.44 (3)
O3···C7ii3.385 (2)H9···H12B2.59 (2)
O3···H6Aiii2.773 (19)H9···H142.29 (2)
O3···H30Bi2.64 (2)H11A···C182.872 (18)
O3···H6Aii2.675 (17)H11A···H18B2.26 (3)
C3···C7ii3.411 (3)H11B···C12.714 (17)
C6···O3iv3.397 (2)H11B···H12.13 (2)
C7···O3iv3.385 (2)H11B···H16Avii2.36 (3)
C7···C3iv3.411 (3)H12A···C212.839 (17)
C12···C213.334 (3)H12A···H18C2.60 (3)
C18···C213.546 (3)H12A···H21C2.21 (3)
C21···C183.546 (3)H12B···H92.59 (2)
C21···C21v3.557 (3)H12B···H142.37 (2)
C21···C123.334 (3)H12B···H15Bvi2.20 (3)
C30···O3i3.380 (2)H12B···H172.37 (2)
C1···H30Aiii2.879 (19)H14···C113.065 (15)
C1···H11B2.714 (17)H14···H92.29 (2)
C1···H6Bvi2.991 (18)H14···H12B2.37 (2)
C2···H30Aiii2.84 (2)H14···H172.33 (2)
C2···H7Aii2.808 (18)H14···H1x2.58 (2)
C3···H30Aiii2.91 (2)H15A···C73.035 (19)
C3···H7Aii2.816 (18)H15A···H7A2.51 (3)
C4···H30A2.80 (2)H15B···C182.957 (18)
C4···H30Aiii3.001 (19)H15B···H12Bix2.20 (3)
C4···H30C2.768 (19)H15B···H18A2.43 (3)
C5···H30Aiii3.044 (19)H16A···C222.906 (18)
C5···H82.998 (17)H16A···H22A2.35 (3)
C7···H15A3.035 (19)H16A···H11Bx2.36 (3)
C8···H18B2.78 (2)H16A···H18Biv2.55 (3)
C10···H30Aiii3.006 (19)H16B···C222.966 (19)
C10···H7B3.086 (18)H16B···H18A2.53 (3)
C11···H12.719 (17)H16B···H202.35 (3)
C11···H143.065 (15)H16B···H22A2.48 (3)
C11···H18B2.752 (19)H17···H12B2.37 (2)
C12···H21C2.887 (19)H17···H142.33 (2)
C13···H21C2.961 (19)H17···H22C2.52 (3)
C15···H18A2.740 (19)H18A···C152.740 (19)
C15···H7A2.728 (17)H18A···C162.74 (2)
C16···H22A2.65 (2)H18A···H15B2.43 (3)
C16···H18A2.74 (2)H18A···H16B2.53 (3)
C18···H15B2.957 (18)H18A···H21Aix2.37 (3)
C18···H11A2.872 (18)H18B···C82.78 (2)
C18···H82.706 (17)H18B···C112.752 (19)
C18···H21C3.078 (19)H18B···H82.14 (3)
C18···H202.770 (17)H18B···H11A2.26 (3)
C20···H18C2.835 (19)H18B···H16Aii2.55 (3)
C21···H18C3.000 (19)H18C···C202.835 (19)
C21···H12A2.839 (17)H18C···C213.000 (19)
C22···H16A2.906 (18)H18C···H12A2.60 (3)
C22···H16B2.966 (19)H18C···H202.46 (3)
C30···H42.546 (17)H18C···H21C2.39 (3)
C30···H6Aiii2.963 (19)H18C···H21Bxi2.58 (3)
C30···H6Aii3.069 (18)H20···C182.770 (17)
H1···C112.719 (17)H20···H16B2.35 (3)
H1···H6Bvi2.56 (2)H20···H18C2.46 (3)
H1···H11B2.13 (2)H21A···H18Avi2.37 (3)
H1···H14vii2.58 (2)H21A···H22C2.58 (3)
H2···H7Bvii2.50 (3)H21B···H22B2.40 (3)
H4···C302.546 (17)H21B···H18Cxi2.58 (3)
H4···H6A2.41 (2)H21C···C122.887 (19)
H4···H30A2.35 (3)H21C···C132.961 (19)
H4···H30C2.35 (3)H21C···C183.078 (19)
H6A···H42.41 (2)H21C···H12A2.21 (3)
H6A···O3viii2.773 (19)H21C···H18C2.39 (3)
H6A···C30viii2.963 (19)H22A···C162.65 (2)
H6A···O3iv2.675 (17)H22A···H16A2.35 (3)
H6A···C30iv3.069 (18)H22A···H16B2.48 (3)
H6B···C1ix2.991 (18)H22B···H21B2.40 (3)
H6B···H1ix2.56 (2)H22C···H172.52 (3)
H6B···H82.56 (2)H22C···H21A2.58 (3)
H6B···H9ix2.59 (3)H30A···C42.80 (2)
H7A···C152.728 (17)H30A···H42.35 (3)
H7A···H15A2.51 (3)H30A···C1viii2.88 (2)
H7A···C2iv2.808 (18)H30A···C2viii2.84 (2)
H7A···C3iv2.816 (18)H30A···C3viii2.91 (2)
H7B···C103.086 (18)H30A···C4viii3.001 (19)
H7B···H92.44 (3)H30A···C5viii3.044 (19)
H7B···H2x2.50 (3)H30A···C10viii3.006 (19)
H7B···H30Civ2.56 (3)H30B···O3i2.64 (2)
H8···C52.998 (17)H30C···C42.768 (19)
H8···C182.706 (17)H30C···H42.35 (3)
H8···H6B2.56 (2)H30C···H7Bii2.56 (3)
C3—O3—C30117.24 (13)C14—C8—H8108.6 (9)
C2—C1—C10122.23 (16)C8—C9—H9104.8 (10)
C1—C2—C3119.53 (16)C10—C9—H9105.6 (10)
O3—C3—C2115.52 (15)C11—C9—H9106.6 (10)
O3—C3—C4124.65 (16)C9—C11—H11A108.5 (10)
C2—C3—C4119.84 (16)C9—C11—H11B109.5 (10)
C3—C4—C5120.58 (16)C12—C11—H11A111.2 (10)
C4—C5—C6117.92 (14)C12—C11—H11B109.9 (10)
C4—C5—C10120.24 (14)H11A—C11—H11B104.3 (15)
C6—C5—C10121.84 (14)C11—C12—H12A108.7 (10)
C5—C6—C7113.92 (15)C11—C12—H12B108.6 (9)
C6—C7—C8111.04 (15)C13—C12—H12A113.5 (10)
C7—C8—C9111.12 (14)C13—C12—H12B107.5 (10)
C7—C8—C14114.22 (14)H12A—C12—H12B105.4 (14)
C9—C8—C14108.88 (15)C8—C14—H14105.4 (9)
C8—C9—C10112.71 (15)C13—C14—H14105.1 (10)
C8—C9—C11111.29 (14)C15—C14—H14107.0 (9)
C10—C9—C11114.96 (14)C14—C15—H15A111.9 (11)
C1—C10—C5117.59 (14)C14—C15—H15B111.7 (10)
C1—C10—C9121.32 (15)C16—C15—H15A111.0 (11)
C5—C10—C9121.02 (14)C16—C15—H15B111.3 (10)
C9—C11—C12113.02 (14)H15A—C15—H15B107.3 (15)
C11—C12—C13112.83 (15)C15—C16—H16A113.9 (10)
C12—C13—C14106.96 (14)C15—C16—H16B112.1 (11)
C12—C13—C17117.16 (15)C17—C16—H16A110.3 (10)
C12—C13—C18109.94 (14)C17—C16—H16B109.2 (11)
C14—C13—C1799.85 (12)H16A—C16—H16B103.8 (14)
C14—C13—C18112.63 (15)C13—C17—H17104.2 (10)
C17—C13—C18109.97 (14)C16—C17—H17107.8 (10)
C8—C14—C13113.54 (13)C20—C17—H17108.6 (10)
C8—C14—C15119.81 (15)C13—C18—H18A111.4 (12)
C13—C14—C15104.96 (14)C13—C18—H18B110.2 (11)
C14—C15—C16103.75 (15)C13—C18—H18C111.4 (10)
C15—C16—C17107.41 (14)H18A—C18—H18B109.7 (16)
C13—C17—C16103.29 (14)H18A—C18—H18C106.0 (16)
C13—C17—C20120.39 (14)H18B—C18—H18C108.1 (15)
C16—C17—C20111.77 (14)C17—C20—H20106.7 (10)
C17—C20—C21113.58 (16)C21—C20—H20109.4 (10)
C17—C20—C22110.26 (16)C22—C20—H20108.1 (10)
C21—C20—C22108.69 (16)C20—C21—H21A111.6 (12)
C2—C1—H1118.1 (10)C20—C21—H21B110.6 (11)
C10—C1—H1119.6 (10)C20—C21—H21C112.8 (11)
C1—C2—H2120.3 (10)H21A—C21—H21B104.9 (16)
C3—C2—H2120.2 (10)H21A—C21—H21C106.7 (16)
C3—C4—H4121.9 (10)H21B—C21—H21C109.8 (16)
C5—C4—H4117.5 (10)C20—C22—H22A111.4 (14)
C5—C6—H6A109.2 (10)C20—C22—H22B109.7 (12)
C5—C6—H6B107.9 (10)C20—C22—H22C109.1 (11)
C7—C6—H6A111.9 (10)H22A—C22—H22B110.0 (17)
C7—C6—H6B109.0 (10)H22A—C22—H22C108.0 (18)
H6A—C6—H6B104.3 (15)H22B—C22—H22C108.5 (16)
C6—C7—H7A111.6 (10)O3—C30—H30A108.8 (10)
C6—C7—H7B109.7 (10)O3—C30—H30B105.5 (11)
C8—C7—H7A110.7 (10)O3—C30—H30C111.0 (11)
C8—C7—H7B106.6 (10)H30A—C30—H30B108.6 (16)
H7A—C7—H7B106.9 (14)H30A—C30—H30C111.2 (15)
C7—C8—H8106.6 (10)H30B—C30—H30C111.5 (15)
C9—C8—H8107.2 (10)
C30—O3—C3—C2175.14 (15)C10—C9—C11—C12177.85 (15)
C30—O3—C3—C44.6 (2)C8—C9—C10—C1165.14 (15)
C10—C1—C2—C30.3 (3)C8—C9—C10—C518.1 (2)
C2—C1—C10—C50.5 (2)C11—C9—C10—C136.2 (2)
C2—C1—C10—C9177.33 (16)C9—C11—C12—C1352.9 (2)
C1—C2—C3—O3179.35 (15)C11—C12—C13—C1453.77 (18)
C1—C2—C3—C40.5 (3)C11—C12—C13—C17164.71 (14)
C2—C3—C4—C50.1 (3)C11—C12—C13—C1868.82 (19)
O3—C3—C4—C5179.86 (15)C17—C13—C14—C8178.22 (15)
C3—C4—C5—C6178.98 (16)C18—C13—C14—C861.61 (19)
C3—C4—C5—C100.8 (2)C18—C13—C14—C1571.04 (17)
C4—C5—C6—C7164.55 (15)C17—C13—C14—C1545.57 (17)
C10—C5—C6—C715.3 (2)C12—C13—C14—C859.28 (19)
C6—C5—C10—C91.9 (2)C12—C13—C14—C15168.06 (14)
C6—C5—C10—C1178.80 (15)C14—C13—C17—C20165.13 (16)
C4—C5—C10—C11.0 (2)C18—C13—C17—C1678.95 (17)
C4—C5—C10—C9177.87 (15)C18—C13—C17—C2046.5 (2)
C5—C6—C7—C844.6 (2)C12—C13—C17—C2079.9 (2)
C6—C7—C8—C961.74 (19)C14—C13—C17—C1639.65 (16)
C6—C7—C8—C14174.61 (15)C12—C13—C17—C16154.60 (15)
C7—C8—C9—C1047.51 (19)C8—C14—C15—C16161.92 (15)
C7—C8—C14—C13174.42 (15)C13—C14—C15—C1632.92 (17)
C7—C8—C14—C1549.4 (2)C14—C15—C16—C177.08 (18)
C9—C8—C14—C1360.73 (19)C15—C16—C17—C20151.69 (15)
C9—C8—C14—C15174.24 (15)C15—C16—C17—C1320.84 (18)
C7—C8—C9—C11178.37 (14)C13—C17—C20—C2155.7 (2)
C14—C8—C9—C10174.16 (13)C13—C17—C20—C22177.91 (17)
C14—C8—C9—C1154.99 (18)C16—C17—C20—C21177.07 (15)
C11—C9—C10—C5147.09 (15)C16—C17—C20—C2260.7 (2)
C8—C9—C11—C1252.5 (2)
Symmetry codes: (i) x, y+1, z+1; (ii) x, y+1/2, z+1/2; (iii) x, y+1/2, z+1/2; (iv) x, y+1/2, z1/2; (v) x+1, y+2, z; (vi) x, y+1, z; (vii) x, y+3/2, z+1/2; (viii) x, y1/2, z+1/2; (ix) x, y1, z; (x) x, y+3/2, z1/2; (xi) x+1, y+1, z.
 

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds