Acta Cryst. (2005). E61, m2214-m2216  [ doi:10.1107/S160053680503120X ]

Di--methoxo-bis{[diacetyl monooxime (4-methoxybenzoyl)hydrazonato-³O,N,N']oxovanadium(V)}

Z.-P. Deng, S. Gao, L.-H. Huo and H. Zhao

Abstract: In the title centrosymmetric dimeric complex, [V₂(C₁₂H₁₃N₃O₃)₂(CH₃O)₂O₂], each V^V atom is six-coordinated by one oxo O atom, two N atoms and one O atom of the tridentate hydrazone ligand and two O atoms of two methoxo groups, leading to a distorted octahedral environment. Two V^V atoms are bridged by methoxo groups, resulting in a dimer, with a VV separation of 3.324 (3) Å.

Online 8 October 2005

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