{1,1′-Bis[bis­(5-methyl-2-fur­yl)phosphino]ferrocene-κ²P,P′}dichloro­platinum(II) dichloro­methane hemisolvate

The synthesis of the title compound, [FePtCl₂(C₁₅H₁₄O₂P)₂]·0.5CH₂Cl₂, has been achieved by reacting PtCl₂(PhCN)₂ with the 1,1′-bis­[bis­(5-methyl-2-furyl)phosphino]ferrocene chelating ligand. The environment at the Pt atom can be described as distorted square-planar, with two cis-Cl atoms and two cis-P atoms.

Key indicators

• Single-crystal X-ray study
• T = 110 K
• Mean [sigma](C-C) = 0.007 Å
• Disorder in solvent or counterion
• R factor = 0.033
• wR factor = 0.077
• Data-to-parameter ratio = 17.5

checkCIF/PLATON results

No syntax errors found





Alert level B
PLAT029_ALERT_3_B _diffrn_measured_fraction_theta_full Low .......       0.95

Alert level C
ABSTM02_ALERT_3_C  The ratio of expected to reported Tmax/Tmin(RR) is > 1.10
            Tmin and Tmax reported:      0.162     0.335
            Tmin and Tmax expected:      0.279     0.669
            RR =      1.158
            Please check that your absorption correction is appropriate.
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       0.50 Ratio
PLAT060_ALERT_3_C Ratio Tmax/Tmin (Exp-to-Rep) (too) Large .......       1.13
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       2.00
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for        C31
PLAT302_ALERT_4_C Anion/Solvent Disorder .........................      50.00 Perc.
PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety        C25
PLAT711_ALERT_1_C BOND    Unknown or Inconsistent Label ..........        CT1
                    FE     CT1
PLAT711_ALERT_1_C BOND    Unknown or Inconsistent Label ..........        CT2
                    FE     CT2
PLAT712_ALERT_1_C ANGLE   Unknown or Inconsistent Label ..........        CT1
                    CT1    FE     CT2

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      1.998
            Tmax scaled      0.669 Tmin scaled      0.324

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  13 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   6 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   0 ALERT type 2 Indicator that the structure model may be wrong or deficient
   4 ALERT type 3 Indicator that the structure quality may be low
   5 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: KappaCCD Server Software (Nonius, 1997); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Johnson & Burnett, 1996); software used to prepare material for publication: SHELXL97 and WinGX (Farrugia, 1999).

{1,1'-Bis[bis(5-methyl-2-furyl)phosphino]ferrocene- κ²P,P'}dichloroplatinum(II) dichloromethane hemisolvate

Crystal data

[FePtCl2(C15H14O2P)2]·0.5CH2Cl2	Z = 2
Mr = 878.77	F(000) = 858
Triclinic, P1	Dx = 1.877 Mg m^−3
a = 10.6903 (2) Å	Mo Kα radiation, λ = 0.71073 Å
b = 10.7487 (3) Å	Cell parameters from 3814 reflections
c = 14.9344 (4) Å	θ = 1–27.5°
α = 80.926 (1)°	µ = 5.36 mm^−1
β = 78.379 (1)°	T = 110 K
γ = 68.302 (1)°	Plate, orange
V = 1555.24 (7) Å^3	0.25 × 0.25 × 0.08 mm

Data collection

Nonius KappaCCD area-detector diffractometer	6868 independent reflections
Radiation source: fine-focus sealed tube	6137 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.034
φ scans (κ = 0) + additional ω scans	θmax = 27.6°, θmin = 2.4°
Absorption correction: multi-scan (Blessing, 1995)	h = −13→13
Tmin = 0.162, Tmax = 0.335	k = −13→13
8983 measured reflections	l = −19→19

Refinement

Refinement on F^2	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.033	Hydrogen site location: difference Fourier map
wR(F^2) = 0.077	H-atom parameters constrained
S = 1.04	w = 1/[σ^2(Fo^2) + (0.0367P)^2 + 4.3017P] where P = (Fo^2 + 2Fc^2)/3
6868 reflections	(Δ/σ)max = 0.001
393 parameters	Δρmax = 1.21 e Å^−3
3 restraints	Δρmin = −2.24 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Fe	0.66901 (6)	0.99426 (6)	0.73235 (4)	0.01098 (13)
Pt	0.773495 (16)	0.570653 (16)	0.733488 (11)	0.00973 (6)
Cl1	0.67129 (11)	0.43310 (10)	0.69361 (7)	0.0151 (2)
Cl2	0.88802 (12)	0.38708 (11)	0.83033 (8)	0.0191 (2)
P1	0.66854 (11)	0.73839 (11)	0.63459 (7)	0.0098 (2)
P2	0.87406 (11)	0.68294 (11)	0.79143 (8)	0.0109 (2)
O1	0.4097 (3)	0.7832 (3)	0.6072 (2)	0.0140 (6)
O2	0.7506 (3)	0.8469 (3)	0.4636 (2)	0.0157 (6)
O3	0.6872 (3)	0.6869 (3)	0.9412 (2)	0.0150 (6)
O4	1.1201 (3)	0.6713 (3)	0.8162 (2)	0.0149 (6)
C1	0.5759 (4)	0.8963 (4)	0.6814 (3)	0.0119 (8)
C2	0.5230 (4)	0.9094 (4)	0.7774 (3)	0.0121 (8)
H2	0.5258	0.8396	0.8233	0.015*
C3	0.4656 (4)	1.0494 (5)	0.7888 (3)	0.0157 (9)
H3	0.4251	1.0867	0.8442	0.019*
C4	0.4801 (4)	1.1225 (4)	0.7027 (3)	0.0159 (9)
H4	0.4509	1.2157	0.6919	0.019*
C5	0.5471 (4)	1.0296 (4)	0.6351 (3)	0.0149 (9)
H5	0.5683	1.0511	0.5725	0.018*
C6	0.8473 (4)	0.8601 (4)	0.7630 (3)	0.0131 (9)
C7	0.7936 (4)	0.9588 (4)	0.8282 (3)	0.0155 (9)
H7	0.7709	0.9424	0.8913	0.019*
C8	0.7811 (5)	1.0868 (5)	0.7789 (3)	0.0167 (9)
H8	0.7491	1.1686	0.8044	0.020*
C9	0.8260 (4)	1.0677 (5)	0.6848 (3)	0.0155 (9)
H9	0.8283	1.1350	0.6377	0.019*
C10	0.8673 (4)	0.9283 (4)	0.6739 (3)	0.0135 (9)
H10	0.9010	0.8887	0.6188	0.016*
C11	0.5456 (4)	0.7184 (4)	0.5768 (3)	0.0130 (9)
C12	0.5606 (5)	0.6508 (5)	0.5050 (3)	0.0164 (9)
H12	0.6424	0.5993	0.4723	0.020*
C13	0.4269 (5)	0.6729 (5)	0.4883 (3)	0.0170 (9)
H13	0.4045	0.6385	0.4428	0.020*
C14	0.3397 (5)	0.7532 (5)	0.5511 (3)	0.0168 (9)
C15	0.1884 (5)	0.8165 (5)	0.5687 (3)	0.0210 (10)
H15A	0.1625	0.9111	0.5502	0.032*
H15B	0.1562	0.8029	0.6330	0.032*
H15C	0.1490	0.7762	0.5343	0.032*
C16	0.7922 (4)	0.7542 (4)	0.5369 (3)	0.0133 (9)
C17	0.9231 (5)	0.6742 (5)	0.5137 (3)	0.0160 (9)
H17	0.9745	0.6035	0.5507	0.019*
C18	0.9677 (5)	0.7183 (5)	0.4221 (3)	0.0177 (9)
H18	1.0539	0.6829	0.3880	0.021*
C19	0.8606 (5)	0.8218 (5)	0.3941 (3)	0.0162 (9)
C20	0.8406 (5)	0.9063 (5)	0.3048 (3)	0.0235 (11)
H20A	0.9187	0.9323	0.2815	0.035*
H20B	0.7607	0.9852	0.3141	0.035*
H20C	0.8294	0.8555	0.2614	0.035*
C21	0.8227 (4)	0.6735 (4)	0.9131 (3)	0.0139 (9)
C22	0.8835 (5)	0.6608 (5)	0.9870 (3)	0.0193 (10)
H22	0.9736	0.6513	0.9867	0.023*
C23	0.7808 (5)	0.6648 (5)	1.0655 (3)	0.0216 (10)
H23	0.7918	0.6586	1.1264	0.026*
C24	0.6653 (5)	0.6793 (5)	1.0354 (3)	0.0170 (9)
C25	0.5239 (5)	0.6905 (5)	1.0796 (4)	0.0270 (11)
H25A	0.5176	0.6843	1.1450	0.041*
H25B	0.5021	0.6188	1.0631	0.041*
H25C	0.4609	0.7753	1.0589	0.041*
C26	1.0564 (5)	0.6125 (4)	0.7728 (3)	0.0144 (9)
C27	1.1504 (4)	0.5226 (5)	0.7170 (3)	0.0150 (9)
H27	1.1336	0.4699	0.6804	0.018*
C28	1.2812 (5)	0.5246 (5)	0.7257 (3)	0.0167 (9)
H28	1.3656	0.4740	0.6953	0.020*
C29	1.2575 (5)	0.6148 (5)	0.7866 (3)	0.0168 (9)
C30	1.3459 (5)	0.6631 (5)	0.8273 (4)	0.0248 (11)
H30A	1.4399	0.6135	0.8066	0.037*
H30B	1.3272	0.6501	0.8931	0.037*
H30C	1.3273	0.7570	0.8086	0.037*
C31	0.9556 (13)	1.0880 (12)	1.0023 (10)	0.052 (4)	0.50
H31A	0.9148	1.1548	0.9548	0.063*	0.50
H31B	0.9732	1.1348	1.0461	0.063*	0.50
Cl3	0.8386 (7)	1.0130 (7)	1.0580 (4)	0.0551 (16)	0.50
Cl4	1.1078 (8)	0.9800 (11)	0.9533 (6)	0.094 (3)	0.50

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Fe	0.0097 (3)	0.0098 (3)	0.0144 (3)	−0.0039 (2)	−0.0026 (2)	−0.0019 (2)
Pt	0.00994 (9)	0.00915 (9)	0.01106 (9)	−0.00362 (6)	−0.00293 (6)	−0.00135 (6)
Cl1	0.0162 (5)	0.0129 (5)	0.0201 (5)	−0.0073 (4)	−0.0063 (4)	−0.0023 (4)
Cl2	0.0254 (6)	0.0119 (5)	0.0222 (6)	−0.0066 (5)	−0.0133 (5)	0.0046 (4)
P1	0.0090 (5)	0.0100 (5)	0.0105 (5)	−0.0031 (4)	−0.0022 (4)	−0.0014 (4)
P2	0.0107 (5)	0.0107 (5)	0.0126 (5)	−0.0038 (4)	−0.0038 (4)	−0.0024 (4)
O1	0.0112 (15)	0.0171 (16)	0.0158 (16)	−0.0049 (13)	−0.0036 (12)	−0.0055 (13)
O2	0.0133 (16)	0.0163 (16)	0.0139 (16)	−0.0027 (13)	−0.0017 (12)	0.0025 (13)
O3	0.0119 (15)	0.0186 (16)	0.0134 (15)	−0.0034 (13)	−0.0031 (12)	−0.0019 (13)
O4	0.0093 (15)	0.0169 (16)	0.0219 (17)	−0.0061 (13)	−0.0037 (12)	−0.0061 (13)
C1	0.012 (2)	0.011 (2)	0.014 (2)	−0.0036 (17)	−0.0040 (16)	−0.0031 (17)
C2	0.008 (2)	0.010 (2)	0.018 (2)	−0.0040 (17)	−0.0003 (17)	−0.0031 (17)
C3	0.011 (2)	0.019 (2)	0.019 (2)	−0.0054 (19)	0.0003 (17)	−0.0089 (19)
C4	0.012 (2)	0.009 (2)	0.025 (2)	−0.0006 (18)	−0.0023 (18)	−0.0046 (18)
C5	0.012 (2)	0.014 (2)	0.021 (2)	−0.0036 (18)	−0.0060 (18)	−0.0022 (18)
C6	0.010 (2)	0.011 (2)	0.020 (2)	−0.0042 (17)	−0.0054 (17)	−0.0024 (17)
C7	0.014 (2)	0.017 (2)	0.017 (2)	−0.0059 (19)	−0.0056 (18)	−0.0024 (18)
C8	0.015 (2)	0.014 (2)	0.026 (3)	−0.0056 (19)	−0.0086 (19)	−0.0066 (19)
C9	0.012 (2)	0.016 (2)	0.021 (2)	−0.0084 (19)	−0.0039 (18)	0.0011 (18)
C10	0.008 (2)	0.015 (2)	0.018 (2)	−0.0021 (18)	−0.0025 (17)	−0.0041 (18)
C11	0.010 (2)	0.013 (2)	0.017 (2)	−0.0041 (18)	−0.0037 (17)	−0.0017 (17)
C12	0.016 (2)	0.015 (2)	0.018 (2)	−0.0039 (19)	−0.0035 (18)	−0.0048 (18)
C13	0.024 (2)	0.016 (2)	0.015 (2)	−0.008 (2)	−0.0093 (19)	−0.0005 (18)
C14	0.017 (2)	0.020 (2)	0.017 (2)	−0.011 (2)	−0.0073 (18)	0.0047 (19)
C15	0.013 (2)	0.027 (3)	0.025 (3)	−0.010 (2)	−0.0062 (19)	0.001 (2)
C16	0.014 (2)	0.015 (2)	0.012 (2)	−0.0066 (18)	−0.0019 (17)	−0.0028 (17)
C17	0.016 (2)	0.015 (2)	0.019 (2)	−0.0072 (19)	−0.0039 (18)	0.0001 (18)
C18	0.013 (2)	0.022 (2)	0.018 (2)	−0.0047 (19)	0.0017 (18)	−0.0072 (19)
C19	0.016 (2)	0.024 (2)	0.014 (2)	−0.014 (2)	0.0016 (17)	−0.0034 (18)
C20	0.022 (3)	0.029 (3)	0.020 (2)	−0.011 (2)	−0.004 (2)	0.005 (2)
C21	0.013 (2)	0.015 (2)	0.015 (2)	−0.0051 (18)	−0.0014 (17)	−0.0040 (17)
C22	0.016 (2)	0.021 (2)	0.022 (2)	−0.007 (2)	−0.0067 (19)	0.001 (2)
C23	0.029 (3)	0.026 (3)	0.011 (2)	−0.008 (2)	−0.0064 (19)	−0.0004 (19)
C24	0.020 (2)	0.016 (2)	0.012 (2)	−0.0040 (19)	−0.0015 (18)	0.0012 (18)
C25	0.026 (3)	0.028 (3)	0.022 (3)	−0.007 (2)	0.001 (2)	0.001 (2)
C26	0.016 (2)	0.013 (2)	0.017 (2)	−0.0067 (18)	−0.0039 (17)	−0.0020 (17)
C27	0.014 (2)	0.018 (2)	0.014 (2)	−0.0065 (19)	−0.0024 (17)	−0.0020 (18)
C28	0.009 (2)	0.015 (2)	0.023 (2)	−0.0035 (18)	−0.0005 (18)	0.0001 (18)
C29	0.011 (2)	0.019 (2)	0.020 (2)	−0.0046 (19)	−0.0038 (18)	−0.0002 (19)
C30	0.019 (3)	0.026 (3)	0.034 (3)	−0.013 (2)	−0.005 (2)	−0.006 (2)
C31	0.085 (12)	0.024 (6)	0.048 (8)	−0.009 (7)	−0.023 (8)	−0.008 (6)
Cl3	0.097 (5)	0.063 (3)	0.026 (2)	−0.054 (4)	−0.003 (3)	−0.0084 (18)
Cl4	0.085 (6)	0.129 (7)	0.055 (4)	−0.024 (4)	0.004 (4)	−0.020 (4)

Geometric parameters (Å, º)

Fe—Cg1	1.644 (5)	C8—H8	0.9300
Fe—Cg2	1.648 (5)	C9—C10	1.423 (6)
Fe—C1	2.003 (4)	C9—H9	0.9300
Fe—C2	2.039 (4)	C10—H10	0.9300
Fe—C3	2.063 (4)	C11—C12	1.339 (6)
Fe—C4	2.069 (5)	C12—C13	1.427 (6)
Fe—C5	2.044 (4)	C12—H12	0.9300
Fe—C6	2.008 (4)	C13—C14	1.343 (7)
Fe—C7	2.046 (4)	C13—H13	0.9300
Fe—C8	2.085 (4)	C14—C15	1.490 (6)
Fe—C9	2.066 (4)	C15—H15A	0.9600
Fe—C10	2.024 (4)	C15—H15B	0.9600
Pt—P1	2.2412 (11)	C15—H15C	0.9600
Pt—P2	2.2416 (10)	C16—C17	1.352 (6)
Pt—Cl1	2.3385 (10)	C17—C18	1.423 (6)
Pt—Cl2	2.3475 (11)	C17—H17	0.9300
P1—C1	1.790 (4)	C18—C19	1.352 (7)
P1—C16	1.793 (4)	C18—H18	0.9300
P1—C11	1.801 (4)	C19—C20	1.496 (6)
P2—C6	1.811 (4)	C20—H20A	0.9600
P2—C21	1.787 (4)	C20—H20B	0.9600
P2—C26	1.790 (5)	C20—H20C	0.9600
O1—C14	1.371 (5)	C21—C22	1.355 (6)
O1—C11	1.374 (5)	C22—C23	1.430 (7)
O2—C19	1.377 (5)	C22—H22	0.9300
O2—C16	1.384 (5)	C23—C24	1.345 (7)
O3—C24	1.374 (5)	C23—H23	0.9300
O3—C21	1.384 (5)	C24—C25	1.491 (7)
O4—C29	1.373 (5)	C25—H25A	0.9600
O4—C26	1.382 (5)	C25—H25B	0.9600
C1—C2	1.440 (6)	C25—H25C	0.9600
C1—C5	1.440 (6)	C26—C27	1.355 (6)
C2—C3	1.423 (6)	C27—C28	1.439 (6)
C2—H2	0.9300	C27—H27	0.9300
C3—C4	1.409 (6)	C28—C29	1.355 (7)
C3—H3	0.9300	C28—H28	0.9300
C4—C5	1.424 (6)	C29—C30	1.492 (6)
C4—H4	0.9300	C30—H30A	0.9600
C5—H5	0.9300	C30—H30B	0.9600
C6—C10	1.432 (6)	C30—H30C	0.9600
C6—C7	1.432 (6)	C31—Cl4	1.709 (13)
C7—C8	1.427 (6)	C31—Cl3	1.738 (13)
C7—H7	0.9300	C31—H31A	0.9700
C8—C9	1.413 (7)	C31—H31B	0.9700
Cg1—Fe—Cg2	177.4 (2)	P2—C6—Fe	122.4 (2)
C1—Fe—C6	107.74 (17)	C8—C7—C6	107.8 (4)
C1—Fe—C10	106.96 (17)	C8—C7—Fe	71.3 (3)
C6—Fe—C10	41.59 (18)	C6—C7—Fe	67.9 (2)
C1—Fe—C2	41.72 (17)	C8—C7—H7	126.1
C6—Fe—C2	108.02 (17)	C6—C7—H7	126.1
C10—Fe—C2	135.49 (17)	Fe—C7—H7	126.3
C1—Fe—C5	41.69 (17)	C9—C8—C7	108.1 (4)
C6—Fe—C5	138.13 (18)	C9—C8—Fe	69.4 (2)
C10—Fe—C5	109.86 (18)	C7—C8—Fe	68.3 (2)
C2—Fe—C5	69.48 (18)	C9—C8—H8	126.0
C1—Fe—C7	138.59 (18)	C7—C8—H8	126.0
C6—Fe—C7	41.35 (17)	Fe—C8—H8	127.9
C10—Fe—C7	69.29 (18)	C8—C9—C10	108.8 (4)
C2—Fe—C7	111.27 (18)	C8—C9—Fe	70.8 (2)
C5—Fe—C7	179.11 (19)	C10—C9—Fe	68.1 (2)
C1—Fe—C3	69.02 (17)	C8—C9—H9	125.6
C6—Fe—C3	137.63 (19)	C10—C9—H9	125.6
C10—Fe—C3	175.81 (17)	Fe—C9—H9	127.1
C2—Fe—C3	40.61 (17)	C9—C10—C6	107.6 (4)
C5—Fe—C3	68.10 (18)	C9—C10—Fe	71.2 (2)
C7—Fe—C3	112.77 (18)	C6—C10—Fe	68.6 (2)
C1—Fe—C9	136.43 (18)	C9—C10—H10	126.2
C6—Fe—C9	68.83 (18)	C6—C10—H10	126.2
C10—Fe—C9	40.71 (17)	Fe—C10—H10	125.5
C2—Fe—C9	176.19 (18)	C12—C11—O1	110.2 (4)
C5—Fe—C9	111.24 (18)	C12—C11—P1	131.7 (4)
C7—Fe—C9	67.98 (18)	O1—C11—P1	118.1 (3)
C3—Fe—C9	143.20 (18)	C11—C12—C13	106.8 (4)
C1—Fe—C4	69.08 (17)	C11—C12—H12	126.6
C6—Fe—C4	176.26 (17)	C13—C12—H12	126.6
C10—Fe—C4	140.58 (18)	C14—C13—C12	106.5 (4)
C2—Fe—C4	68.33 (17)	C14—C13—H13	126.8
C5—Fe—C4	40.51 (18)	C12—C13—H13	126.8
C7—Fe—C4	140.08 (18)	C13—C14—O1	110.3 (4)
C3—Fe—C4	39.87 (18)	C13—C14—C15	133.3 (4)
C9—Fe—C4	114.78 (18)	O1—C14—C15	116.4 (4)
C1—Fe—C8	175.20 (18)	C14—C15—H15A	109.5
C6—Fe—C8	68.68 (17)	C14—C15—H15B	109.5
C10—Fe—C8	68.25 (18)	H15A—C15—H15B	109.5
C2—Fe—C8	141.77 (18)	C14—C15—H15C	109.5
C5—Fe—C8	139.21 (18)	H15A—C15—H15C	109.5
C7—Fe—C8	40.41 (17)	H15B—C15—H15C	109.5
C3—Fe—C8	115.76 (18)	C17—C16—O2	109.5 (4)
C9—Fe—C8	39.80 (18)	C17—C16—P1	130.2 (4)
C4—Fe—C8	114.61 (18)	O2—C16—P1	119.4 (3)
P1—Pt—P2	97.35 (4)	C16—C17—C18	107.2 (4)
P1—Pt—Cl1	90.44 (4)	C16—C17—H17	126.4
P2—Pt—Cl1	171.47 (4)	C18—C17—H17	126.4
P1—Pt—Cl2	176.78 (4)	C19—C18—C17	106.7 (4)
P2—Pt—Cl2	84.76 (4)	C19—C18—H18	126.6
Cl1—Pt—Cl2	87.61 (4)	C17—C18—H18	126.6
C1—P1—C16	111.4 (2)	C18—C19—O2	110.1 (4)
C1—P1—C11	102.2 (2)	C18—C19—C20	132.7 (4)
C16—P1—C11	99.2 (2)	O2—C19—C20	117.2 (4)
C1—P1—Pt	115.30 (15)	C19—C20—H20A	109.5
C16—P1—Pt	108.43 (15)	C19—C20—H20B	109.5
C11—P1—Pt	119.15 (15)	H20A—C20—H20B	109.5
C21—P2—C26	106.1 (2)	C19—C20—H20C	109.5
C21—P2—C6	102.3 (2)	H20A—C20—H20C	109.5
C26—P2—C6	100.9 (2)	H20B—C20—H20C	109.5
C21—P2—Pt	107.49 (14)	C22—C21—O3	110.0 (4)
C26—P2—Pt	113.99 (15)	C22—C21—P2	135.5 (4)
C6—P2—Pt	124.35 (14)	O3—C21—P2	114.5 (3)
C14—O1—C11	106.2 (3)	C21—C22—C23	106.0 (4)
C19—O2—C16	106.5 (3)	C21—C22—H22	127.0
C24—O3—C21	106.7 (3)	C23—C22—H22	127.0
C29—O4—C26	106.8 (3)	C24—C23—C22	107.7 (4)
C2—C1—C5	107.8 (4)	C24—C23—H23	126.1
C2—C1—P1	123.7 (3)	C22—C23—H23	126.1
C5—C1—P1	128.4 (3)	C23—C24—O3	109.6 (4)
C2—C1—Fe	70.5 (2)	C23—C24—C25	135.4 (4)
C5—C1—Fe	70.7 (2)	O3—C24—C25	115.0 (4)
P1—C1—Fe	121.6 (2)	C24—C25—H25A	109.5
C3—C2—C1	107.2 (4)	C24—C25—H25B	109.5
C3—C2—Fe	70.6 (2)	H25A—C25—H25B	109.5
C1—C2—Fe	67.8 (2)	C24—C25—H25C	109.5
C3—C2—H2	126.4	H25A—C25—H25C	109.5
C1—C2—H2	126.4	H25B—C25—H25C	109.5
Fe—C2—H2	126.7	C27—C26—O4	110.0 (4)
C4—C3—C2	109.1 (4)	C27—C26—P2	134.6 (3)
C4—C3—Fe	70.3 (3)	O4—C26—P2	115.0 (3)
C2—C3—Fe	68.8 (2)	C26—C27—C28	106.5 (4)
C4—C3—H3	125.5	C26—C27—H27	126.7
C2—C3—H3	125.5	C28—C27—H27	126.7
Fe—C3—H3	127.0	C29—C28—C27	106.6 (4)
C3—C4—C5	108.5 (4)	C29—C28—H28	126.7
C3—C4—Fe	69.8 (3)	C27—C28—H28	126.7
C5—C4—Fe	68.8 (2)	C28—C29—O4	110.2 (4)
C3—C4—H4	125.7	C28—C29—C30	134.5 (4)
C5—C4—H4	125.7	O4—C29—C30	115.3 (4)
Fe—C4—H4	127.2	C29—C30—H30A	109.5
C4—C5—C1	107.5 (4)	C29—C30—H30B	109.5
C4—C5—Fe	70.7 (3)	H30A—C30—H30B	109.5
C1—C5—Fe	67.6 (2)	C29—C30—H30C	109.5
C4—C5—H5	126.3	H30A—C30—H30C	109.5
C1—C5—H5	126.3	H30B—C30—H30C	109.5
Fe—C5—H5	126.9	Cl4—C31—Cl3	115.1 (8)
C10—C6—C7	107.8 (4)	Cl4—C31—H31A	108.5
C10—C6—P2	127.6 (3)	Cl3—C31—H31A	108.5
C7—C6—P2	124.5 (3)	Cl4—C31—H31B	108.5
C10—C6—Fe	69.8 (2)	Cl3—C31—H31B	108.5
C7—C6—Fe	70.8 (2)	H31A—C31—H31B	107.5