Acta Cryst. (2005). E61, m2369-m2370  [ doi:10.1107/S1600536805033611 ]

-(Furan-2-carbaldehyde azine)-1²O,N:2²N',O'-bis[(furan-2-carbaldehyde azine-²N,O)silver(I)] bis(hexafluorophosphate): an unusual complex containing two metal atoms and three ligands

L. Wang, Y.-B. Dong, J.-P. Ma and R.-Q. Huang

Abstract: The title complex, [Ag₂(C₁₀H₈N₂O₂)₃](PF₆)₂, contains two silver cations and three molecules of the new Schiff base ligand furan-2-carbaldehyde azine, accompanied by two charge-balancing PF₆^- anions. There is a centre of inversion at the mid-point of the N-N bond of the central ligand. The Ag atom adopts a `see-saw' coordination, with two short Ag-N bonds and two long Ag-O bonds.

Online 22 October 2005

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