Acta Cryst. (2005). E61, m2421-m2423  [ doi:10.1107/S1600536805034136 ]

Chloro(1-isopropylidene-4-methyl-3-thiosemicarbazidato-²N³,S)dimethyltin(IV)

A. T. Swesi, Y. Farina and B. M. Yamin

Abstract: In the title compound, [Sn(CH₃)₂(C₅H₁₀N₃S)Cl], the 1-isopropylidene-4-methyl-3-thiosemicarbazidate ligand has a Z configuration and is chelated to the Sn atom through the S and hydrazinic N atoms in a distorted trigonal-bipyramidal pentacoordination environment. The molecular structure is stabilized by intramolecular C-HN and intermolecular N-HS hydrogen bonds. The latter link the molecules into dimers.

Online 31 October 2005

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