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Acta Cryst. (2005). E61, m2286-m2288  [ doi:10.1107/S1600536805032204 ]

A one-dimensional helical chain polymer: catena-poly[[[bis(1H-imidazole)zinc(II)]-[mu]-3-carboxylatophenoxyacetato] trihydrate]

X.-F. Zhang, S. Gao, L.-H. Huo and J.-G. Zhao

Abstract: In the title one-dimensional polymer, {[Zn(3-CPOA)(C3H4N2)2]·3H2O}n (3-CPOA2- is the 3-carboxylatophenoxyacetate dianion, C9H6O5), the Zn atom shows tetrahedral coordination, as it is linked to two N atoms from two imidazole molecules and two carboxylate O atoms from two different 3-CPOA2- groups. Adjacent Zn atoms are linked by 3-CPOA2- ligands into a helical chain. The chains are linked into a three-dimensional network by hydrogen bonds.

Online 15 October 2005


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