The title compound, [Pd2(C4H3OSe)4(C18H15P)2], crystallizes as a centrocymmetric furan-2-selenolate-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with bridging Pd—Se distances of 2.4568 (8) and 2.4729 (8) Å, and a terminal Pd—Se distance of 2.4623 (8) Å. Terminal selenolate ligands are in trans positions with respect to each other.
Supporting information
CCDC reference: 289875
Key indicators
- Single-crystal X-ray study
- T = 120 K
- Mean (C-C) = 0.009 Å
- R factor = 0.042
- wR factor = 0.102
- Data-to-parameter ratio = 16.2
checkCIF/PLATON results
No syntax errors found
Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ?
PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.36 Ratio
| Author Response: High Ueq(max)/Ueq(min) ratio is observed because
of the positional disorder in the furyl ring.
|
PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Pd1 - Se2 .. 7.24 su
| Author Response: This is due to the empirical multi-scan absorption
correction.
|
PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C13
| Author Response: There is positional disorder in the furyl ring
|
PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C12
| Author Response: There is positional disorder in the furyl ring
|
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 9
0 ALERT level A = In general: serious problem
0 ALERT level B = Potentially serious problem
6 ALERT level C = Check and explain
0 ALERT level G = General alerts; check
1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
4 ALERT type 2 Indicator that the structure model may be wrong or deficient
1 ALERT type 3 Indicator that the structure quality may be low
0 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: COLLECT (Nonius, 1998); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXL97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: DIAMOND (Brandenburg & Berndt, 1999); software used to prepare material for publication: WinGX (Farrugia, 1999).
Di-µ-furan-2-selenolato-bis[(furan-2-selenolato)(triphenylphosphine)palladium]
top
Crystal data top
[Pd2(C4H3OSe)4(C18H15P)2] | F(000) = 1288 |
Mr = 1321.44 | Dx = 1.795 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 3924 reflections |
a = 13.045 (3) Å | θ = 3.1–26.0° |
b = 16.394 (3) Å | µ = 3.82 mm−1 |
c = 12.233 (2) Å | T = 120 K |
β = 110.85 (3)° | Plate, orange |
V = 2444.8 (10) Å3 | 0.15 × 0.10 × 0.08 mm |
Z = 2 | |
Data collection top
Bruker–Nonius KappaCCD diffractometer | 4701 independent reflections |
Radiation source: fine-focus sealed tube | 3924 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.050 |
φ scans, and ω scans with κ offsets | θmax = 26.0°, θmin = 3.1° |
Absorption correction: multi-scan (SHELXTL; Bruker, 2001) | h = −16→15 |
Tmin = 0.638, Tmax = 0.737 | k = −19→20 |
17303 measured reflections | l = −15→15 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.042 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.102 | H-atom parameters constrained |
S = 1.04 | w = 1/[σ2(Fo2) + (0.0378P)2 + 10.5236P] where P = (Fo2 + 2Fc2)/3 |
4701 reflections | (Δ/σ)max < 0.001 |
290 parameters | Δρmax = 1.75 e Å−3 |
0 restraints | Δρmin = −0.93 e Å−3 |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
Pd1 | 0.37476 (3) | 0.00294 (2) | 0.36834 (3) | 0.02079 (11) | |
Se2 | 0.45340 (4) | 0.07504 (3) | 0.55752 (4) | 0.02376 (13) | |
Se1 | 0.21198 (4) | 0.09146 (3) | 0.29532 (4) | 0.02807 (14) | |
P1 | 0.29905 (10) | −0.07365 (7) | 0.20388 (10) | 0.0217 (3) | |
C11 | 0.1765 (4) | 0.1128 (3) | 0.4285 (5) | 0.0318 (11) | |
C12 | 0.1147 (4) | 0.0644 (4) | 0.4719 (5) | 0.0349 (12) | |
H12 | 0.0846 | 0.0127 | 0.4427 | 0.042* | |
C13 | 0.1045 (7) | 0.1051 (7) | 0.5662 (7) | 0.073 (3) | |
H13 | 0.0656 | 0.0863 | 0.6139 | 0.087* | |
C14 | 0.1582 (7) | 0.1746 (7) | 0.5785 (6) | 0.079 (3) | |
H14 | 0.1640 | 0.2139 | 0.6374 | 0.095* | |
O1 | 0.2066 (4) | 0.1824 (3) | 0.4911 (5) | 0.0640 (14) | |
C111 | 0.2031 (4) | −0.1458 (3) | 0.2282 (4) | 0.0237 (10) | |
C112 | 0.1771 (4) | −0.1401 (3) | 0.3291 (4) | 0.0274 (11) | |
H112 | 0.2070 | −0.0971 | 0.3832 | 0.033* | |
C113 | 0.1081 (4) | −0.1967 (3) | 0.3507 (5) | 0.0354 (12) | |
H113 | 0.0915 | −0.1925 | 0.4201 | 0.043* | |
C114 | 0.0629 (4) | −0.2593 (3) | 0.2727 (5) | 0.0368 (13) | |
H114 | 0.0157 | −0.2980 | 0.2884 | 0.044* | |
C115 | 0.0868 (5) | −0.2650 (4) | 0.1716 (5) | 0.0414 (14) | |
H115 | 0.0548 | −0.3073 | 0.1170 | 0.050* | |
C116 | 0.1569 (4) | −0.2096 (3) | 0.1494 (5) | 0.0329 (12) | |
H116 | 0.1739 | −0.2147 | 0.0804 | 0.040* | |
C121 | 0.3893 (4) | −0.1391 (3) | 0.1582 (4) | 0.0269 (10) | |
C122 | 0.4389 (4) | −0.2060 (3) | 0.2272 (5) | 0.0338 (12) | |
H122 | 0.4217 | −0.2190 | 0.2945 | 0.041* | |
C123 | 0.5133 (5) | −0.2537 (3) | 0.1982 (6) | 0.0418 (14) | |
H123 | 0.5471 | −0.2988 | 0.2462 | 0.050* | |
C124 | 0.5388 (5) | −0.2367 (4) | 0.1010 (6) | 0.0477 (16) | |
H124 | 0.5895 | −0.2700 | 0.0817 | 0.057* | |
C125 | 0.4900 (5) | −0.1705 (4) | 0.0308 (5) | 0.0431 (14) | |
H125 | 0.5073 | −0.1584 | −0.0366 | 0.052* | |
C126 | 0.4153 (4) | −0.1216 (3) | 0.0596 (5) | 0.0332 (12) | |
H126 | 0.3822 | −0.0762 | 0.0118 | 0.040* | |
C131 | 0.2271 (4) | −0.0136 (3) | 0.0740 (4) | 0.0269 (10) | |
C132 | 0.1266 (4) | −0.0355 (4) | −0.0086 (5) | 0.0345 (12) | |
H132 | 0.0921 | −0.0850 | −0.0006 | 0.041* | |
C133 | 0.0769 (5) | 0.0159 (4) | −0.1033 (5) | 0.0483 (16) | |
H133 | 0.0077 | 0.0014 | −0.1594 | 0.058* | |
C134 | 0.1261 (6) | 0.0868 (4) | −0.1168 (6) | 0.0506 (17) | |
H134 | 0.0905 | 0.1216 | −0.1813 | 0.061* | |
C135 | 0.2271 (6) | 0.1078 (4) | −0.0371 (6) | 0.0494 (16) | |
H135 | 0.2625 | 0.1563 | −0.0474 | 0.059* | |
C136 | 0.2773 (5) | 0.0576 (3) | 0.0590 (5) | 0.0391 (13) | |
H136 | 0.3466 | 0.0723 | 0.1146 | 0.047* | |
C21 | 0.3819 (4) | 0.0153 (3) | 0.6427 (5) | 0.0311 (11) | |
C22 | 0.3483 (5) | 0.0328 (4) | 0.7298 (5) | 0.0455 (15) | |
H22 | 0.3567 | 0.0837 | 0.7691 | 0.055* | |
C23 | 0.2966 (6) | −0.0392 (5) | 0.7546 (6) | 0.0547 (17) | |
H23 | 0.2635 | −0.0446 | 0.8120 | 0.066* | |
C24 | 0.3044 (6) | −0.0958 (4) | 0.6819 (7) | 0.061 (2) | |
H24 | 0.2778 | −0.1500 | 0.6793 | 0.073* | |
O2 | 0.3563 (4) | −0.0660 (2) | 0.6098 (4) | 0.0459 (10) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
Pd1 | 0.01984 (19) | 0.02059 (19) | 0.01961 (19) | 0.00004 (13) | 0.00418 (15) | −0.00194 (13) |
Se2 | 0.0230 (2) | 0.0220 (2) | 0.0226 (3) | 0.00181 (18) | 0.0036 (2) | −0.00239 (18) |
Se1 | 0.0258 (3) | 0.0282 (3) | 0.0277 (3) | 0.00639 (19) | 0.0065 (2) | 0.0014 (2) |
P1 | 0.0198 (6) | 0.0231 (6) | 0.0195 (6) | −0.0013 (5) | 0.0038 (5) | −0.0020 (5) |
C11 | 0.027 (3) | 0.029 (3) | 0.038 (3) | 0.009 (2) | 0.011 (2) | 0.001 (2) |
C12 | 0.031 (3) | 0.041 (3) | 0.038 (3) | 0.008 (2) | 0.019 (2) | 0.009 (2) |
C13 | 0.055 (5) | 0.117 (8) | 0.055 (5) | 0.040 (5) | 0.030 (4) | 0.028 (5) |
C14 | 0.068 (5) | 0.116 (8) | 0.042 (4) | 0.058 (5) | 0.003 (4) | −0.026 (5) |
O1 | 0.054 (3) | 0.056 (3) | 0.075 (4) | 0.010 (2) | 0.015 (3) | −0.021 (3) |
C111 | 0.022 (2) | 0.025 (2) | 0.020 (2) | 0.0014 (19) | 0.0022 (19) | 0.0016 (19) |
C112 | 0.028 (3) | 0.026 (3) | 0.025 (3) | 0.003 (2) | 0.006 (2) | 0.000 (2) |
C113 | 0.033 (3) | 0.039 (3) | 0.036 (3) | 0.008 (2) | 0.014 (2) | 0.011 (2) |
C114 | 0.029 (3) | 0.031 (3) | 0.053 (4) | 0.001 (2) | 0.017 (3) | 0.009 (3) |
C115 | 0.038 (3) | 0.035 (3) | 0.048 (4) | −0.016 (2) | 0.010 (3) | −0.010 (3) |
C116 | 0.035 (3) | 0.034 (3) | 0.029 (3) | −0.008 (2) | 0.010 (2) | −0.008 (2) |
C121 | 0.023 (2) | 0.025 (2) | 0.026 (3) | −0.0018 (19) | 0.001 (2) | −0.010 (2) |
C122 | 0.037 (3) | 0.025 (3) | 0.038 (3) | −0.003 (2) | 0.011 (2) | −0.007 (2) |
C123 | 0.040 (3) | 0.027 (3) | 0.053 (4) | 0.007 (2) | 0.010 (3) | −0.003 (3) |
C124 | 0.037 (3) | 0.041 (3) | 0.064 (4) | 0.004 (3) | 0.017 (3) | −0.023 (3) |
C125 | 0.039 (3) | 0.056 (4) | 0.039 (3) | 0.001 (3) | 0.020 (3) | −0.011 (3) |
C126 | 0.030 (3) | 0.039 (3) | 0.029 (3) | 0.000 (2) | 0.008 (2) | −0.005 (2) |
C131 | 0.028 (3) | 0.032 (3) | 0.022 (2) | 0.002 (2) | 0.011 (2) | 0.000 (2) |
C132 | 0.029 (3) | 0.046 (3) | 0.030 (3) | 0.002 (2) | 0.012 (2) | 0.001 (2) |
C133 | 0.031 (3) | 0.076 (5) | 0.031 (3) | 0.015 (3) | 0.001 (3) | 0.012 (3) |
C134 | 0.053 (4) | 0.063 (4) | 0.037 (3) | 0.027 (3) | 0.018 (3) | 0.024 (3) |
C135 | 0.062 (4) | 0.043 (4) | 0.043 (4) | 0.001 (3) | 0.019 (3) | 0.016 (3) |
C136 | 0.041 (3) | 0.037 (3) | 0.037 (3) | −0.004 (3) | 0.011 (3) | 0.006 (2) |
C21 | 0.024 (2) | 0.041 (3) | 0.025 (3) | 0.001 (2) | 0.005 (2) | 0.004 (2) |
C22 | 0.044 (3) | 0.050 (4) | 0.042 (4) | 0.009 (3) | 0.015 (3) | −0.008 (3) |
C23 | 0.056 (4) | 0.072 (5) | 0.037 (3) | 0.008 (4) | 0.020 (3) | 0.014 (3) |
C24 | 0.066 (5) | 0.043 (4) | 0.092 (6) | 0.002 (3) | 0.049 (4) | 0.017 (4) |
O2 | 0.057 (3) | 0.032 (2) | 0.061 (3) | −0.0012 (19) | 0.035 (2) | 0.0005 (19) |
Geometric parameters (Å, º) top
Pd1—P1 | 2.2771 (13) | C121—C122 | 1.395 (7) |
Pd1—Se2i | 2.4568 (8) | C122—C123 | 1.387 (8) |
Pd1—Se1 | 2.4623 (8) | C122—H122 | 0.9500 |
Pd1—Se2 | 2.4729 (8) | C123—C124 | 1.372 (9) |
Se2—C21 | 1.900 (5) | C123—H123 | 0.9500 |
Se2—Pd1i | 2.4568 (8) | C124—C125 | 1.389 (9) |
Se1—C11 | 1.877 (5) | C124—H124 | 0.9500 |
P1—C131 | 1.820 (5) | C125—C126 | 1.400 (8) |
P1—C111 | 1.822 (5) | C125—H125 | 0.9500 |
P1—C121 | 1.822 (5) | C126—H126 | 0.9500 |
C11—O1 | 1.352 (7) | C131—C136 | 1.381 (7) |
C11—C12 | 1.366 (7) | C131—C132 | 1.388 (7) |
C12—C13 | 1.380 (10) | C132—C133 | 1.392 (8) |
C12—H12 | 0.9500 | C132—H132 | 0.9500 |
C13—C14 | 1.318 (13) | C133—C134 | 1.366 (9) |
C13—H13 | 0.9500 | C133—H133 | 0.9500 |
C14—O1 | 1.428 (10) | C134—C135 | 1.376 (10) |
C14—H14 | 0.9500 | C134—H134 | 0.9500 |
C111—C112 | 1.395 (7) | C135—C136 | 1.393 (8) |
C111—C116 | 1.404 (7) | C135—H135 | 0.9500 |
C112—C113 | 1.383 (7) | C136—H136 | 0.9500 |
C112—H112 | 0.9500 | C21—C22 | 1.319 (8) |
C113—C114 | 1.382 (8) | C21—O2 | 1.397 (7) |
C113—H113 | 0.9500 | C22—C23 | 1.445 (10) |
C114—C115 | 1.382 (8) | C22—H22 | 0.9500 |
C114—H114 | 0.9500 | C23—C24 | 1.315 (10) |
C115—C116 | 1.383 (7) | C23—H23 | 0.9500 |
C115—H115 | 0.9500 | C24—O2 | 1.379 (8) |
C116—H116 | 0.9500 | C24—H24 | 0.9500 |
C121—C126 | 1.394 (7) | | |
| | | |
P1—Pd1—Se2i | 95.23 (4) | C126—C121—P1 | 121.8 (4) |
P1—Pd1—Se1 | 87.57 (4) | C122—C121—P1 | 119.2 (4) |
Se2i—Pd1—Se1 | 175.18 (2) | C123—C122—C121 | 120.3 (5) |
P1—Pd1—Se2 | 174.50 (4) | C123—C122—H122 | 119.9 |
Se2i—Pd1—Se2 | 83.28 (3) | C121—C122—H122 | 119.9 |
Se1—Pd1—Se2 | 94.29 (3) | C124—C123—C122 | 121.0 (5) |
C21—Se2—Pd1i | 95.21 (16) | C124—C123—H123 | 119.5 |
C21—Se2—Pd1 | 98.37 (16) | C122—C123—H123 | 119.5 |
Pd1i—Se2—Pd1 | 96.72 (3) | C123—C124—C125 | 119.7 (5) |
C11—Se1—Pd1 | 104.01 (16) | C123—C124—H124 | 120.2 |
C131—P1—C111 | 108.8 (2) | C125—C124—H124 | 120.2 |
C131—P1—C121 | 103.9 (2) | C124—C125—C126 | 119.9 (6) |
C111—P1—C121 | 102.9 (2) | C124—C125—H125 | 120.0 |
C131—P1—Pd1 | 113.55 (17) | C126—C125—H125 | 120.0 |
C111—P1—Pd1 | 108.73 (16) | C121—C126—C125 | 120.3 (5) |
C121—P1—Pd1 | 118.14 (16) | C121—C126—H126 | 119.8 |
O1—C11—C12 | 111.2 (5) | C125—C126—H126 | 119.8 |
O1—C11—Se1 | 122.5 (4) | C136—C131—C132 | 119.4 (5) |
C12—C11—Se1 | 126.2 (4) | C136—C131—P1 | 116.8 (4) |
C11—C12—C13 | 106.9 (6) | C132—C131—P1 | 123.8 (4) |
C11—C12—H12 | 126.5 | C131—C132—C133 | 119.3 (6) |
C13—C12—H12 | 126.5 | C131—C132—H132 | 120.4 |
C14—C13—C12 | 107.9 (7) | C133—C132—H132 | 120.4 |
C14—C13—H13 | 126.1 | C134—C133—C132 | 121.1 (6) |
C12—C13—H13 | 126.1 | C134—C133—H133 | 119.5 |
C13—C14—O1 | 110.6 (6) | C132—C133—H133 | 119.5 |
C13—C14—H14 | 124.7 | C133—C134—C135 | 120.0 (6) |
O1—C14—H14 | 124.7 | C133—C134—H134 | 120.0 |
C11—O1—C14 | 103.4 (6) | C135—C134—H134 | 120.0 |
C112—C111—C116 | 118.5 (4) | C134—C135—C136 | 119.6 (6) |
C112—C111—P1 | 119.9 (4) | C134—C135—H135 | 120.2 |
C116—C111—P1 | 121.6 (4) | C136—C135—H135 | 120.2 |
C113—C112—C111 | 120.3 (5) | C131—C136—C135 | 120.6 (6) |
C113—C112—H112 | 119.9 | C131—C136—H136 | 119.7 |
C111—C112—H112 | 119.9 | C135—C136—H136 | 119.7 |
C114—C113—C112 | 120.8 (5) | C22—C21—O2 | 109.1 (5) |
C114—C113—H113 | 119.6 | C22—C21—Se2 | 134.3 (5) |
C112—C113—H113 | 119.6 | O2—C21—Se2 | 116.5 (4) |
C115—C114—C113 | 119.5 (5) | C21—C22—C23 | 107.8 (6) |
C115—C114—H114 | 120.3 | C21—C22—H22 | 126.1 |
C113—C114—H114 | 120.3 | C23—C22—H22 | 126.1 |
C114—C115—C116 | 120.4 (5) | C24—C23—C22 | 106.3 (6) |
C114—C115—H115 | 119.8 | C24—C23—H23 | 126.8 |
C116—C115—H115 | 119.8 | C22—C23—H23 | 126.8 |
C115—C116—C111 | 120.5 (5) | C23—C24—O2 | 110.9 (6) |
C115—C116—H116 | 119.8 | C23—C24—H24 | 124.6 |
C111—C116—H116 | 119.8 | O2—C24—H24 | 124.6 |
C126—C121—C122 | 118.9 (5) | C24—O2—C21 | 106.0 (5) |
| | | |
Se2i—Pd1—Se2—C21 | −96.30 (16) | Pd1—P1—C121—C126 | −108.6 (4) |
Se1—Pd1—Se2—C21 | 87.88 (16) | C131—P1—C121—C122 | −165.7 (4) |
Se2i—Pd1—Se2—Pd1i | 0.0 | C111—P1—C121—C122 | −52.2 (4) |
Se1—Pd1—Se2—Pd1i | −175.82 (2) | Pd1—P1—C121—C122 | 67.5 (4) |
P1—Pd1—Se1—C11 | 137.63 (17) | C126—C121—C122—C123 | 0.3 (8) |
Se2—Pd1—Se1—C11 | −37.19 (17) | P1—C121—C122—C123 | −175.9 (4) |
Se2i—Pd1—P1—C131 | −138.78 (17) | C121—C122—C123—C124 | −0.6 (8) |
Se1—Pd1—P1—C131 | 37.28 (17) | C122—C123—C124—C125 | 0.4 (9) |
Se2i—Pd1—P1—C111 | 99.89 (16) | C123—C124—C125—C126 | 0.0 (9) |
Se1—Pd1—P1—C111 | −84.05 (16) | C122—C121—C126—C125 | 0.1 (8) |
Se2i—Pd1—P1—C121 | −16.8 (2) | P1—C121—C126—C125 | 176.2 (4) |
Se1—Pd1—P1—C121 | 159.3 (2) | C124—C125—C126—C121 | −0.2 (9) |
Pd1—Se1—C11—O1 | 98.6 (4) | C111—P1—C131—C136 | 163.5 (4) |
Pd1—Se1—C11—C12 | −84.6 (5) | C121—P1—C131—C136 | −87.3 (4) |
O1—C11—C12—C13 | 0.2 (7) | Pd1—P1—C131—C136 | 42.3 (4) |
Se1—C11—C12—C13 | −176.9 (4) | C111—P1—C131—C132 | −16.5 (5) |
C11—C12—C13—C14 | −0.2 (8) | C121—P1—C131—C132 | 92.6 (5) |
C12—C13—C14—O1 | 0.1 (8) | Pd1—P1—C131—C132 | −137.7 (4) |
C12—C11—O1—C14 | −0.2 (6) | C136—C131—C132—C133 | −1.8 (8) |
Se1—C11—O1—C14 | 177.0 (4) | P1—C131—C132—C133 | 178.2 (4) |
C13—C14—O1—C11 | 0.1 (7) | C131—C132—C133—C134 | 0.8 (9) |
C131—P1—C111—C112 | −116.2 (4) | C132—C133—C134—C135 | 1.0 (10) |
C121—P1—C111—C112 | 134.0 (4) | C133—C134—C135—C136 | −1.8 (10) |
Pd1—P1—C111—C112 | 7.9 (4) | C132—C131—C136—C135 | 1.0 (8) |
C131—P1—C111—C116 | 66.0 (5) | P1—C131—C136—C135 | −179.0 (5) |
C121—P1—C111—C116 | −43.7 (5) | C134—C135—C136—C131 | 0.8 (10) |
Pd1—P1—C111—C116 | −169.8 (4) | Pd1i—Se2—C21—C22 | 112.6 (6) |
C116—C111—C112—C113 | 0.6 (7) | Pd1—Se2—C21—C22 | −149.8 (6) |
P1—C111—C112—C113 | −177.2 (4) | Pd1i—Se2—C21—O2 | −67.7 (4) |
C111—C112—C113—C114 | −0.6 (8) | Pd1—Se2—C21—O2 | 29.9 (4) |
C112—C113—C114—C115 | −0.3 (8) | O2—C21—C22—C23 | −1.0 (7) |
C113—C114—C115—C116 | 1.2 (9) | Se2—C21—C22—C23 | 178.7 (5) |
C114—C115—C116—C111 | −1.2 (9) | C21—C22—C23—C24 | 1.1 (8) |
C112—C111—C116—C115 | 0.3 (8) | C22—C23—C24—O2 | −0.8 (8) |
P1—C111—C116—C115 | 178.1 (4) | C23—C24—O2—C21 | 0.2 (8) |
C131—P1—C121—C126 | 18.2 (5) | C22—C21—O2—C24 | 0.6 (7) |
C111—P1—C121—C126 | 131.6 (4) | Se2—C21—O2—C24 | −179.2 (4) |
Symmetry code: (i) −x+1, −y, −z+1. |