Tris[4-(3-methyl-4-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-yl­idene)isobutanolato-κ²O,O′]bis­(triphenyl­phosphine oxide-κO)europium(III)

In the title complex, [Eu(C₁₄H₁₅N₂O₂)₃(C₁₈H₁₅OP)₂], the Eu^III ion is surrounded by eight O atoms, six from the β-diketonate ligands and two from the triphenyl­phosphine oxides, with a distorted triangular dodeca­hedral coordination.

Key indicators

• Single-crystal X-ray study
• T = 294 K
• Mean [sigma](C-C) = 0.009 Å
• R factor = 0.048
• wR factor = 0.110
• Data-to-parameter ratio = 18.0

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.45 Ratio
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C48
PLAT242_ALERT_2_B Check Low       Ueq as Compared to Neighbors for        C62

Alert level C
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.38 Ratio
PLAT230_ALERT_2_C Hirshfeld Test Diff for    C66    -   C75     ..       5.74 su
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         O2
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C3
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for         C4
PLAT241_ALERT_2_C Check High      Ueq as Compared to Neighbors for        C35
PLAT242_ALERT_2_C Check Low       Ueq as Compared to Neighbors for         C1
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...          9
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      32.00 A   3  

   0 ALERT level A = In general: serious problem
   3 ALERT level B = Potentially serious problem
   9 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  10 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SAINT (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1999); software used to prepare material for publication: SHELXTL.

Tris[4-(3-methyl-4-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)isobutanolato- κ²O,O']bis(triphenylphosphine oxide-κO)europium(III)

Crystal data

[Eu(C14H15N2O2)3(C18H15OP)2]	F(000) = 2968
Mr = 1438.34	Dx = 1.331 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 5765 reflections
a = 13.3872 (14) Å	θ = 2.3–21.3°
b = 23.187 (2) Å	µ = 0.98 mm^−1
c = 23.130 (2) Å	T = 294 K
β = 91.890 (2)°	Block, colorless
V = 7175.7 (13) Å^3	0.20 × 0.18 × 0.16 mm
Z = 4

Data collection

Bruker SMART CCD area-detector diffractometer	15550 independent reflections
Radiation source: fine-focus sealed tube	8316 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.081
φ and ω scans	θmax = 27.0°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −7→17
Tmin = 0.815, Tmax = 0.855	k = −29→29
41976 measured reflections	l = −27→29

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.048	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.110	H-atom parameters constrained
S = 0.98	w = 1/[σ^2(Fo^2) + (0.0389P)^2] where P = (Fo^2 + 2Fc^2)/3
15550 reflections	(Δ/σ)max = 0.001
865 parameters	Δρmax = 0.82 e Å^−3
24 restraints	Δρmin = −0.66 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Eu1	0.031366 (18)	0.136231 (10)	0.776841 (10)	0.03353 (8)
P1	0.17882 (10)	0.07254 (6)	0.65613 (6)	0.0481 (4)
P2	−0.19737 (9)	0.12877 (5)	0.87052 (6)	0.0419 (3)
N1	−0.1087 (3)	0.26412 (16)	0.64993 (17)	0.0444 (10)
N2	−0.0711 (4)	0.31409 (18)	0.62556 (18)	0.0598 (12)
N3	−0.1570 (3)	−0.01592 (16)	0.70211 (16)	0.0446 (11)
N4	−0.1714 (3)	−0.07138 (16)	0.72447 (18)	0.0531 (11)
N5	0.2754 (3)	0.18673 (18)	0.90859 (18)	0.0530 (11)
N6	0.3001 (3)	0.2399 (2)	0.93312 (18)	0.0589 (12)
O1	0.1455 (2)	0.08999 (14)	0.71437 (13)	0.0495 (9)
O2	−0.1192 (2)	0.12969 (14)	0.82657 (13)	0.0536 (9)
O3	−0.0560 (2)	0.18863 (13)	0.70783 (13)	0.0447 (8)
O4	0.1463 (2)	0.20835 (14)	0.73951 (13)	0.0476 (9)
O5	−0.0646 (2)	0.06637 (12)	0.72400 (12)	0.0397 (8)
O6	0.0475 (2)	0.04558 (13)	0.82537 (13)	0.0499 (9)
O7	0.1489 (2)	0.14510 (13)	0.85217 (13)	0.0460 (8)
O8	0.0052 (2)	0.23062 (14)	0.82758 (14)	0.0513 (9)
C1	0.3114 (4)	0.0603 (2)	0.6592 (2)	0.0561 (15)
C2	0.3592 (5)	0.0283 (3)	0.6180 (3)	0.106 (3)
H2	0.3230	0.0137	0.5863	0.127*
C3	0.4599 (6)	0.0180 (4)	0.6238 (4)	0.145 (4)
H3	0.4913	−0.0035	0.5958	0.174*
C4	0.5141 (6)	0.0385 (5)	0.6692 (5)	0.151 (4)
H4	0.5823	0.0309	0.6725	0.181*
C5	0.4684 (5)	0.0711 (4)	0.7116 (4)	0.115 (3)
H5	0.5057	0.0861	0.7427	0.138*
C6	0.3667 (5)	0.0808 (3)	0.7065 (3)	0.083 (2)
H6	0.3350	0.1012	0.7352	0.099*
C7	0.1489 (4)	0.1238 (2)	0.5998 (2)	0.0548 (15)
C8	0.0501 (5)	0.1399 (3)	0.5923 (2)	0.0697 (17)
H8	0.0027	0.1247	0.6165	0.084*
C9	0.0206 (6)	0.1785 (3)	0.5490 (3)	0.095 (2)
H9	−0.0457	0.1901	0.5446	0.114*
C10	0.0916 (9)	0.1989 (3)	0.5130 (4)	0.115 (3)
H10	0.0726	0.2244	0.4837	0.138*
C11	0.1884 (8)	0.1831 (4)	0.5190 (4)	0.113 (3)
H11	0.2351	0.1973	0.4937	0.136*
C12	0.2173 (6)	0.1458 (3)	0.5625 (3)	0.085 (2)
H12	0.2842	0.1353	0.5669	0.103*
C13	0.1223 (4)	0.0068 (2)	0.6311 (2)	0.0462 (13)
C14	0.0999 (4)	−0.0345 (2)	0.6725 (2)	0.0593 (15)
H14	0.1154	−0.0273	0.7113	0.071*
C15	0.0548 (5)	−0.0862 (3)	0.6565 (3)	0.0723 (17)
H15	0.0412	−0.1138	0.6843	0.087*
C16	0.0306 (5)	−0.0961 (3)	0.5998 (3)	0.0777 (19)
H16	−0.0013	−0.1302	0.5889	0.093*
C17	0.0529 (5)	−0.0563 (3)	0.5588 (3)	0.080 (2)
H17	0.0377	−0.0640	0.5200	0.096*
C18	0.0975 (4)	−0.0050 (2)	0.5738 (2)	0.0660 (17)
H18	0.1112	0.0220	0.5454	0.079*
C19	−0.2956 (4)	0.1791 (2)	0.8528 (2)	0.0467 (13)
C20	−0.2661 (4)	0.2343 (2)	0.8383 (2)	0.0620 (16)
H20	−0.1985	0.2430	0.8369	0.074*
C21	−0.3362 (6)	0.2762 (3)	0.8258 (3)	0.083 (2)
H21	−0.3162	0.3135	0.8170	0.099*
C22	−0.4349 (6)	0.2628 (3)	0.8263 (3)	0.092 (2)
H22	−0.4824	0.2910	0.8176	0.110*
C23	−0.4649 (5)	0.2081 (3)	0.8395 (3)	0.096 (2)
H23	−0.5326	0.1991	0.8391	0.115*
C24	−0.3954 (4)	0.1664 (3)	0.8531 (3)	0.0720 (18)
H24	−0.4162	0.1294	0.8626	0.086*
C25	−0.1471 (4)	0.1496 (2)	0.9403 (2)	0.0483 (13)
C26	−0.0464 (4)	0.1421 (2)	0.9516 (2)	0.0588 (15)
H26	−0.0064	0.1267	0.9234	0.071*
C27	−0.0046 (5)	0.1573 (3)	1.0048 (3)	0.0766 (19)
H27	0.0632	0.1516	1.0126	0.092*
C28	−0.0628 (6)	0.1808 (3)	1.0457 (3)	0.082 (2)
H28	−0.0338	0.1920	1.0811	0.099*
C29	−0.1637 (6)	0.1883 (3)	1.0358 (3)	0.0772 (19)
H29	−0.2033	0.2035	1.0644	0.093*
C30	−0.2054 (5)	0.1728 (2)	0.9822 (2)	0.0671 (17)
H30	−0.2734	0.1781	0.9746	0.080*
C31	−0.2508 (4)	0.0586 (2)	0.8788 (3)	0.0541 (15)
C32	−0.2466 (4)	0.0289 (2)	0.9300 (3)	0.0773 (19)
H32	−0.2197	0.0466	0.9630	0.093*
C33	−0.2817 (5)	−0.0271 (3)	0.9335 (4)	0.114 (3)
H33	−0.2792	−0.0469	0.9685	0.137*
C34	−0.3198 (6)	−0.0526 (4)	0.8848 (6)	0.127 (5)
H34	−0.3429	−0.0904	0.8868	0.152*
C35	−0.3253 (6)	−0.0245 (4)	0.8328 (5)	0.122 (3)
H35	−0.3522	−0.0429	0.8001	0.146*
C36	−0.2899 (4)	0.0320 (3)	0.8294 (3)	0.082 (2)
H36	−0.2927	0.0516	0.7943	0.098*
C37	−0.0391 (4)	0.2364 (2)	0.68314 (19)	0.0395 (12)
C38	0.0501 (4)	0.2695 (2)	0.6808 (2)	0.0426 (12)
C39	0.0225 (4)	0.3173 (2)	0.6438 (2)	0.0539 (14)
C40	0.0815 (5)	0.3690 (2)	0.6264 (3)	0.092 (2)
H40A	0.0391	0.3946	0.6042	0.138*
H40B	0.1362	0.3569	0.6035	0.138*
H40C	0.1069	0.3885	0.6604	0.138*
C41	−0.2078 (4)	0.2464 (2)	0.6369 (2)	0.0454 (13)
C42	−0.2620 (4)	0.2186 (2)	0.6777 (2)	0.0591 (15)
H42	−0.2336	0.2121	0.7144	0.071*
C43	−0.3579 (5)	0.2002 (3)	0.6651 (3)	0.0754 (18)
H43	−0.3940	0.1815	0.6932	0.091*
C44	−0.4004 (5)	0.2093 (3)	0.6106 (4)	0.082 (2)
H44	−0.4653	0.1972	0.6018	0.099*
C45	−0.3457 (5)	0.2365 (3)	0.5700 (3)	0.082 (2)
H45	−0.3738	0.2425	0.5331	0.098*
C46	−0.2489 (4)	0.2556 (2)	0.5826 (2)	0.0608 (16)
H46	−0.2126	0.2742	0.5546	0.073*
C47	0.1410 (4)	0.2528 (2)	0.7089 (2)	0.0464 (13)
C48	0.2364 (4)	0.2878 (2)	0.7042 (2)	0.0576 (15)
H48	0.2308	0.3118	0.6693	0.069*
C49	0.3267 (5)	0.2482 (3)	0.6993 (3)	0.104 (2)
H49A	0.3868	0.2709	0.7007	0.156*
H49B	0.3219	0.2277	0.6633	0.156*
H49C	0.3283	0.2213	0.7308	0.156*
C50	0.2472 (6)	0.3268 (3)	0.7562 (3)	0.116 (3)
H50A	0.1892	0.3510	0.7583	0.174*
H50B	0.3056	0.3504	0.7528	0.174*
H50C	0.2537	0.3038	0.7906	0.174*
C51	−0.0908 (3)	0.01578 (19)	0.73611 (18)	0.0339 (11)
C52	−0.0612 (4)	−0.02117 (19)	0.78307 (19)	0.0387 (12)
C53	−0.1156 (4)	−0.07368 (19)	0.7725 (2)	0.0476 (13)
C54	−0.1175 (5)	−0.1288 (2)	0.8069 (2)	0.0730 (18)
H54A	−0.1692	−0.1535	0.7913	0.110*
H54B	−0.1305	−0.1201	0.8465	0.110*
H54C	−0.0541	−0.1478	0.8048	0.110*
C55	−0.2022 (3)	−0.0005 (2)	0.6487 (2)	0.0413 (12)
C56	−0.2130 (4)	0.0566 (2)	0.6322 (2)	0.0530 (14)
H56	−0.1907	0.0858	0.6570	0.064*
C57	−0.2567 (4)	0.0703 (2)	0.5792 (2)	0.0648 (16)
H57	−0.2625	0.1087	0.5681	0.078*
C58	−0.2917 (4)	0.0278 (3)	0.5428 (2)	0.0717 (18)
H58	−0.3217	0.0372	0.5072	0.086*
C59	−0.2820 (4)	−0.0289 (3)	0.5593 (2)	0.0696 (18)
H59	−0.3055	−0.0579	0.5347	0.083*
C60	−0.2382 (4)	−0.0429 (2)	0.6117 (2)	0.0592 (15)
H60	−0.2327	−0.0815	0.6225	0.071*
C61	0.0110 (4)	−0.0038 (2)	0.82567 (19)	0.0392 (12)
C62	0.0512 (4)	−0.0443 (2)	0.8719 (2)	0.0483 (13)
H62	0.0090	−0.0788	0.8728	0.058*
C63	0.0518 (6)	−0.0154 (3)	0.9296 (2)	0.106 (2)
H63A	0.0801	−0.0410	0.9584	0.159*
H63B	−0.0154	−0.0058	0.9393	0.159*
H63C	0.0911	0.0192	0.9283	0.159*
C64	0.1545 (5)	−0.0611 (3)	0.8587 (3)	0.131 (3)
H64A	0.1538	−0.0838	0.8240	0.196*
H64B	0.1827	−0.0834	0.8902	0.196*
H64C	0.1941	−0.0271	0.8535	0.196*
C65	0.1864 (4)	0.1893 (2)	0.87816 (19)	0.0379 (11)
C66	0.1507 (4)	0.2462 (2)	0.8838 (2)	0.0401 (12)
C67	0.2264 (4)	0.2750 (2)	0.9186 (2)	0.0512 (14)
C68	0.2335 (4)	0.3368 (2)	0.9381 (3)	0.0777 (19)
H68A	0.2920	0.3416	0.9628	0.117*
H68B	0.1751	0.3466	0.9590	0.117*
H68C	0.2380	0.3615	0.9050	0.117*
C69	0.3410 (4)	0.1397 (3)	0.9184 (2)	0.0546 (14)
C70	0.3352 (5)	0.0921 (3)	0.8830 (3)	0.0776 (19)
H70	0.2872	0.0906	0.8531	0.093*
C71	0.4013 (5)	0.0458 (3)	0.8919 (3)	0.096 (2)
H71	0.3966	0.0137	0.8679	0.115*
C72	0.4722 (5)	0.0475 (3)	0.9354 (3)	0.092 (2)
H72	0.5162	0.0169	0.9414	0.110*
C73	0.4772 (5)	0.0950 (3)	0.9697 (3)	0.083 (2)
H73	0.5260	0.0963	0.9992	0.099*
C74	0.4131 (4)	0.1413 (3)	0.9629 (2)	0.0692 (17)
H74	0.4181	0.1729	0.9875	0.083*
C75	0.0574 (4)	0.2641 (2)	0.8584 (2)	0.0499 (14)
C76	0.0159 (4)	0.3242 (2)	0.8685 (3)	0.0635 (16)
H76	0.0726	0.3503	0.8756	0.076*
C77	−0.0457 (5)	0.3475 (2)	0.8168 (3)	0.089 (2)
H77A	−0.0055	0.3475	0.7831	0.133*
H77B	−0.0669	0.3861	0.8248	0.133*
H77C	−0.1032	0.3234	0.8099	0.133*
C78	−0.0437 (5)	0.3221 (3)	0.9231 (3)	0.093 (2)
H78A	−0.1010	0.2977	0.9169	0.140*
H78B	−0.0653	0.3603	0.9327	0.140*
H78C	−0.0026	0.3070	0.9544	0.140*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Eu1	0.03850 (14)	0.02719 (12)	0.03483 (13)	−0.00300 (13)	0.00008 (10)	0.00174 (12)
P1	0.0456 (8)	0.0497 (9)	0.0496 (8)	−0.0020 (7)	0.0107 (7)	−0.0077 (7)
P2	0.0424 (7)	0.0352 (8)	0.0488 (8)	−0.0009 (6)	0.0095 (6)	−0.0005 (6)
N1	0.049 (3)	0.034 (2)	0.049 (3)	0.001 (2)	−0.004 (2)	0.014 (2)
N2	0.069 (3)	0.041 (3)	0.069 (3)	−0.001 (2)	−0.004 (3)	0.022 (2)
N3	0.057 (3)	0.033 (2)	0.043 (2)	−0.012 (2)	−0.008 (2)	0.0015 (19)
N4	0.069 (3)	0.031 (2)	0.059 (3)	−0.016 (2)	0.001 (3)	−0.001 (2)
N5	0.054 (3)	0.049 (3)	0.055 (3)	−0.006 (2)	−0.009 (2)	−0.008 (2)
N6	0.057 (3)	0.059 (3)	0.060 (3)	−0.006 (3)	−0.006 (3)	−0.018 (2)
O1	0.047 (2)	0.055 (2)	0.048 (2)	0.0010 (17)	0.0120 (17)	−0.0092 (17)
O2	0.047 (2)	0.055 (2)	0.059 (2)	−0.0044 (18)	0.0155 (18)	−0.0069 (18)
O3	0.047 (2)	0.0347 (19)	0.051 (2)	−0.0055 (16)	−0.0115 (17)	0.0140 (16)
O4	0.048 (2)	0.041 (2)	0.053 (2)	−0.0084 (16)	0.0000 (18)	0.0122 (17)
O5	0.051 (2)	0.0249 (17)	0.0432 (19)	−0.0090 (15)	−0.0063 (17)	0.0053 (14)
O6	0.069 (2)	0.031 (2)	0.049 (2)	−0.0047 (18)	−0.0176 (19)	0.0095 (16)
O7	0.051 (2)	0.041 (2)	0.0454 (19)	−0.0011 (17)	−0.0112 (17)	−0.0057 (16)
O8	0.051 (2)	0.039 (2)	0.064 (2)	0.0020 (17)	−0.0022 (19)	−0.0127 (18)
C1	0.042 (3)	0.060 (4)	0.067 (4)	−0.002 (3)	0.011 (3)	−0.011 (3)
C2	0.058 (5)	0.161 (8)	0.100 (5)	0.016 (5)	0.019 (4)	−0.039 (5)
C3	0.062 (6)	0.204 (11)	0.170 (10)	0.023 (7)	0.038 (6)	−0.037 (8)
C4	0.039 (5)	0.202 (12)	0.214 (12)	0.009 (6)	0.023 (7)	−0.004 (9)
C5	0.046 (5)	0.156 (8)	0.142 (8)	−0.009 (5)	−0.018 (5)	0.001 (6)
C6	0.057 (4)	0.100 (5)	0.092 (5)	−0.008 (4)	0.002 (4)	−0.013 (4)
C7	0.063 (4)	0.046 (4)	0.055 (4)	−0.007 (3)	0.001 (3)	−0.009 (3)
C8	0.093 (5)	0.063 (4)	0.053 (4)	0.003 (4)	0.001 (4)	−0.005 (3)
C9	0.125 (7)	0.080 (5)	0.077 (5)	0.030 (5)	−0.025 (5)	−0.020 (4)
C10	0.216 (12)	0.054 (5)	0.075 (6)	0.002 (7)	−0.005 (8)	0.012 (4)
C11	0.163 (9)	0.083 (6)	0.095 (6)	−0.037 (6)	0.031 (7)	0.019 (5)
C12	0.109 (6)	0.070 (5)	0.078 (5)	−0.026 (4)	0.015 (4)	0.009 (4)
C13	0.046 (3)	0.040 (3)	0.053 (3)	0.005 (2)	0.003 (3)	−0.005 (3)
C14	0.076 (4)	0.053 (4)	0.049 (3)	−0.002 (3)	0.008 (3)	−0.011 (3)
C15	0.083 (5)	0.053 (4)	0.081 (5)	−0.011 (3)	0.011 (4)	−0.002 (3)
C16	0.075 (5)	0.057 (4)	0.099 (5)	−0.013 (4)	−0.016 (4)	−0.012 (4)
C17	0.097 (5)	0.066 (5)	0.076 (5)	0.001 (4)	−0.031 (4)	−0.012 (4)
C18	0.089 (5)	0.058 (4)	0.050 (4)	−0.004 (3)	−0.007 (3)	0.000 (3)
C19	0.057 (4)	0.044 (3)	0.039 (3)	0.007 (3)	0.003 (3)	0.001 (2)
C20	0.069 (4)	0.049 (4)	0.067 (4)	−0.004 (3)	−0.009 (3)	0.011 (3)
C21	0.114 (6)	0.043 (4)	0.091 (5)	0.008 (4)	−0.013 (5)	0.002 (3)
C22	0.098 (6)	0.073 (5)	0.104 (6)	0.050 (5)	0.005 (5)	0.009 (4)
C23	0.065 (5)	0.097 (6)	0.127 (6)	0.027 (4)	0.022 (4)	0.042 (5)
C24	0.055 (4)	0.058 (4)	0.103 (5)	0.006 (3)	0.016 (4)	0.028 (4)
C25	0.058 (4)	0.039 (3)	0.048 (3)	−0.001 (3)	0.001 (3)	0.005 (2)
C26	0.071 (4)	0.057 (4)	0.049 (3)	−0.006 (3)	−0.003 (3)	0.000 (3)
C27	0.077 (5)	0.074 (5)	0.078 (5)	−0.016 (4)	−0.016 (4)	0.009 (4)
C28	0.121 (7)	0.061 (4)	0.062 (5)	−0.017 (5)	−0.019 (5)	0.007 (4)
C29	0.124 (6)	0.062 (4)	0.046 (4)	−0.002 (4)	0.005 (4)	0.001 (3)
C30	0.078 (4)	0.063 (4)	0.061 (4)	0.011 (3)	0.005 (4)	−0.001 (3)
C31	0.041 (3)	0.037 (3)	0.085 (4)	−0.002 (3)	0.014 (3)	−0.009 (3)
C32	0.058 (4)	0.049 (4)	0.125 (6)	−0.007 (3)	0.008 (4)	0.028 (4)
C33	0.076 (6)	0.062 (6)	0.205 (10)	0.002 (4)	0.026 (6)	0.048 (6)
C34	0.063 (5)	0.047 (5)	0.273 (15)	−0.009 (4)	0.038 (8)	−0.033 (7)
C35	0.075 (6)	0.092 (8)	0.200 (11)	−0.020 (5)	0.036 (7)	−0.067 (7)
C36	0.063 (4)	0.068 (5)	0.116 (6)	−0.017 (4)	0.020 (4)	−0.032 (4)
C37	0.051 (3)	0.031 (3)	0.036 (3)	−0.001 (3)	0.005 (3)	0.002 (2)
C38	0.053 (3)	0.033 (3)	0.042 (3)	−0.005 (2)	−0.005 (3)	0.010 (2)
C39	0.063 (4)	0.035 (3)	0.064 (4)	−0.008 (3)	0.007 (3)	0.013 (3)
C40	0.091 (5)	0.061 (4)	0.124 (6)	−0.016 (4)	−0.006 (4)	0.052 (4)
C41	0.045 (3)	0.040 (3)	0.051 (3)	0.008 (3)	−0.003 (3)	0.003 (3)
C42	0.059 (4)	0.059 (4)	0.058 (4)	−0.001 (3)	−0.005 (3)	0.009 (3)
C43	0.054 (4)	0.074 (5)	0.098 (5)	0.004 (3)	0.010 (4)	0.012 (4)
C44	0.048 (4)	0.080 (5)	0.118 (6)	0.005 (4)	−0.023 (5)	−0.008 (4)
C45	0.072 (5)	0.094 (5)	0.078 (5)	0.019 (4)	−0.021 (4)	−0.002 (4)
C46	0.056 (4)	0.071 (4)	0.055 (4)	0.012 (3)	−0.003 (3)	0.011 (3)
C47	0.058 (4)	0.039 (3)	0.041 (3)	−0.008 (3)	−0.003 (3)	−0.001 (2)
C48	0.061 (4)	0.058 (4)	0.054 (3)	−0.022 (3)	−0.001 (3)	0.015 (3)
C49	0.062 (4)	0.100 (5)	0.150 (6)	−0.018 (4)	0.007 (4)	0.028 (4)
C50	0.137 (6)	0.111 (5)	0.100 (5)	−0.077 (5)	0.006 (5)	−0.018 (4)
C51	0.039 (3)	0.026 (3)	0.037 (3)	0.000 (2)	0.004 (2)	−0.004 (2)
C52	0.047 (3)	0.029 (3)	0.040 (3)	0.000 (2)	0.000 (3)	0.003 (2)
C53	0.061 (4)	0.026 (3)	0.056 (3)	−0.007 (3)	0.007 (3)	0.005 (2)
C54	0.107 (5)	0.038 (3)	0.073 (4)	−0.022 (3)	−0.006 (4)	0.012 (3)
C55	0.041 (3)	0.042 (3)	0.041 (3)	−0.007 (2)	0.000 (3)	−0.006 (2)
C56	0.062 (4)	0.044 (3)	0.053 (3)	0.003 (3)	−0.002 (3)	−0.003 (3)
C57	0.079 (4)	0.059 (4)	0.055 (4)	−0.001 (3)	−0.013 (3)	0.010 (3)
C58	0.079 (5)	0.082 (5)	0.054 (4)	−0.004 (4)	−0.013 (3)	−0.003 (4)
C59	0.092 (5)	0.068 (4)	0.048 (4)	−0.016 (4)	−0.005 (3)	−0.024 (3)
C60	0.075 (4)	0.045 (3)	0.057 (4)	−0.010 (3)	−0.006 (3)	−0.006 (3)
C61	0.051 (3)	0.032 (3)	0.035 (3)	0.003 (2)	0.003 (3)	0.003 (2)
C62	0.064 (4)	0.031 (3)	0.049 (3)	0.006 (3)	−0.002 (3)	0.010 (2)
C63	0.163 (6)	0.102 (5)	0.053 (4)	0.041 (5)	0.000 (4)	0.013 (4)
C64	0.123 (6)	0.127 (6)	0.143 (6)	0.063 (5)	0.032 (5)	0.067 (5)
C65	0.037 (3)	0.040 (3)	0.037 (3)	−0.007 (2)	0.000 (2)	−0.004 (2)
C66	0.040 (3)	0.037 (3)	0.044 (3)	0.001 (2)	0.004 (3)	−0.004 (2)
C67	0.057 (4)	0.045 (3)	0.052 (3)	−0.012 (3)	0.010 (3)	−0.013 (3)
C68	0.083 (5)	0.059 (4)	0.090 (5)	−0.015 (3)	−0.002 (4)	−0.030 (3)
C69	0.051 (3)	0.057 (4)	0.055 (3)	0.005 (3)	0.005 (3)	0.003 (3)
C70	0.070 (4)	0.064 (4)	0.097 (5)	0.011 (4)	−0.024 (4)	−0.008 (4)
C71	0.081 (5)	0.063 (5)	0.143 (7)	0.018 (4)	−0.013 (5)	−0.014 (4)
C72	0.072 (5)	0.088 (6)	0.116 (6)	0.023 (4)	0.007 (5)	0.025 (5)
C73	0.060 (4)	0.112 (6)	0.076 (5)	0.029 (4)	−0.003 (4)	0.017 (5)
C74	0.056 (4)	0.097 (5)	0.054 (4)	0.007 (4)	−0.001 (3)	0.001 (4)
C75	0.059 (4)	0.039 (3)	0.052 (3)	−0.008 (3)	0.011 (3)	−0.009 (3)
C76	0.066 (4)	0.041 (3)	0.084 (4)	−0.003 (3)	0.003 (4)	−0.013 (3)
C77	0.099 (5)	0.053 (4)	0.114 (6)	0.017 (4)	−0.002 (5)	0.007 (4)
C78	0.107 (6)	0.086 (5)	0.087 (5)	0.032 (4)	0.013 (4)	−0.032 (4)

Geometric parameters (Å, º)

Eu1—O1	2.391 (3)	C32—H32	0.9300
Eu1—O2	2.358 (3)	C33—C34	1.356 (11)
Eu1—O3	2.296 (3)	C33—H33	0.9300
Eu1—O4	2.449 (3)	C34—C35	1.367 (11)
Eu1—O5	2.380 (3)	C34—H34	0.9300
Eu1—O6	2.389 (3)	C35—C36	1.397 (9)
Eu1—O7	2.318 (3)	C35—H35	0.9300
Eu1—O8	2.513 (3)	C36—H36	0.9300
P1—O1	1.489 (3)	C37—C38	1.422 (6)
P1—C13	1.789 (5)	C38—C47	1.415 (6)
P1—C1	1.797 (5)	C38—C39	1.439 (6)
P1—C7	1.799 (6)	C39—C40	1.497 (7)
P2—O2	1.483 (3)	C40—H40A	0.9600
P2—C31	1.790 (5)	C40—H40B	0.9600
P2—C25	1.794 (5)	C40—H40C	0.9600
P2—C19	1.795 (5)	C41—C42	1.370 (7)
N1—C37	1.351 (5)	C41—C46	1.373 (6)
N1—N2	1.390 (5)	C42—C43	1.375 (7)
N1—C41	1.412 (6)	C42—H42	0.9300
N2—C39	1.311 (6)	C43—C44	1.381 (8)
N3—C51	1.378 (5)	C43—H43	0.9300
N3—N4	1.402 (5)	C44—C45	1.365 (8)
N3—C55	1.405 (5)	C44—H44	0.9300
N4—C53	1.320 (5)	C45—C46	1.391 (8)
N5—C65	1.365 (5)	C45—H45	0.9300
N5—N6	1.393 (5)	C46—H46	0.9300
N5—C69	1.414 (6)	C47—C48	1.520 (7)
N6—C67	1.314 (6)	C48—C50	1.507 (7)
O3—C37	1.270 (5)	C48—C49	1.525 (8)
O4—C47	1.253 (5)	C48—H48	0.9800
O5—C51	1.258 (5)	C49—H49A	0.9600
O6—C61	1.245 (5)	C49—H49B	0.9600
O7—C65	1.282 (5)	C49—H49C	0.9600
O8—C75	1.251 (5)	C50—H50A	0.9600
C1—C2	1.380 (7)	C50—H50B	0.9600
C1—C6	1.385 (7)	C50—H50C	0.9600
C2—C3	1.372 (9)	C51—C52	1.429 (6)
C2—H2	0.9300	C52—C61	1.416 (6)
C3—C4	1.344 (11)	C52—C53	1.435 (6)
C3—H3	0.9300	C53—C54	1.505 (6)
C4—C5	1.395 (11)	C54—H54A	0.9600
C4—H4	0.9300	C54—H54B	0.9600
C5—C6	1.380 (8)	C54—H54C	0.9600
C5—H5	0.9300	C55—C60	1.381 (6)
C6—H6	0.9300	C55—C56	1.383 (6)
C7—C12	1.377 (8)	C56—C57	1.379 (6)
C7—C8	1.379 (7)	C56—H56	0.9300
C8—C9	1.391 (8)	C57—C58	1.369 (7)
C8—H8	0.9300	C57—H57	0.9300
C9—C10	1.367 (10)	C58—C59	1.374 (7)
C9—H9	0.9300	C58—H58	0.9300
C10—C11	1.349 (10)	C59—C60	1.368 (6)
C10—H10	0.9300	C59—H59	0.9300
C11—C12	1.374 (9)	C60—H60	0.9300
C11—H11	0.9300	C61—C62	1.508 (6)
C12—H12	0.9300	C62—C64	1.479 (8)
C13—C18	1.383 (6)	C62—C63	1.494 (7)
C13—C14	1.393 (7)	C62—H62	0.9800
C14—C15	1.387 (7)	C63—H63A	0.9600
C14—H14	0.9300	C63—H63B	0.9600
C15—C16	1.359 (7)	C63—H63C	0.9600
C15—H15	0.9300	C64—H64A	0.9600
C16—C17	1.365 (8)	C64—H64B	0.9600
C16—H16	0.9300	C64—H64C	0.9600
C17—C18	1.371 (7)	C65—C66	1.410 (6)
C17—H17	0.9300	C66—C75	1.426 (6)
C18—H18	0.9300	C66—C67	1.437 (6)
C19—C24	1.368 (7)	C67—C68	1.504 (6)
C19—C20	1.383 (7)	C68—H68A	0.9600
C20—C21	1.376 (7)	C68—H68B	0.9600
C20—H20	0.9300	C68—H68C	0.9600
C21—C22	1.357 (8)	C69—C70	1.374 (7)
C21—H21	0.9300	C69—C74	1.387 (7)
C22—C23	1.369 (9)	C70—C71	1.402 (8)
C22—H22	0.9300	C70—H70	0.9300
C23—C24	1.371 (7)	C71—C72	1.361 (8)
C23—H23	0.9300	C71—H71	0.9300
C24—H24	0.9300	C72—C73	1.357 (8)
C25—C30	1.373 (7)	C72—H72	0.9300
C25—C26	1.377 (7)	C73—C74	1.381 (8)
C26—C27	1.380 (7)	C73—H73	0.9300
C26—H26	0.9300	C74—H74	0.9300
C27—C28	1.359 (8)	C75—C76	1.522 (7)
C27—H27	0.9300	C76—C78	1.517 (7)
C28—C29	1.373 (8)	C76—C77	1.528 (7)
C28—H28	0.9300	C76—H76	0.9800
C29—C30	1.390 (7)	C77—H77A	0.9600
C29—H29	0.9300	C77—H77B	0.9600
C30—H30	0.9300	C77—H77C	0.9600
C31—C32	1.371 (7)	C78—H78A	0.9600
C31—C36	1.385 (7)	C78—H78B	0.9600
C32—C33	1.384 (8)	C78—H78C	0.9600
O4—Eu1—O8	70.67 (11)	C31—C36—C35	119.4 (8)
O1—Eu1—O4	70.84 (11)	C31—C36—H36	120.3
O7—Eu1—O8	70.94 (11)	C35—C36—H36	120.3
O7—Eu1—O6	71.13 (11)	O3—C37—N1	122.7 (4)
O5—Eu1—O6	71.42 (10)	O3—C37—C38	130.6 (5)
O2—Eu1—O8	72.16 (11)	N1—C37—C38	106.6 (4)
O3—Eu1—O4	72.85 (10)	C47—C38—C37	123.0 (4)
O5—Eu1—O1	74.30 (10)	C47—C38—C39	133.1 (5)
O3—Eu1—O5	75.46 (10)	C37—C38—C39	103.9 (4)
O2—Eu1—O5	75.58 (11)	N2—C39—C38	111.8 (5)
O2—Eu1—O6	77.26 (12)	N2—C39—C40	117.7 (5)
O7—Eu1—O4	77.61 (11)	C38—C39—C40	130.5 (5)
O3—Eu1—O8	77.77 (11)	C39—C40—H40A	109.5
O6—Eu1—O1	80.79 (11)	C39—C40—H40B	109.5
O3—Eu1—O2	87.09 (11)	H40A—C40—H40B	109.5
O7—Eu1—O1	93.59 (11)	C39—C40—H40C	109.5
O3—Eu1—O1	97.94 (11)	H40A—C40—H40C	109.5
O7—Eu1—O2	102.06 (11)	H40B—C40—H40C	109.5
O6—Eu1—O8	123.95 (11)	C42—C41—C46	119.8 (5)
O5—Eu1—O4	128.21 (10)	C42—C41—N1	120.4 (5)
O6—Eu1—O4	135.92 (11)	C46—C41—N1	119.8 (5)
O5—Eu1—O8	138.68 (10)	C41—C42—C43	120.8 (5)
O2—Eu1—O4	140.62 (11)	C41—C42—H42	119.6
O1—Eu1—O8	140.75 (11)	C43—C42—H42	119.6
O7—Eu1—O5	142.00 (10)	C42—C43—C44	120.0 (6)
O3—Eu1—O7	142.51 (11)	C42—C43—H43	120.0
O3—Eu1—O6	145.92 (11)	C44—C43—H43	120.0
O2—Eu1—O1	147.06 (11)	C45—C44—C43	119.0 (6)
O1—P1—C13	112.8 (2)	C45—C44—H44	120.5
O1—P1—C1	109.5 (2)	C43—C44—H44	120.5
C13—P1—C1	106.6 (2)	C44—C45—C46	121.2 (6)
O1—P1—C7	114.2 (2)	C44—C45—H45	119.4
C13—P1—C7	104.3 (2)	C46—C45—H45	119.4
C1—P1—C7	109.2 (3)	C41—C46—C45	119.1 (6)
O2—P2—C31	112.3 (2)	C41—C46—H46	120.4
O2—P2—C25	111.1 (2)	C45—C46—H46	120.4
C31—P2—C25	106.7 (3)	O4—C47—C38	121.1 (5)
O2—P2—C19	111.3 (2)	O4—C47—C48	116.6 (5)
C31—P2—C19	108.8 (3)	C38—C47—C48	122.3 (4)
C25—P2—C19	106.3 (2)	C50—C48—C47	108.8 (5)
C37—N1—N2	112.0 (4)	C50—C48—C49	111.4 (6)
C37—N1—C41	127.5 (4)	C47—C48—C49	110.7 (5)
N2—N1—C41	120.4 (4)	C50—C48—H48	108.6
C39—N2—N1	105.7 (4)	C47—C48—H48	108.6
C51—N3—N4	111.9 (4)	C49—C48—H48	108.6
C51—N3—C55	128.1 (4)	C48—C49—H49A	109.5
N4—N3—C55	119.9 (4)	C48—C49—H49B	109.5
C53—N4—N3	105.5 (4)	H49A—C49—H49B	109.5
C65—N5—N6	111.3 (4)	C48—C49—H49C	109.5
C65—N5—C69	130.1 (4)	H49A—C49—H49C	109.5
N6—N5—C69	118.7 (4)	H49B—C49—H49C	109.5
C67—N6—N5	106.1 (4)	C48—C50—H50A	109.5
P1—O1—Eu1	152.28 (19)	C48—C50—H50B	109.5
P2—O2—Eu1	165.7 (2)	H50A—C50—H50B	109.5
C37—O3—Eu1	132.8 (3)	C48—C50—H50C	109.5
C47—O4—Eu1	137.5 (3)	H50A—C50—H50C	109.5
C51—O5—Eu1	132.0 (3)	H50B—C50—H50C	109.5
C61—O6—Eu1	141.5 (3)	O5—C51—N3	123.3 (4)
C65—O7—Eu1	132.0 (3)	O5—C51—C52	131.0 (4)
C75—O8—Eu1	136.2 (3)	N3—C51—C52	105.7 (4)
C2—C1—C6	118.7 (5)	C61—C52—C51	121.6 (4)
C2—C1—P1	122.5 (5)	C61—C52—C53	133.6 (4)
C6—C1—P1	118.6 (4)	C51—C52—C53	104.7 (4)
C3—C2—C1	120.2 (7)	N4—C53—C52	112.2 (4)
C3—C2—H2	119.9	N4—C53—C54	117.4 (4)
C1—C2—H2	119.9	C52—C53—C54	130.4 (5)
C4—C3—C2	121.2 (9)	C53—C54—H54A	109.5
C4—C3—H3	119.4	C53—C54—H54B	109.5
C2—C3—H3	119.4	H54A—C54—H54B	109.5
C3—C4—C5	120.2 (8)	C53—C54—H54C	109.5
C3—C4—H4	119.9	H54A—C54—H54C	109.5
C5—C4—H4	119.9	H54B—C54—H54C	109.5
C6—C5—C4	118.8 (8)	C60—C55—C56	118.8 (5)
C6—C5—H5	120.6	C60—C55—N3	119.6 (5)
C4—C5—H5	120.6	C56—C55—N3	121.6 (4)
C5—C6—C1	120.8 (7)	C57—C56—C55	120.1 (5)
C5—C6—H6	119.6	C57—C56—H56	119.9
C1—C6—H6	119.6	C55—C56—H56	119.9
C12—C7—C8	118.4 (6)	C58—C57—C56	120.5 (5)
C12—C7—P1	124.2 (5)	C58—C57—H57	119.7
C8—C7—P1	117.3 (5)	C56—C57—H57	119.7
C7—C8—C9	120.8 (7)	C57—C58—C59	119.4 (5)
C7—C8—H8	119.6	C57—C58—H58	120.3
C9—C8—H8	119.6	C59—C58—H58	120.3
C10—C9—C8	118.3 (8)	C60—C59—C58	120.5 (5)
C10—C9—H9	120.8	C60—C59—H59	119.7
C8—C9—H9	120.8	C58—C59—H59	119.7
C11—C10—C9	121.9 (8)	C59—C60—C55	120.6 (5)
C11—C10—H10	119.1	C59—C60—H60	119.7
C9—C10—H10	119.1	C55—C60—H60	119.7
C10—C11—C12	119.5 (9)	O6—C61—C52	121.1 (4)
C10—C11—H11	120.2	O6—C61—C62	116.5 (4)
C12—C11—H11	120.2	C52—C61—C62	122.4 (4)
C11—C12—C7	121.0 (7)	C64—C62—C63	108.9 (6)
C11—C12—H12	119.5	C64—C62—C61	109.5 (5)
C7—C12—H12	119.5	C63—C62—C61	110.3 (4)
C18—C13—C14	118.2 (5)	C64—C62—H62	109.4
C18—C13—P1	124.3 (4)	C63—C62—H62	109.4
C14—C13—P1	117.5 (4)	C61—C62—H62	109.4
C15—C14—C13	120.8 (5)	C62—C63—H63A	109.5
C15—C14—H14	119.6	C62—C63—H63B	109.5
C13—C14—H14	119.6	H63A—C63—H63B	109.5
C16—C15—C14	119.5 (6)	C62—C63—H63C	109.5
C16—C15—H15	120.3	H63A—C63—H63C	109.5
C14—C15—H15	120.3	H63B—C63—H63C	109.5
C15—C16—C17	120.4 (6)	C62—C64—H64A	109.5
C15—C16—H16	119.8	C62—C64—H64B	109.5
C17—C16—H16	119.8	H64A—C64—H64B	109.5
C16—C17—C18	120.9 (6)	C62—C64—H64C	109.5
C16—C17—H17	119.5	H64A—C64—H64C	109.5
C18—C17—H17	119.5	H64B—C64—H64C	109.5
C17—C18—C13	120.3 (5)	O7—C65—N5	121.9 (4)
C17—C18—H18	119.9	O7—C65—C66	131.5 (5)
C13—C18—H18	119.9	N5—C65—C66	106.6 (4)
C24—C19—C20	119.1 (5)	C65—C66—C75	121.9 (4)
C24—C19—P2	124.5 (4)	C65—C66—C67	104.6 (4)
C20—C19—P2	116.3 (4)	C75—C66—C67	133.4 (5)
C21—C20—C19	120.4 (6)	N6—C67—C66	111.4 (5)
C21—C20—H20	119.8	N6—C67—C68	118.2 (5)
C19—C20—H20	119.8	C66—C67—C68	130.4 (5)
C22—C21—C20	119.6 (6)	C67—C68—H68A	109.5
C22—C21—H21	120.2	C67—C68—H68B	109.5
C20—C21—H21	120.2	H68A—C68—H68B	109.5
C21—C22—C23	120.5 (6)	C67—C68—H68C	109.5
C21—C22—H22	119.8	H68A—C68—H68C	109.5
C23—C22—H22	119.8	H68B—C68—H68C	109.5
C22—C23—C24	120.2 (6)	C70—C69—C74	119.2 (5)
C22—C23—H23	119.9	C70—C69—N5	120.1 (5)
C24—C23—H23	119.9	C74—C69—N5	120.7 (5)
C19—C24—C23	120.1 (6)	C69—C70—C71	120.3 (6)
C19—C24—H24	119.9	C69—C70—H70	119.8
C23—C24—H24	119.9	C71—C70—H70	119.8
C30—C25—C26	119.4 (5)	C72—C71—C70	120.5 (7)
C30—C25—P2	122.4 (4)	C72—C71—H71	119.8
C26—C25—P2	118.2 (4)	C70—C71—H71	119.8
C25—C26—C27	120.2 (6)	C73—C72—C71	118.4 (7)
C25—C26—H26	119.9	C73—C72—H72	120.8
C27—C26—H26	119.9	C71—C72—H72	120.8
C28—C27—C26	119.9 (6)	C72—C73—C74	123.1 (6)
C28—C27—H27	120.0	C72—C73—H73	118.5
C26—C27—H27	120.0	C74—C73—H73	118.5
C27—C28—C29	121.1 (6)	C73—C74—C69	118.5 (6)
C27—C28—H28	119.4	C73—C74—H74	120.7
C29—C28—H28	119.4	C69—C74—H74	120.7
C28—C29—C30	118.7 (7)	O8—C75—C66	121.4 (5)
C28—C29—H29	120.6	O8—C75—C76	117.1 (5)
C30—C29—H29	120.6	C66—C75—C76	121.5 (5)
C25—C30—C29	120.6 (6)	C78—C76—C75	107.7 (5)
C25—C30—H30	119.7	C78—C76—C77	112.2 (5)
C29—C30—H30	119.7	C75—C76—C77	113.1 (5)
C32—C31—C36	119.5 (6)	C78—C76—H76	107.9
C32—C31—P2	123.0 (5)	C75—C76—H76	107.9
C36—C31—P2	117.3 (5)	C77—C76—H76	107.9
C31—C32—C33	121.2 (7)	C76—C77—H77A	109.5
C31—C32—H32	119.4	C76—C77—H77B	109.5
C33—C32—H32	119.4	H77A—C77—H77B	109.5
C34—C33—C32	118.7 (9)	C76—C77—H77C	109.5
C34—C33—H33	120.7	H77A—C77—H77C	109.5
C32—C33—H33	120.7	H77B—C77—H77C	109.5
C33—C34—C35	122.0 (10)	C76—C78—H78A	109.5
C33—C34—H34	119.0	C76—C78—H78B	109.5
C35—C34—H34	119.0	H78A—C78—H78B	109.5
C34—C35—C36	119.3 (10)	C76—C78—H78C	109.5
C34—C35—H35	120.4	H78A—C78—H78C	109.5
C36—C35—H35	120.4	H78B—C78—H78C	109.5
C37—N1—N2—C39	0.0 (6)	C26—C27—C28—C29	1.8 (10)
C41—N1—N2—C39	−177.4 (4)	C27—C28—C29—C30	−1.7 (9)
C51—N3—N4—C53	1.0 (5)	C26—C25—C30—C29	−0.4 (8)
C55—N3—N4—C53	176.4 (4)	P2—C25—C30—C29	179.9 (4)
C65—N5—N6—C67	0.8 (6)	C28—C29—C30—C25	1.0 (9)
C69—N5—N6—C67	−178.5 (4)	O2—P2—C31—C32	119.6 (5)
C13—P1—O1—Eu1	−85.0 (5)	C25—P2—C31—C32	−2.4 (5)
C1—P1—O1—Eu1	156.6 (4)	C19—P2—C31—C32	−116.7 (5)
C7—P1—O1—Eu1	33.9 (5)	O2—P2—C31—C36	−54.6 (5)
O3—Eu1—O1—P1	−14.3 (4)	C25—P2—C31—C36	−176.6 (4)
O7—Eu1—O1—P1	−158.6 (4)	C19—P2—C31—C36	69.0 (5)
O2—Eu1—O1—P1	82.6 (5)	C36—C31—C32—C33	−0.6 (9)
O5—Eu1—O1—P1	58.1 (4)	P2—C31—C32—C33	−174.7 (5)
O6—Eu1—O1—P1	131.2 (4)	C31—C32—C33—C34	0.7 (11)
O4—Eu1—O1—P1	−83.0 (4)	C32—C33—C34—C35	−0.6 (14)
O8—Eu1—O1—P1	−94.7 (4)	C33—C34—C35—C36	0.5 (14)
C31—P2—O2—Eu1	−114.2 (9)	C32—C31—C36—C35	0.5 (9)
C25—P2—O2—Eu1	5.3 (9)	P2—C31—C36—C35	175.0 (5)
C19—P2—O2—Eu1	123.5 (8)	C34—C35—C36—C31	−0.5 (12)
O3—Eu1—O2—P2	−136.4 (9)	Eu1—O3—C37—N1	−169.2 (3)
O7—Eu1—O2—P2	6.9 (9)	Eu1—O3—C37—C38	14.5 (8)
O5—Eu1—O2—P2	147.8 (9)	N2—N1—C37—O3	−177.3 (4)
O6—Eu1—O2—P2	74.1 (9)	C41—N1—C37—O3	−0.1 (8)
O1—Eu1—O2—P2	123.4 (8)	N2—N1—C37—C38	−0.2 (5)
O4—Eu1—O2—P2	−78.2 (9)	C41—N1—C37—C38	177.0 (5)
O8—Eu1—O2—P2	−58.3 (9)	O3—C37—C38—C47	−0.9 (8)
O7—Eu1—O3—C37	24.7 (5)	N1—C37—C38—C47	−177.7 (4)
O2—Eu1—O3—C37	130.8 (4)	O3—C37—C38—C39	177.0 (5)
O5—Eu1—O3—C37	−153.4 (4)	N1—C37—C38—C39	0.2 (5)
O6—Eu1—O3—C37	−167.2 (4)	N1—N2—C39—C38	0.1 (6)
O1—Eu1—O3—C37	−81.9 (4)	N1—N2—C39—C40	−177.2 (5)
O4—Eu1—O3—C37	−14.9 (4)	C47—C38—C39—N2	177.4 (5)
O8—Eu1—O3—C37	58.4 (4)	C37—C38—C39—N2	−0.2 (6)
O3—Eu1—O4—C47	12.4 (4)	C47—C38—C39—C40	−5.6 (10)
O7—Eu1—O4—C47	−144.2 (5)	C37—C38—C39—C40	176.7 (6)
O2—Eu1—O4—C47	−50.2 (5)	C37—N1—C41—C42	36.2 (7)
O5—Eu1—O4—C47	67.2 (5)	N2—N1—C41—C42	−146.8 (5)
O6—Eu1—O4—C47	170.5 (4)	C37—N1—C41—C46	−141.8 (5)
O1—Eu1—O4—C47	117.5 (5)	N2—N1—C41—C46	35.2 (7)
O8—Eu1—O4—C47	−70.3 (5)	C46—C41—C42—C43	−0.7 (8)
O3—Eu1—O5—C51	−160.4 (4)	N1—C41—C42—C43	−178.6 (5)
O7—Eu1—O5—C51	21.6 (5)	C41—C42—C43—C44	0.3 (9)
O2—Eu1—O5—C51	−69.6 (4)	C42—C43—C44—C45	0.3 (9)
O6—Eu1—O5—C51	11.5 (4)	C43—C44—C45—C46	−0.7 (10)
O1—Eu1—O5—C51	96.9 (4)	C42—C41—C46—C45	0.3 (8)
O4—Eu1—O5—C51	145.9 (4)	N1—C41—C46—C45	178.3 (5)
O8—Eu1—O5—C51	−109.2 (4)	C44—C45—C46—C41	0.4 (9)
O3—Eu1—O6—C61	3.0 (6)	Eu1—O4—C47—C38	−7.0 (7)
O7—Eu1—O6—C61	175.4 (5)	Eu1—O4—C47—C48	172.4 (3)
O2—Eu1—O6—C61	67.7 (5)	C37—C38—C47—O4	−2.8 (8)
O5—Eu1—O6—C61	−11.2 (5)	C39—C38—C47—O4	180.0 (5)
O1—Eu1—O6—C61	−87.6 (5)	C37—C38—C47—C48	177.9 (5)
O4—Eu1—O6—C61	−137.4 (5)	C39—C38—C47—C48	0.7 (9)
O8—Eu1—O6—C61	125.6 (5)	O4—C47—C48—C50	−82.9 (6)
O3—Eu1—O7—C65	10.3 (5)	C38—C47—C48—C50	96.4 (6)
O2—Eu1—O7—C65	−90.8 (4)	O4—C47—C48—C49	39.8 (7)
O5—Eu1—O7—C65	−172.8 (3)	C38—C47—C48—C49	−140.9 (5)
O6—Eu1—O7—C65	−162.7 (4)	Eu1—O5—C51—N3	172.0 (3)
O1—Eu1—O7—C65	118.3 (4)	Eu1—O5—C51—C52	−9.6 (7)
O4—Eu1—O7—C65	48.9 (4)	N4—N3—C51—O5	178.4 (4)
O8—Eu1—O7—C65	−24.7 (4)	C55—N3—C51—O5	3.5 (7)
O3—Eu1—O8—C75	−135.6 (5)	N4—N3—C51—C52	−0.3 (5)
O7—Eu1—O8—C75	23.5 (5)	C55—N3—C51—C52	−175.2 (4)
O2—Eu1—O8—C75	133.5 (5)	O5—C51—C52—C61	−1.8 (8)
O5—Eu1—O8—C75	173.9 (4)	N3—C51—C52—C61	176.8 (4)
O6—Eu1—O8—C75	73.3 (5)	O5—C51—C52—C53	−179.0 (5)
O1—Eu1—O8—C75	−48.0 (5)	N3—C51—C52—C53	−0.4 (5)
O4—Eu1—O8—C75	−59.7 (5)	N3—N4—C53—C52	−1.3 (6)
O1—P1—C1—C2	160.7 (5)	N3—N4—C53—C54	179.0 (4)
C13—P1—C1—C2	38.4 (6)	C61—C52—C53—N4	−175.7 (5)
C7—P1—C1—C2	−73.7 (6)	C51—C52—C53—N4	1.1 (6)
O1—P1—C1—C6	−15.2 (5)	C61—C52—C53—C54	4.0 (10)
C13—P1—C1—C6	−137.5 (5)	C51—C52—C53—C54	−179.2 (5)
C7—P1—C1—C6	110.4 (5)	C51—N3—C55—C60	157.9 (5)
C6—C1—C2—C3	−1.1 (11)	N4—N3—C55—C60	−16.7 (7)
P1—C1—C2—C3	−177.0 (7)	C51—N3—C55—C56	−23.1 (7)
C1—C2—C3—C4	0.1 (15)	N4—N3—C55—C56	162.4 (5)
C2—C3—C4—C5	−0.2 (17)	C60—C55—C56—C57	−1.6 (8)
C3—C4—C5—C6	1.3 (16)	N3—C55—C56—C57	179.3 (5)
C4—C5—C6—C1	−2.3 (12)	C55—C56—C57—C58	1.3 (9)
C2—C1—C6—C5	2.2 (10)	C56—C57—C58—C59	−0.6 (9)
P1—C1—C6—C5	178.2 (6)	C57—C58—C59—C60	0.2 (10)
O1—P1—C7—C12	127.7 (5)	C58—C59—C60—C55	−0.6 (9)
C13—P1—C7—C12	−108.8 (5)	C56—C55—C60—C59	1.3 (8)
C1—P1—C7—C12	4.8 (6)	N3—C55—C60—C59	−179.7 (5)
O1—P1—C7—C8	−55.2 (5)	Eu1—O6—C61—C52	6.3 (8)
C13—P1—C7—C8	68.4 (5)	Eu1—O6—C61—C62	−176.3 (3)
C1—P1—C7—C8	−178.0 (4)	C51—C52—C61—O6	3.9 (7)
C12—C7—C8—C9	−1.5 (9)	C53—C52—C61—O6	−179.7 (5)
P1—C7—C8—C9	−178.8 (4)	C51—C52—C61—C62	−173.4 (4)
C7—C8—C9—C10	1.7 (9)	C53—C52—C61—C62	3.0 (8)
C8—C9—C10—C11	−0.7 (12)	O6—C61—C62—C64	−70.9 (6)
C9—C10—C11—C12	−0.6 (14)	C52—C61—C62—C64	106.5 (6)
C10—C11—C12—C7	0.8 (12)	O6—C61—C62—C63	48.9 (7)
C8—C7—C12—C11	0.2 (9)	C52—C61—C62—C63	−133.7 (5)
P1—C7—C12—C11	177.3 (5)	Eu1—O7—C65—N5	−159.1 (3)
O1—P1—C13—C18	146.2 (5)	Eu1—O7—C65—C66	22.6 (7)
C1—P1—C13—C18	−93.6 (5)	N6—N5—C65—O7	−179.7 (4)
C7—P1—C13—C18	21.8 (5)	C69—N5—C65—O7	−0.5 (8)
O1—P1—C13—C14	−32.3 (5)	N6—N5—C65—C66	−1.0 (5)
C1—P1—C13—C14	87.8 (4)	C69—N5—C65—C66	178.1 (5)
C7—P1—C13—C14	−156.7 (4)	O7—C65—C66—C75	−0.1 (8)
C18—C13—C14—C15	0.5 (8)	N5—C65—C66—C75	−178.5 (4)
P1—C13—C14—C15	179.2 (4)	O7—C65—C66—C67	179.3 (5)
C13—C14—C15—C16	−1.2 (9)	N5—C65—C66—C67	0.8 (5)
C14—C15—C16—C17	1.8 (10)	N5—N6—C67—C66	−0.2 (6)
C15—C16—C17—C18	−1.8 (10)	N5—N6—C67—C68	−178.6 (4)
C16—C17—C18—C13	1.1 (10)	C65—C66—C67—N6	−0.3 (6)
C14—C13—C18—C17	−0.5 (9)	C75—C66—C67—N6	178.9 (5)
P1—C13—C18—C17	−179.0 (5)	C65—C66—C67—C68	177.8 (5)
O2—P2—C19—C24	131.9 (5)	C75—C66—C67—C68	−3.0 (9)
C31—P2—C19—C24	7.6 (6)	C65—N5—C69—C70	19.2 (8)
C25—P2—C19—C24	−107.0 (5)	N6—N5—C69—C70	−161.7 (5)
O2—P2—C19—C20	−48.4 (4)	C65—N5—C69—C74	−162.1 (5)
C31—P2—C19—C20	−172.7 (4)	N6—N5—C69—C74	17.0 (7)
C25—P2—C19—C20	72.7 (4)	C74—C69—C70—C71	0.1 (9)
C24—C19—C20—C21	1.7 (8)	N5—C69—C70—C71	178.8 (6)
P2—C19—C20—C21	−178.0 (4)	C69—C70—C71—C72	−0.4 (11)
C19—C20—C21—C22	−1.7 (10)	C70—C71—C72—C73	0.0 (11)
C20—C21—C22—C23	0.4 (11)	C71—C72—C73—C74	0.6 (11)
C21—C22—C23—C24	1.0 (12)	C72—C73—C74—C69	−0.8 (10)
C20—C19—C24—C23	−0.4 (9)	C70—C69—C74—C73	0.5 (8)
P2—C19—C24—C23	179.3 (5)	N5—C69—C74—C73	−178.3 (5)
C22—C23—C24—C19	−1.0 (11)	Eu1—O8—C75—C66	−15.2 (8)
O2—P2—C25—C30	155.2 (4)	Eu1—O8—C75—C76	166.1 (3)
C31—P2—C25—C30	−82.0 (5)	C65—C66—C75—O8	−3.3 (7)
C19—P2—C25—C30	34.0 (5)	C67—C66—C75—O8	177.5 (5)
O2—P2—C25—C26	−24.5 (5)	C65—C66—C75—C76	175.3 (5)
C31—P2—C25—C26	98.2 (4)	C67—C66—C75—C76	−3.8 (9)
C19—P2—C25—C26	−145.7 (4)	O8—C75—C76—C78	91.1 (6)
C30—C25—C26—C27	0.5 (8)	C66—C75—C76—C78	−87.6 (6)
P2—C25—C26—C27	−179.8 (4)	O8—C75—C76—C77	−33.5 (7)
C25—C26—C27—C28	−1.2 (9)	C66—C75—C76—C77	147.8 (5)