Acta Cryst. (2005). E61, m2670-m2673  [ doi:10.1107/S1600536805037864 ]

(Adeninato-N⁹)[N-(2-aminoethyl)salicylideneiminato]palladium(II) 3.5-hydrate

M. Odoko and N. Okabe

Abstract: In the title compound, {[(2-aminoethyl)iminomethyl]phenolato-³N,N',O}(9H-purine-6-aminato-N⁹)palladium(II) 3.5-hydrate, [Pd(C₅H₄N₅)(C₉H₁₁N₂O)]·3.5H₂O, the Pd^II ion is coordinated by the N9 atom of the adeninate ligand, two N atoms and one O atom of the N-(2-aminoethyl)salicylideneiminate in a square-planar coordination. The crystal structure is stabilized by centrosymmetric stacking interactions between neighbouring complexes, and by hydrogen bonds involving adeninate and N-(2-aminoethyl)salicylideneiminate ligands, and non-coordinated water molecules.

Online 23 November 2005

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