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Acta Cryst. (2005). E61, o4165-o4166  [ doi:10.1107/S1600536805037244 ]

(R)-(+)-2,3-Methylenedioxy-8-oxoberbine

A. Gzella, M. Chrzanowska and A. Dreas

Abstract: The title compound [systematic name: (R)-(+)-2,3-methylenedioxy-5,6,13,13a-tetrahydro-8H-dibenzo[a,g]quinolizin-8-one], C18H15NO3, an optically active protoberberine derivative, was synthesized and its absolute configuration has been additionally confirmed by this crystal structure refinement. The H atom at the asymmetric centre assumes a [beta] configuration and is oriented in the bisectional position relative to the tetrahydropyridine ring and axial to the tetrahydropyridinone ring.

Online 19 November 2005


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