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Acta Cryst. (2005). E61, m2595-m2597  [ doi:10.1107/S160053680503638X ]

catena-Poly[trimethyltin(IV)-[mu]-3,4-dichlorophenylacetato]

M. A. Saeed, D. C. Craig, A. Badshah, S. Ali and M. K. Rauf

Abstract: The title compound, [Sn(CH3)3(C8H5Cl2O2)]n, forms polymeric chains involving both O atoms of the carboxylate group. The coordination geometry of the Sn atom is slightly distorted trigonal bipyramidal. The three methyl groups occupy the equatorial positions, with Sn-C bond lengths in the range 2.103 (8)-2.118 (7) Å. The two O atoms are situated in the axial positions, with Sn-O distances of 2.189 (4) Å and 2.369 (5) Å.

Online 16 November 2005


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