Acta Cryst. (2005). E61, m2507-m2509  [ doi:10.1107/S1600536805035257 ]

Poly[[(1,10-phenanthroline)(₃-pyridine-2,3-dicarboxylato)manganese(II)] monohydrate]

X.-L. Niu, J.-M. Dou, C.-W. Hu, D.-C. Li and D.-Q. Wang

Abstract: The title complex, {[Mn(C₇H₃NO₄)(C₁₂H₈N₂)]·H₂O}_n, conventionally abbreviated to {[Mn(2,3-pddc)(phen)]·H₂O}_n (phen is 1,10-phenanthroline and 2,3-pddc is 2,3-pyridinedicarboxylate), has been synthesized under hydrothermal conditions. In the complex, the Mn atom is coordinated by three O atoms of three symmetry-equivalent 2,3-pddc molecules. The complex thus extends in two dimensions, resulting in the formation of a two-dimensional network structure. The complex is further assembled into a three-dimensional network by - stacking interactions involving the phen ligands.

Online 5 November 2005

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