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Acta Cryst. (2006). E62, m77-m79  [ doi:10.1107/S1600536805040754 ]

Di-[mu]-chloro-bis[(2,2-bipyridine)chlorocopper(II)]

G. E. Kostakis, E. Nordlander, M. Haukka and J. C. Plakatouras

Abstract: The title compound, [Cu2Cl4(C10H8N2)2], represents the first example of a simple dimeric coordination complex of CuII and 2,2'-bipyridine (bpy). The metal is in a five-coordinate distorted square-pyramidal environment, bonded to a 2,2'- bipyridine molecule, two bridging chlorides and one terminal chloride. There is a centre of symmetry at the mid-point of the Cu...Cu vector.

Online 10 December 2005


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