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Acta Cryst. (2006). E62, o276-o278  [ doi:10.1107/S160053680504170X ]

Benzimidazolium 3,5-dihydroxybenzoate

X. Huang, J.-G. Liu and D.-J. Xu

Abstract: In the crystal structure of the title compound, C7H7N2+·C7H5O4-, the partially overlapped arrangement and the face-to-face separation of 3.557 (7) Å suggest [pi]-[pi] stacking between parallel benzimidazolium cations, and the C-H...Cg angle of 173° and H...Cg separation of 2.64 Å (where Cg is the centroid of the benzene ring) suggest C-H...[pi] stacking between the benzimidazolium cation and dihydroxybenzoate anion. Classical N-H...O and O-H...O and weak C-H...O hydrogen bonds consolidate the crystal structure.

Online 21 December 2005


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