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Acta Cryst. (2006). E62, o276-o278 [ doi:10.1107/S160053680504170X ]
Abstract: In the crystal structure of the title compound, C7H7N2+·C7H5O4-, the partially overlapped arrangement and the face-to-face separation of 3.557 (7) Å suggest
-
stacking between parallel benzimidazolium cations, and the C-H
Cg angle of 173° and H
Cg separation of 2.64 Å (where Cg is the centroid of the benzene ring) suggest C-H
stacking between the benzimidazolium cation and dihydroxybenzoate anion. Classical N-H
O and O-H
O and weak C-H
O hydrogen bonds consolidate the crystal structure.
Online 21 December 2005
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