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Acta Cryst. (2006). E62, o236-o238 [ doi:10.1107/S1600536805041255 ]
Abstract: The title compound, C6H9N2+·C2H3O2-, contains eight- and sixteen-membered hydrogen-bonded rings involving 2-amino-3-methylpyridinium and acetate ions. The 2-amino-3-methylpyridinium and acetate ions are linked into zigzag chains by C-H
O and N-H
O hydrogen bonds. The dihedral angle between the 2-amino-3-methylpyridinium ring and the hydrogen-bonded acetate ion is 6.63 (6)°. The heterocycle is fully protonated, enabling amine-imine tautomerization.
Online 14 December 2005
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