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Acta Cryst. (2006). E62, m1-m3  [ doi:10.1107/S1600536805039152 ]

1,1'-(Butane-1,4-diyl)bis(1H-benzimidazol-3-ium) bis[bis(pyridine-2,6-dicarboxylato-[kappa]3O,N,O')ferrate(III)] methanol disolvate

Z.-Y. Hou and D.-M. Zhu

Abstract: In the title complex, (C18H20N4)[Fe(C7O4H3N)2]2·2CH4O, the Fe atom exists in an approximately octahedral geometry, chelated by two pyridine-2,6-dicarboxylate ligands. Extensive hydrogen bonding among the carboxylate groups, the 1,1'-(butane-1,4-diyl)bis-1H-benzimidazol-3-ium ion and solvent methanol molecules as well as [pi]-[pi] stacking are present in the structure.

Online 3 December 2005


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