Acta Cryst. (2006). E62, m138-m140  [ doi:10.1107/S1600536805041681 ]

Chloro(pyrimidine-2-thiolato-²N,S)(triphenylphosphine-P)palladium(II) methanol hemisolvate

F. Shaheen, M. Najam-Ul-Haq, A. Badshah, K. Wurst and S. Ali

Abstract: In the title compound, [Pd(C₄H₃N₂S)Cl(C₁₈H₁₅P)]·0.5CH₃OH, the Pd atom is four-coordinate and exhibits a slightly distorted square-planar geometry with the S atom of the pyrimidine-2-thiolate ligand trans to the chloro ligand and the coordinated N atom trans to the phosphine. The compound crystallizes with two unique molecules and a disordered methanol solvent molecule in the asymmetric unit.

Online 21 December 2005

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