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Acta Cryst. (2006). E62, m58-m60  [ doi:10.1107/S1600536805040043 ]

Weak intermolecular hydrogen bonding in the pyridine adduct of a nickel(II) complex with a sterically demanding [beta]-diketonate ligand

N. Judas and B. Kaitner

Abstract: The nickel(II) complex trans-bis(2-benzyl-1,3-diphenylpropane-1,3-dionato)dipyridinenickel(II), [Ni(C22H17O2)2(C5H5N)2], with a bulky [beta]-diketonate ligand, 2-benzyl-1,3-diphenylpropane-1,3-dione, has an octahedral nickel(II) centre. Molecules are held together by C-H...O and C-H...[pi] interactions to form layers.

Online 10 December 2005


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