Acta Cryst. (2006). E62, m166-m167  [ doi:10.1107/S1600536805041711 ]

Bis[2-(phenylsulfanyl)benzenethiolato]palladium(II)

D. Shimizu, N. Takeda, T. Sasamori and N. Tokitoh

Abstract: In the title complex, [Pd(C₁₂H₉S₂)₂], the central Pd atom has a slightly distorted cis-planar four-coordinate geometry defined by the two thiolate and the two sulfanyl S atoms from two 2-(phenylsulfanyl)benzenethiolate ligands. The two phenyl groups are on the same side of the PdS₄ plane and indicative of the typical arrangement of intermolecular -stacking. Moreover, an intermolecular C-H stacking interaction links molecules to one another.

Online 23 December 2005

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