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Acta Cryst. (2006). E62, m292-m294  [ doi:10.1107/S1600536806001127 ]

catena-Poly[[cis-diaqua(2,2'-bipyridine)manganese(II)]-[mu]-5-sulfonatosalicylato]

S.-R. Fan and L.-G. Zhu

Abstract: In the title polymeric compound, [Mn(C7H4O6S)(C10H8N2)(H2O)2]n, the octahedral coordination geometry of each MnII atom comprises two N-atom donors of one 2,2'-bipyridine ligand, two O atoms, one from a carboxylate and one from a sulfonate group of two 5-sulfonatosalicylate ligands, and two further O atoms from two water molecules. The molecules, bridged by 5-sulfonatosalicylate ligands, form a one-dimensional polymeric chain. Intermolecular O-H...O hydrogen bonds between the chains generate a two-dimensional hydrogen-bonded layer.

Online 18 January 2006


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