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Acta Cryst. (2006). E62, m227-m228  [ doi:10.1107/S1600536805041504 ]

[11,23-Dimethyl-15,19-diaza-3,7-diazoniatricyclo[19.3.1.19,13]tetracosa-1(25),2,7,9,11,13(26),14,19,21,23-decaene-25,26-diolato-[kappa]4N15,N19,O,O']tris(nitrato-[kappa]2O,O')samarium(III)

A. M. d'Hardemare, C. Philouze and O. Jarjayes

Abstract: In the title compound, [Sm(NO3)3(C24H28N4O2)], the Sm atom has tenfold coordination, built up from two imino N atoms, two deprotonated phenolic O atoms and three bidentate nitrate groups. The Sm ion is incorporated in an out-of-plane position relative to the macrocyclic ligand, which adopts a folded conformation.

Online 7 January 2006


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