Acta Cryst. (2006). E62, m275-m277  [ doi:10.1107/S1600536806000146 ]

(C)-(2,4-Di-tert-butyl-6-{[(2S)-3,3-dimethyl-1-oxido-2-butyl]iminomethyl}phenolato)ethanol-cis-dioxomolybdenum(VI) at 100 K

J. Hartung, M. Greb, I. Svoboda and H. Fuess

Abstract: The central atom in the title complex, [Mo(C₂₁H₃₂NO₂)O₂(C₂H₆O)], is offset from the equatorial plane of a tetragonally distorted octahedron. This plane is defined by three donor atoms from a tridentate Schiff base auxiliary (O₂N) and one oxo ligand. A second oxo ligand and an O donor atom of an ethanol molecule are located in axial positions of the coordination polyhedron. The absolute configuration at Mo is C. There are two molecules in the asymmetric unit.

Online 11 January 2006

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