Acta Cryst. (2006). E62, m237-m238  [ doi:10.1107/S1600536806000298 ]

Bis(-methyl mercaptoacetato-²S:S)bis[tricarbonyliron(I)]

J.-T. Liu, Y.-C. Du, L. Zhang, Y.-J. Mao and Y.-L. Wu

Abstract: In the title compound, [Fe₂(C₃H₅O₂S)₂(CO)₆], the asymmetric unit contains only one-half of the molecule and the central [Fe₂S₂] fragment possesses a butterfly form on a twofold rotation axis. Each Fe atom is in a distorted tetragonal-pyramidal geometry and both C atoms bonded to sulfur are in equatorial positions.

Online 11 January 2006

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