Acta Cryst. (2006). E62, m347-m349  [ doi:10.1107/S1600536806001887 ]

Bis(-thiophene-2-carbaldehyde thiosemicarbazonato)bis[acetonitrilecopper(I)] bis(tetrafluoroborate)

R. D. Pike, A. B. Wiles and T. A. Tronic

Abstract: The title compound, [Cu₂(C₆H₇N₃S₂)₂(C₂H₃N)₂](BF₄)₂, is a dimer with a central Cu₂S₂ core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and perpendicular to the Cu₂S₂ plane.

Online 25 January 2006

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