Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806000523/wk6072sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806000523/wk6072Isup2.hkl |
CCDC reference: 298562
Key indicators
- Single-crystal X-ray study
- T = 146 K
- Mean (C-C) = 0.006 Å
- R factor = 0.032
- wR factor = 0.082
- Data-to-parameter ratio = 11.8
checkCIF/PLATON results
No syntax errors found
Alert level A PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............ 24.72 Deg.
Author Response: Due to the crystal quality diffraction was observed only out to \Q~max~= 24.72 \% with 0.96 data completeness, but the data were virtually complete up to \Q= 23.0 \%. |
Alert level B PLAT029_ALERT_3_B _diffrn_measured_fraction_theta_full Low ....... 0.96 PLAT222_ALERT_3_B Large Non-Solvent H Ueq(max)/Ueq(min) ... 4.57 Ratio
Alert level C THETM01_ALERT_3_C The value of sine(theta_max)/wavelength is less than 0.590 Calculated sin(theta_max)/wavelength = 0.5884 PLAT023_ALERT_3_C Resolution (too) Low [sin(th)/Lambda < 0.6]..... 24.72 Deg. PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT164_ALERT_4_C Nr. of Refined C-H H-Atoms in Heavy-At Struct... 8 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.21 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C21
1 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 5 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: SMART (Bruker, 1999); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: SHELXL97.
[Rh2(C5H4N)2(C8H12)2] | F(000) = 1232 |
Mr = 610.36 | Dx = 1.747 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
a = 13.9304 (7) Å | Cell parameters from 6511 reflections |
b = 12.0102 (6) Å | θ = 2.2–24.7° |
c = 14.1320 (7) Å | µ = 1.45 mm−1 |
β = 101.015 (1)° | T = 146 K |
V = 2320.8 (2) Å3 | Block, orange-red |
Z = 4 | 0.33 × 0.19 × 0.16 mm |
Bruker SMART 1K CCD diffractometer | 3802 independent reflections |
Radiation source: fine-focus sealed tube | 3334 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.068 |
ω scans | θmax = 24.7°, θmin = 2.2° |
Absorption correction: multi-scan (Blessing, 1995) | h = −16→13 |
Tmin = 0.647, Tmax = 0.801 | k = −13→13 |
10107 measured reflections | l = −15→16 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.032 | Hydrogen site location: geom and difmap |
wR(F2) = 0.082 | H atoms treated by a mixture of independent and constrained refinement |
S = 1.00 | w = 1/[σ2(Fo2) + (0.056P)2] where P = (Fo2 + 2Fc2)/3 |
3802 reflections | (Δ/σ)max = 0.001 |
321 parameters | Δρmax = 0.53 e Å−3 |
0 restraints | Δρmin = −1.29 e Å−3 |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Rh1 | 0.641066 (19) | 0.22054 (2) | 0.927451 (17) | 0.01570 (11) | |
Rh2 | 0.806775 (19) | 0.38377 (2) | 0.834246 (18) | 0.01645 (11) | |
O1 | 0.76655 (18) | 0.2799 (2) | 1.01752 (16) | 0.0210 (6) | |
O2 | 0.73320 (18) | 0.26027 (18) | 0.74591 (15) | 0.0184 (5) | |
N1 | 0.8551 (2) | 0.2423 (2) | 1.0054 (2) | 0.0182 (6) | |
N2 | 0.7456 (2) | 0.1522 (2) | 0.77256 (19) | 0.0154 (6) | |
C1 | 0.5647 (3) | 0.2702 (3) | 1.0428 (3) | 0.0222 (8) | |
H1 | 0.616 (3) | 0.272 (3) | 1.096 (3) | 0.019 (10)* | |
C2 | 0.5552 (3) | 0.3567 (3) | 0.9758 (2) | 0.0217 (8) | |
H2 | 0.608 (3) | 0.409 (3) | 0.990 (3) | 0.023 (10)* | |
C3 | 0.4624 (3) | 0.3799 (3) | 0.9025 (3) | 0.0267 (9) | |
H3A | 0.4559 | 0.4612 | 0.8915 | 0.032* | |
H3B | 0.4052 | 0.3545 | 0.9289 | 0.032* | |
C4 | 0.4621 (3) | 0.3210 (3) | 0.8054 (2) | 0.0248 (8) | |
H4A | 0.3936 | 0.3048 | 0.7744 | 0.030* | |
H4B | 0.4895 | 0.3723 | 0.7626 | 0.030* | |
C5 | 0.5197 (3) | 0.2138 (3) | 0.8146 (2) | 0.0206 (8) | |
H5 | 0.543 (3) | 0.191 (3) | 0.756 (3) | 0.022 (10)* | |
C6 | 0.5117 (3) | 0.1291 (3) | 0.8815 (2) | 0.0197 (8) | |
H6 | 0.533 (3) | 0.056 (4) | 0.870 (3) | 0.041 (12)* | |
C7 | 0.4411 (3) | 0.1335 (3) | 0.9509 (3) | 0.0242 (8) | |
H7A | 0.4185 | 0.0571 | 0.9612 | 0.029* | |
H7B | 0.3832 | 0.1781 | 0.9218 | 0.029* | |
C8 | 0.4877 (3) | 0.1847 (3) | 1.0491 (2) | 0.0260 (8) | |
H8A | 0.4356 | 0.2197 | 1.0778 | 0.031* | |
H8B | 0.5171 | 0.1243 | 1.0929 | 0.031* | |
C9 | 0.7135 (3) | 0.1158 (3) | 0.8533 (2) | 0.0166 (7) | |
C10 | 0.7295 (3) | 0.0022 (3) | 0.8730 (2) | 0.0205 (8) | |
H10 | 0.7099 | −0.0282 | 0.9284 | 0.025* | |
C11 | 0.7725 (3) | −0.0675 (3) | 0.8152 (3) | 0.0228 (8) | |
H11 | 0.7837 | −0.1437 | 0.8317 | 0.027* | |
C12 | 0.7992 (3) | −0.0247 (3) | 0.7328 (3) | 0.0249 (8) | |
H12 | 0.8271 | −0.0717 | 0.6912 | 0.030* | |
C13 | 0.7848 (3) | 0.0857 (3) | 0.7123 (2) | 0.0204 (8) | |
H13 | 0.8022 | 0.1160 | 0.6558 | 0.024* | |
C14 | 0.9029 (3) | 0.1763 (3) | 1.0759 (2) | 0.0225 (8) | |
H14 | 0.8742 | 0.1590 | 1.1299 | 0.027* | |
C15 | 0.9923 (3) | 0.1341 (3) | 1.0701 (3) | 0.0260 (9) | |
H15 | 1.0258 | 0.0861 | 1.1189 | 0.031* | |
C16 | 1.0337 (3) | 0.1626 (3) | 0.9913 (3) | 0.0251 (8) | |
H16 | 1.0961 | 0.1345 | 0.9855 | 0.030* | |
C17 | 0.9831 (3) | 0.2319 (3) | 0.9217 (2) | 0.0212 (8) | |
H17 | 1.0120 | 0.2509 | 0.8682 | 0.025* | |
C18 | 0.8902 (3) | 0.2764 (3) | 0.9263 (2) | 0.0178 (8) | |
C19 | 0.8464 (3) | 0.5092 (3) | 0.9363 (3) | 0.0262 (8) | |
H19 | 0.871 (3) | 0.478 (3) | 1.000 (3) | 0.015 (9)* | |
C20 | 0.9099 (3) | 0.5111 (3) | 0.8701 (3) | 0.0283 (9) | |
H20 | 0.969 (3) | 0.480 (3) | 0.887 (3) | 0.019 (9)* | |
C21 | 0.9060 (4) | 0.5978 (4) | 0.7926 (3) | 0.0534 (14) | |
H21A | 0.8959 | 0.6714 | 0.8207 | 0.064* | |
H21B | 0.9703 | 0.5996 | 0.7726 | 0.064* | |
C22 | 0.8298 (4) | 0.5816 (4) | 0.7063 (3) | 0.0467 (12) | |
H22A | 0.8620 | 0.5603 | 0.6523 | 0.056* | |
H22B | 0.7969 | 0.6539 | 0.6894 | 0.056* | |
C23 | 0.7526 (3) | 0.4959 (3) | 0.7138 (3) | 0.0255 (8) | |
H23 | 0.737 (3) | 0.451 (3) | 0.664 (3) | 0.028 (11)* | |
C24 | 0.6908 (3) | 0.5014 (3) | 0.7777 (3) | 0.0246 (8) | |
H24 | 0.633 (3) | 0.454 (3) | 0.772 (2) | 0.014 (9)* | |
C25 | 0.6883 (4) | 0.5949 (4) | 0.8484 (3) | 0.0437 (12) | |
H25A | 0.6947 | 0.6663 | 0.8153 | 0.052* | |
H25B | 0.6235 | 0.5947 | 0.8674 | 0.052* | |
C26 | 0.7645 (3) | 0.5907 (4) | 0.9370 (4) | 0.0478 (13) | |
H26A | 0.7326 | 0.5722 | 0.9919 | 0.057* | |
H26B | 0.7932 | 0.6660 | 0.9489 | 0.057* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Rh1 | 0.01333 (17) | 0.02128 (18) | 0.01199 (16) | 0.00158 (10) | 0.00117 (11) | −0.00191 (10) |
Rh2 | 0.01531 (17) | 0.01777 (18) | 0.01507 (17) | 0.00113 (10) | −0.00015 (12) | −0.00025 (10) |
O1 | 0.0141 (13) | 0.0321 (15) | 0.0163 (12) | 0.0023 (10) | 0.0016 (10) | −0.0030 (10) |
O2 | 0.0229 (14) | 0.0164 (12) | 0.0145 (12) | 0.0024 (10) | 0.0000 (10) | 0.0011 (10) |
N1 | 0.0113 (15) | 0.0219 (15) | 0.0206 (15) | 0.0012 (12) | 0.0009 (12) | −0.0029 (12) |
N2 | 0.0160 (15) | 0.0164 (15) | 0.0126 (14) | −0.0009 (12) | −0.0005 (11) | −0.0010 (11) |
C1 | 0.020 (2) | 0.030 (2) | 0.0165 (18) | 0.0025 (16) | 0.0045 (16) | −0.0093 (15) |
C2 | 0.022 (2) | 0.024 (2) | 0.0188 (19) | 0.0007 (16) | 0.0034 (15) | −0.0063 (15) |
C3 | 0.026 (2) | 0.025 (2) | 0.030 (2) | 0.0066 (16) | 0.0073 (17) | −0.0051 (16) |
C4 | 0.022 (2) | 0.030 (2) | 0.0203 (18) | 0.0040 (16) | −0.0017 (15) | 0.0008 (16) |
C5 | 0.0152 (19) | 0.029 (2) | 0.0158 (18) | 0.0028 (15) | −0.0008 (15) | −0.0066 (15) |
C6 | 0.0165 (19) | 0.024 (2) | 0.0186 (18) | −0.0033 (15) | 0.0025 (15) | −0.0057 (15) |
C7 | 0.019 (2) | 0.032 (2) | 0.0220 (19) | −0.0002 (16) | 0.0042 (15) | −0.0014 (15) |
C8 | 0.026 (2) | 0.034 (2) | 0.0198 (19) | 0.0002 (17) | 0.0063 (16) | −0.0034 (16) |
C9 | 0.0129 (18) | 0.0209 (19) | 0.0146 (17) | −0.0027 (14) | −0.0005 (14) | 0.0000 (13) |
C10 | 0.0166 (18) | 0.0254 (19) | 0.0186 (17) | 0.0019 (15) | 0.0007 (14) | 0.0046 (15) |
C11 | 0.0183 (19) | 0.0187 (19) | 0.029 (2) | −0.0002 (15) | −0.0017 (15) | −0.0009 (15) |
C12 | 0.022 (2) | 0.028 (2) | 0.0241 (19) | 0.0056 (16) | 0.0037 (15) | −0.0070 (16) |
C13 | 0.0207 (19) | 0.027 (2) | 0.0138 (17) | 0.0017 (15) | 0.0042 (14) | −0.0030 (15) |
C14 | 0.021 (2) | 0.028 (2) | 0.0168 (17) | −0.0035 (16) | −0.0021 (14) | 0.0015 (15) |
C15 | 0.025 (2) | 0.0242 (19) | 0.026 (2) | 0.0033 (16) | −0.0024 (16) | 0.0077 (16) |
C16 | 0.0152 (19) | 0.030 (2) | 0.029 (2) | 0.0085 (16) | 0.0003 (15) | −0.0012 (16) |
C17 | 0.0181 (19) | 0.028 (2) | 0.0175 (18) | 0.0015 (15) | 0.0036 (15) | −0.0018 (15) |
C18 | 0.0197 (19) | 0.0169 (18) | 0.0161 (17) | −0.0035 (14) | 0.0016 (15) | −0.0029 (13) |
C19 | 0.028 (2) | 0.025 (2) | 0.0229 (19) | −0.0015 (17) | −0.0024 (16) | −0.0076 (16) |
C20 | 0.017 (2) | 0.031 (2) | 0.034 (2) | −0.0010 (17) | −0.0016 (17) | −0.0020 (17) |
C21 | 0.049 (3) | 0.056 (3) | 0.050 (3) | −0.031 (3) | −0.003 (2) | 0.012 (2) |
C22 | 0.043 (3) | 0.047 (3) | 0.049 (3) | −0.011 (2) | 0.005 (2) | 0.023 (2) |
C23 | 0.030 (2) | 0.023 (2) | 0.023 (2) | 0.0009 (17) | 0.0020 (17) | 0.0053 (17) |
C24 | 0.021 (2) | 0.026 (2) | 0.025 (2) | 0.0069 (17) | 0.0017 (16) | 0.0055 (16) |
C25 | 0.045 (3) | 0.046 (3) | 0.037 (2) | 0.025 (2) | 0.000 (2) | −0.007 (2) |
C26 | 0.033 (3) | 0.049 (3) | 0.057 (3) | 0.006 (2) | −0.003 (2) | −0.030 (2) |
Rh1—Rh2 | 3.4740 (4) | C8—H8B | 0.9900 |
Rh1—C9 | 2.026 (3) | C9—C10 | 1.401 (5) |
Rh1—O1 | 2.082 (2) | C10—C11 | 1.384 (5) |
Rh1—C5 | 2.093 (3) | C10—H10 | 0.9500 |
Rh1—C6 | 2.104 (4) | C11—C12 | 1.387 (5) |
Rh1—C1 | 2.192 (3) | C11—H11 | 0.9500 |
Rh1—C2 | 2.210 (4) | C12—C13 | 1.364 (5) |
Rh2—C18 | 2.032 (3) | C12—H12 | 0.9500 |
Rh2—O2 | 2.078 (2) | C13—H13 | 0.9500 |
Rh2—C19 | 2.086 (4) | C14—C15 | 1.362 (5) |
Rh2—C20 | 2.093 (4) | C14—H14 | 0.9500 |
Rh2—C24 | 2.180 (4) | C15—C16 | 1.391 (5) |
Rh2—C23 | 2.188 (4) | C15—H15 | 0.9500 |
O1—N1 | 1.354 (4) | C16—C17 | 1.375 (5) |
O2—N2 | 1.353 (3) | C16—H16 | 0.9500 |
N1—C14 | 1.345 (5) | C17—C18 | 1.413 (5) |
N1—C18 | 1.366 (5) | C17—H17 | 0.9500 |
N2—C13 | 1.356 (4) | C19—C20 | 1.406 (6) |
N2—C9 | 1.374 (4) | C19—C26 | 1.503 (6) |
C1—C2 | 1.395 (5) | C19—H19 | 0.98 (3) |
C1—C8 | 1.501 (5) | C20—C21 | 1.504 (6) |
C1—H1 | 0.93 (4) | C20—H20 | 0.90 (4) |
C2—C3 | 1.520 (5) | C21—C22 | 1.469 (6) |
C2—H2 | 0.96 (4) | C21—H21A | 0.9900 |
C3—C4 | 1.543 (5) | C21—H21B | 0.9900 |
C3—H3A | 0.9900 | C22—C23 | 1.507 (6) |
C3—H3B | 0.9900 | C22—H22A | 0.9900 |
C4—C5 | 1.510 (5) | C22—H22B | 0.9900 |
C4—H4A | 0.9900 | C23—C24 | 1.363 (5) |
C4—H4B | 0.9900 | C23—H23 | 0.89 (4) |
C5—C6 | 1.408 (5) | C24—C25 | 1.509 (6) |
C5—H5 | 0.98 (4) | C24—H24 | 0.98 (4) |
C6—C7 | 1.516 (5) | C25—C26 | 1.479 (6) |
C6—H6 | 0.95 (5) | C25—H25A | 0.9900 |
C7—C8 | 1.544 (5) | C25—H25B | 0.9900 |
C7—H7A | 0.9900 | C26—H26A | 0.9900 |
C7—H7B | 0.9900 | C26—H26B | 0.9900 |
C8—H8A | 0.9900 | ||
C9—Rh1—O1 | 94.94 (12) | C7—C8—H8A | 108.8 |
C9—Rh1—C5 | 89.50 (14) | C1—C8—H8B | 108.8 |
O1—Rh1—C5 | 160.22 (12) | C7—C8—H8B | 108.8 |
C9—Rh1—C6 | 89.89 (14) | H8A—C8—H8B | 107.7 |
O1—Rh1—C6 | 159.56 (12) | N2—C9—C10 | 114.3 (3) |
C5—Rh1—C6 | 39.19 (14) | N2—C9—Rh1 | 120.3 (2) |
C9—Rh1—C1 | 156.07 (14) | C10—C9—Rh1 | 125.3 (3) |
O1—Rh1—C1 | 85.53 (12) | C11—C10—C9 | 122.8 (3) |
C5—Rh1—C1 | 98.12 (14) | C11—C10—H10 | 118.6 |
C6—Rh1—C1 | 82.12 (14) | C9—C10—H10 | 118.6 |
C9—Rh1—C2 | 166.41 (13) | C10—C11—C12 | 119.2 (3) |
O1—Rh1—C2 | 89.91 (12) | C10—C11—H11 | 120.4 |
C5—Rh1—C2 | 81.83 (14) | C12—C11—H11 | 120.4 |
C6—Rh1—C2 | 89.95 (15) | C13—C12—C11 | 119.1 (3) |
C1—Rh1—C2 | 36.94 (14) | C13—C12—H12 | 120.5 |
C18—Rh2—O2 | 95.01 (11) | C11—C12—H12 | 120.5 |
C18—Rh2—C19 | 88.45 (14) | N2—C13—C12 | 120.0 (3) |
O2—Rh2—C19 | 164.95 (13) | N2—C13—H13 | 120.0 |
C18—Rh2—C20 | 91.54 (15) | C12—C13—H13 | 120.0 |
O2—Rh2—C20 | 154.63 (13) | N1—C14—C15 | 120.3 (3) |
C19—Rh2—C20 | 39.32 (16) | N1—C14—H14 | 119.9 |
C18—Rh2—C24 | 159.93 (14) | C15—C14—H14 | 119.9 |
O2—Rh2—C24 | 89.79 (12) | C14—C15—C16 | 118.7 (3) |
C19—Rh2—C24 | 82.23 (15) | C14—C15—H15 | 120.6 |
C20—Rh2—C24 | 92.40 (16) | C16—C15—H15 | 120.6 |
C18—Rh2—C23 | 163.48 (15) | C17—C16—C15 | 119.2 (3) |
O2—Rh2—C23 | 85.11 (12) | C17—C16—H16 | 120.4 |
C19—Rh2—C23 | 95.71 (15) | C15—C16—H16 | 120.4 |
C20—Rh2—C23 | 81.81 (15) | C16—C17—C18 | 123.0 (3) |
C24—Rh2—C23 | 36.35 (14) | C16—C17—H17 | 118.5 |
N1—O1—Rh1 | 119.14 (19) | C18—C17—H17 | 118.5 |
N2—O2—Rh2 | 119.68 (18) | N1—C18—C17 | 113.5 (3) |
C14—N1—O1 | 115.9 (3) | N1—C18—Rh2 | 117.7 (2) |
C14—N1—C18 | 125.3 (3) | C17—C18—Rh2 | 128.9 (3) |
O1—N1—C18 | 118.7 (3) | C20—C19—C26 | 124.7 (4) |
O2—N2—C13 | 115.8 (3) | C20—C19—Rh2 | 70.6 (2) |
O2—N2—C9 | 119.5 (3) | C26—C19—Rh2 | 111.9 (3) |
C13—N2—C9 | 124.6 (3) | C20—C19—H19 | 118 (2) |
C2—C1—C8 | 125.0 (3) | C26—C19—H19 | 112 (2) |
C2—C1—Rh1 | 72.2 (2) | Rh2—C19—H19 | 111 (2) |
C8—C1—Rh1 | 108.2 (2) | C19—C20—C21 | 123.7 (4) |
C2—C1—H1 | 119 (2) | C19—C20—Rh2 | 70.1 (2) |
C8—C1—H1 | 115 (2) | C21—C20—Rh2 | 113.7 (3) |
Rh1—C1—H1 | 101 (2) | C19—C20—H20 | 119 (2) |
C1—C2—C3 | 123.9 (4) | C21—C20—H20 | 113 (2) |
C1—C2—Rh1 | 70.8 (2) | Rh2—C20—H20 | 108 (2) |
C3—C2—Rh1 | 111.4 (2) | C22—C21—C20 | 115.6 (4) |
C1—C2—H2 | 112 (2) | C22—C21—H21A | 108.4 |
C3—C2—H2 | 123 (2) | C20—C21—H21A | 108.4 |
Rh1—C2—H2 | 96 (2) | C22—C21—H21B | 108.4 |
C2—C3—C4 | 112.3 (3) | C20—C21—H21B | 108.4 |
C2—C3—H3A | 109.1 | H21A—C21—H21B | 107.4 |
C4—C3—H3A | 109.1 | C21—C22—C23 | 116.3 (4) |
C2—C3—H3B | 109.1 | C21—C22—H22A | 108.2 |
C4—C3—H3B | 109.1 | C23—C22—H22A | 108.2 |
H3A—C3—H3B | 107.9 | C21—C22—H22B | 108.2 |
C5—C4—C3 | 113.8 (3) | C23—C22—H22B | 108.2 |
C5—C4—H4A | 108.8 | H22A—C22—H22B | 107.4 |
C3—C4—H4A | 108.8 | C24—C23—C22 | 124.3 (4) |
C5—C4—H4B | 108.8 | C24—C23—Rh2 | 71.5 (2) |
C3—C4—H4B | 108.8 | C22—C23—Rh2 | 109.3 (3) |
H4A—C4—H4B | 107.7 | C24—C23—H23 | 118 (3) |
C6—C5—C4 | 124.4 (3) | C22—C23—H23 | 115 (3) |
C6—C5—Rh1 | 70.9 (2) | Rh2—C23—H23 | 104 (3) |
C4—C5—Rh1 | 111.8 (2) | C23—C24—C25 | 124.9 (4) |
C6—C5—H5 | 117 (2) | C23—C24—Rh2 | 72.1 (2) |
C4—C5—H5 | 115 (2) | C25—C24—Rh2 | 110.4 (3) |
Rh1—C5—H5 | 107 (2) | C23—C24—H24 | 122 (2) |
C5—C6—C7 | 123.7 (3) | C25—C24—H24 | 112 (2) |
C5—C6—Rh1 | 70.0 (2) | Rh2—C24—H24 | 101 (2) |
C7—C6—Rh1 | 113.9 (2) | C26—C25—C24 | 115.6 (4) |
C5—C6—H6 | 119 (3) | C26—C25—H25A | 108.4 |
C7—C6—H6 | 114 (3) | C24—C25—H25A | 108.4 |
Rh1—C6—H6 | 105 (3) | C26—C25—H25B | 108.4 |
C6—C7—C8 | 112.5 (3) | C24—C25—H25B | 108.4 |
C6—C7—H7A | 109.1 | H25A—C25—H25B | 107.5 |
C8—C7—H7A | 109.1 | C25—C26—C19 | 116.1 (4) |
C6—C7—H7B | 109.1 | C25—C26—H26A | 108.3 |
C8—C7—H7B | 109.1 | C19—C26—H26A | 108.3 |
H7A—C7—H7B | 107.8 | C25—C26—H26B | 108.3 |
C1—C8—C7 | 113.6 (3) | C19—C26—H26B | 108.3 |
C1—C8—H8A | 108.8 | H26A—C26—H26B | 107.4 |
C9—Rh1—O1—N1 | 1.6 (2) | N2—C9—C10—C11 | −1.0 (5) |
C5—Rh1—O1—N1 | −100.8 (4) | Rh1—C9—C10—C11 | 174.6 (3) |
C6—Rh1—O1—N1 | 104.7 (4) | C9—C10—C11—C12 | −1.6 (5) |
C1—Rh1—O1—N1 | 157.6 (2) | C10—C11—C12—C13 | 1.8 (5) |
C2—Rh1—O1—N1 | −165.7 (2) | O2—N2—C13—C12 | −179.4 (3) |
C18—Rh2—O2—N2 | 7.8 (2) | C9—N2—C13—C12 | −3.4 (5) |
C19—Rh2—O2—N2 | −94.9 (5) | C11—C12—C13—N2 | 0.5 (5) |
C20—Rh2—O2—N2 | 112.2 (3) | O1—N1—C14—C15 | 179.8 (3) |
C24—Rh2—O2—N2 | −152.6 (2) | C18—N1—C14—C15 | −2.6 (5) |
C23—Rh2—O2—N2 | 171.3 (2) | N1—C14—C15—C16 | 1.4 (6) |
Rh1—O1—N1—C14 | −110.7 (3) | C14—C15—C16—C17 | −0.2 (6) |
Rh1—O1—N1—C18 | 71.6 (3) | C15—C16—C17—C18 | 0.0 (6) |
Rh2—O2—N2—C13 | −118.3 (3) | C14—N1—C18—C17 | 2.3 (5) |
Rh2—O2—N2—C9 | 65.5 (3) | O1—N1—C18—C17 | 179.8 (3) |
C9—Rh1—C1—C2 | −172.1 (3) | C14—N1—C18—Rh2 | −176.4 (3) |
O1—Rh1—C1—C2 | 95.8 (2) | O1—N1—C18—Rh2 | 1.1 (4) |
C5—Rh1—C1—C2 | −64.6 (2) | C16—C17—C18—N1 | −1.0 (5) |
C6—Rh1—C1—C2 | −100.5 (2) | C16—C17—C18—Rh2 | 177.5 (3) |
C9—Rh1—C1—C8 | −50.1 (5) | O2—Rh2—C18—N1 | −91.6 (3) |
O1—Rh1—C1—C8 | −142.3 (3) | C19—Rh2—C18—N1 | 73.7 (3) |
C5—Rh1—C1—C8 | 57.3 (3) | C20—Rh2—C18—N1 | 112.9 (3) |
C6—Rh1—C1—C8 | 21.4 (3) | C24—Rh2—C18—N1 | 11.6 (6) |
C2—Rh1—C1—C8 | 121.9 (4) | C23—Rh2—C18—N1 | 178.7 (4) |
C8—C1—C2—C3 | 3.2 (6) | O2—Rh2—C18—C17 | 90.0 (3) |
Rh1—C1—C2—C3 | 103.4 (3) | C19—Rh2—C18—C17 | −104.7 (3) |
C8—C1—C2—Rh1 | −100.2 (3) | C20—Rh2—C18—C17 | −65.5 (3) |
C9—Rh1—C2—C1 | 166.2 (5) | C24—Rh2—C18—C17 | −166.8 (4) |
O1—Rh1—C2—C1 | −82.7 (2) | C23—Rh2—C18—C17 | 0.3 (7) |
C5—Rh1—C2—C1 | 115.4 (2) | C18—Rh2—C19—C20 | 94.3 (2) |
C6—Rh1—C2—C1 | 76.9 (2) | O2—Rh2—C19—C20 | −162.0 (4) |
C9—Rh1—C2—C3 | 46.4 (7) | C24—Rh2—C19—C20 | −103.5 (3) |
O1—Rh1—C2—C3 | 157.5 (3) | C23—Rh2—C19—C20 | −69.6 (3) |
C5—Rh1—C2—C3 | −4.5 (3) | C18—Rh2—C19—C26 | −145.1 (3) |
C6—Rh1—C2—C3 | −42.9 (3) | O2—Rh2—C19—C26 | −41.5 (7) |
C1—Rh1—C2—C3 | −119.8 (4) | C20—Rh2—C19—C26 | 120.6 (4) |
C1—C2—C3—C4 | −92.6 (4) | C24—Rh2—C19—C26 | 17.1 (3) |
Rh1—C2—C3—C4 | −11.9 (4) | C23—Rh2—C19—C26 | 50.9 (3) |
C2—C3—C4—C5 | 29.5 (5) | C26—C19—C20—C21 | 2.0 (6) |
C3—C4—C5—C6 | 47.8 (5) | Rh2—C19—C20—C21 | 105.8 (4) |
C3—C4—C5—Rh1 | −33.3 (4) | C26—C19—C20—Rh2 | −103.8 (4) |
C9—Rh1—C5—C6 | 90.4 (2) | C18—Rh2—C20—C19 | −85.7 (2) |
O1—Rh1—C5—C6 | −166.2 (3) | O2—Rh2—C20—C19 | 169.2 (2) |
C1—Rh1—C5—C6 | −66.8 (2) | C24—Rh2—C20—C19 | 74.7 (2) |
C2—Rh1—C5—C6 | −100.0 (2) | C23—Rh2—C20—C19 | 109.5 (3) |
C9—Rh1—C5—C4 | −149.2 (3) | C18—Rh2—C20—C21 | 155.3 (4) |
O1—Rh1—C5—C4 | −45.9 (5) | O2—Rh2—C20—C21 | 50.2 (5) |
C6—Rh1—C5—C4 | 120.3 (4) | C19—Rh2—C20—C21 | −119.1 (5) |
C1—Rh1—C5—C4 | 53.5 (3) | C24—Rh2—C20—C21 | −44.4 (4) |
C2—Rh1—C5—C4 | 20.3 (3) | C23—Rh2—C20—C21 | −9.5 (4) |
C4—C5—C6—C7 | 2.1 (6) | C19—C20—C21—C22 | −79.5 (6) |
Rh1—C5—C6—C7 | 106.0 (3) | Rh2—C20—C21—C22 | 1.6 (6) |
C4—C5—C6—Rh1 | −103.8 (3) | C20—C21—C22—C23 | 12.3 (7) |
C9—Rh1—C6—C5 | −89.3 (2) | C21—C22—C23—C24 | 61.0 (7) |
O1—Rh1—C6—C5 | 166.7 (3) | C21—C22—C23—Rh2 | −19.3 (6) |
C1—Rh1—C6—C5 | 113.3 (2) | C18—Rh2—C23—C24 | −172.6 (4) |
C2—Rh1—C6—C5 | 77.1 (2) | O2—Rh2—C23—C24 | 96.3 (2) |
C9—Rh1—C6—C7 | 151.8 (3) | C19—Rh2—C23—C24 | −68.6 (3) |
O1—Rh1—C6—C7 | 47.8 (5) | C20—Rh2—C23—C24 | −105.5 (3) |
C5—Rh1—C6—C7 | −118.9 (4) | C18—Rh2—C23—C22 | −51.7 (6) |
C1—Rh1—C6—C7 | −5.6 (3) | O2—Rh2—C23—C22 | −142.9 (3) |
C2—Rh1—C6—C7 | −41.8 (3) | C19—Rh2—C23—C22 | 52.2 (3) |
C5—C6—C7—C8 | −92.3 (4) | C20—Rh2—C23—C22 | 15.3 (3) |
Rh1—C6—C7—C8 | −11.2 (4) | C24—Rh2—C23—C22 | 120.8 (4) |
C2—C1—C8—C7 | 46.9 (5) | C22—C23—C24—C25 | 1.7 (6) |
Rh1—C1—C8—C7 | −33.9 (4) | Rh2—C23—C24—C25 | 102.8 (4) |
C6—C7—C8—C1 | 30.6 (5) | C22—C23—C24—Rh2 | −101.2 (4) |
O2—N2—C9—C10 | 179.4 (3) | C18—Rh2—C24—C23 | 173.8 (3) |
C13—N2—C9—C10 | 3.5 (5) | O2—Rh2—C24—C23 | −82.0 (2) |
O2—N2—C9—Rh1 | 3.6 (4) | C19—Rh2—C24—C23 | 110.8 (3) |
C13—N2—C9—Rh1 | −172.3 (3) | C20—Rh2—C24—C23 | 72.7 (3) |
O1—Rh1—C9—N2 | −89.1 (3) | C18—Rh2—C24—C25 | 52.4 (6) |
C5—Rh1—C9—N2 | 71.6 (3) | O2—Rh2—C24—C25 | 156.5 (3) |
C6—Rh1—C9—N2 | 110.8 (3) | C19—Rh2—C24—C25 | −10.7 (3) |
C1—Rh1—C9—N2 | −179.2 (3) | C20—Rh2—C24—C25 | −48.8 (3) |
C2—Rh1—C9—N2 | 21.5 (7) | C23—Rh2—C24—C25 | −121.5 (4) |
O1—Rh1—C9—C10 | 95.6 (3) | C23—C24—C25—C26 | −79.8 (6) |
C5—Rh1—C9—C10 | −103.7 (3) | Rh2—C24—C25—C26 | 2.2 (6) |
C6—Rh1—C9—C10 | −64.5 (3) | C24—C25—C26—C19 | 12.3 (7) |
C1—Rh1—C9—C10 | 5.4 (5) | C20—C19—C26—C25 | 59.7 (6) |
C2—Rh1—C9—C10 | −153.9 (5) | Rh2—C19—C26—C25 | −21.2 (6) |