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In the structure of the title complex, [PtCl(C18H15P)3]ClO4·2CH2Cl2, the coordination polyhedron with platinum as the central atom has a distorted square-planar geometry formed by three P atoms from three triphenyl­phosphine ligands and one Cl atom.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806001826/wk6073sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806001826/wk6073Isup2.hkl
Contains datablock I

CCDC reference: 298563

Key indicators

  • Single-crystal X-ray study
  • T = 303 K
  • Mean [sigma](C-C) = 0.018 Å
  • Disorder in solvent or counterion
  • R factor = 0.065
  • wR factor = 0.180
  • Data-to-parameter ratio = 17.1

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 4.09 Ratio
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT150_ALERT_1_C Volume as Calculated Differs from that Given ... 5586.00 Ang-3 PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.04 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C5 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C10 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C16 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C7 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for Cl2 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for C55 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for C56 PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 47.00 Perc. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 18 PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 26.90 Deg. O4' -CL2 -O4 1.555 1.555 1.555 PLAT779_ALERT_2_C Suspect or Irrelevant (Bond) Angle in CIF ...... 41.00 Deg. O1 -CL2 -O3' 1.555 1.555 1.555
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 15 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 7 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1998); cell refinement: SMART (Bruker, 1998); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

Chlorotris(triphenylphosphine)platinum(II) perchlorate dichloromethane disolvate top
Crystal data top
[PtCl(C18H15P)3](ClO4)·2CH2Cl2F(000) = 2400
Mr = 1201.73Dx = 1.429 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
a = 17.889 (5) ÅCell parameters from 992 reflections
b = 12.323 (3) Åθ = 2.9–24.7°
c = 26.217 (9) ŵ = 2.83 mm1
β = 104.848 (12)°T = 303 K
V = 5586 (3) Å3Block, colorless
Z = 40.24 × 0.20 × 0.10 mm
Data collection top
Bruker SMART APEX-II CCD area-detector
diffractometer
11417 independent reflections
Radiation source: fine-focus sealed tube7366 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.072
φ and ω scansθmax = 26.5°, θmin = 1.2°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 2220
Tmin = 0.493, Tmax = 0.753k = 1515
28838 measured reflectionsl = 3226
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.065Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.180H-atom parameters constrained
S = 1.09 w = 1/[σ2(Fo2) + (0.0887P)2]
where P = (Fo2 + 2Fc2)/3
11417 reflections(Δ/σ)max = 0.006
669 parametersΔρmax = 1.46 e Å3
164 restraintsΔρmin = 1.03 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pt10.705751 (18)0.70379 (3)0.384905 (15)0.03302 (13)
Cl10.58334 (13)0.7618 (2)0.33447 (12)0.0575 (8)
P10.75095 (13)0.85494 (19)0.34633 (11)0.0364 (6)
P20.63154 (12)0.59179 (19)0.42660 (10)0.0337 (5)
P30.82088 (12)0.62386 (18)0.42224 (10)0.0305 (5)
C10.7541 (5)0.8281 (8)0.2796 (4)0.043 (2)
C20.7342 (6)0.7259 (9)0.2591 (5)0.055 (3)
H20.71800.67260.27890.066*
C30.7392 (7)0.7042 (12)0.2067 (5)0.076 (4)
H30.72630.63530.19280.091*
C40.7618 (8)0.7793 (15)0.1763 (6)0.088 (5)
H40.76400.76380.14200.105*
C50.7810 (8)0.8779 (15)0.1980 (7)0.094 (5)
H50.79850.93030.17820.113*
C60.7760 (6)0.9046 (10)0.2480 (5)0.062 (3)
H60.78740.97480.26060.075*
C70.6854 (5)0.9681 (8)0.3461 (5)0.046 (3)
C80.6568 (6)1.0307 (9)0.3025 (6)0.064 (3)
H80.66821.01380.27080.077*
C90.6095 (9)1.1217 (12)0.3060 (9)0.103 (6)
H90.58751.16360.27640.124*
C100.5976 (11)1.1454 (15)0.3539 (11)0.132 (9)
H100.56811.20630.35640.158*
C110.6257 (11)1.0866 (15)0.3979 (9)0.126 (7)
H110.61651.10710.42990.152*
C120.6684 (8)0.9954 (11)0.3942 (6)0.090 (5)
H120.68620.95150.42370.108*
C130.8435 (5)0.9194 (7)0.3777 (4)0.040 (2)
C140.9026 (6)0.9274 (9)0.3545 (5)0.060 (3)
H140.89750.89210.32240.072*
C150.9702 (8)0.9844 (12)0.3752 (7)0.081 (4)
H151.00970.98760.35800.097*
C160.9757 (10)1.0349 (12)0.4214 (9)0.113 (8)
H161.01931.07680.43570.136*
C170.9186 (9)1.0269 (10)0.4488 (7)0.089 (5)
H170.92481.06040.48150.106*
C180.8520 (7)0.9676 (9)0.4263 (5)0.063 (3)
H180.81330.96060.44390.075*
C190.5785 (5)0.6891 (7)0.4551 (4)0.040 (2)
C200.6198 (6)0.7733 (9)0.4868 (5)0.057 (3)
H200.67320.77720.49240.069*
C210.5830 (7)0.8481 (10)0.5092 (6)0.075 (4)
H210.61170.90190.53030.090*
C220.5024 (8)0.8466 (9)0.5013 (6)0.079 (4)
H220.47760.89990.51600.095*
C230.4601 (6)0.7636 (10)0.4709 (6)0.068 (4)
H230.40670.76030.46550.082*
C240.4986 (6)0.6853 (9)0.4485 (5)0.054 (3)
H240.47030.62940.42870.065*
C250.5624 (4)0.5007 (7)0.3847 (4)0.032 (2)
C260.5511 (5)0.4954 (9)0.3309 (4)0.050 (3)
H260.57990.54060.31490.060*
C270.4980 (6)0.4248 (11)0.2995 (5)0.066 (3)
H270.49340.41960.26340.079*
C280.4528 (7)0.3634 (10)0.3233 (6)0.076 (4)
H280.41570.31800.30250.091*
C290.4604 (6)0.3662 (9)0.3773 (6)0.066 (4)
H290.42940.32370.39290.079*
C300.5168 (5)0.4359 (8)0.4074 (5)0.052 (3)
H300.52360.43860.44380.063*
C310.6754 (5)0.5016 (7)0.4815 (4)0.037 (2)
C320.6820 (6)0.5292 (10)0.5334 (5)0.058 (3)
H320.66560.59740.54120.070*
C330.7128 (8)0.4573 (12)0.5747 (5)0.077 (4)
H330.71670.47690.60950.092*
C340.7376 (7)0.3561 (12)0.5626 (6)0.076 (4)
H340.75850.30770.58980.092*
C350.7319 (6)0.3257 (9)0.5111 (5)0.056 (3)
H350.74840.25760.50330.067*
C360.7007 (5)0.4001 (8)0.4709 (4)0.049 (3)
H360.69690.38070.43610.059*
C370.8484 (4)0.6283 (7)0.4938 (4)0.033 (2)
C380.8437 (6)0.7263 (8)0.5163 (4)0.050 (3)
H380.82240.78480.49510.059*
C390.8703 (6)0.7407 (10)0.5708 (5)0.057 (3)
H390.86620.80830.58560.068*
C400.9019 (6)0.6566 (11)0.6022 (5)0.064 (3)
H400.92090.66630.63840.076*
C410.9057 (6)0.5546 (11)0.5793 (5)0.066 (3)
H410.92720.49600.60040.079*
C420.8782 (5)0.5412 (8)0.5267 (4)0.047 (3)
H420.87920.47260.51210.057*
C430.8208 (5)0.4837 (7)0.4000 (4)0.038 (2)
C440.7594 (6)0.4419 (8)0.3607 (4)0.049 (3)
H440.71720.48570.34570.059*
C450.7612 (8)0.3335 (10)0.3437 (5)0.071 (4)
H450.71970.30500.31830.085*
C460.8249 (9)0.2703 (9)0.3650 (6)0.078 (4)
H460.82550.19810.35480.094*
C470.8875 (8)0.3121 (9)0.4011 (6)0.073 (4)
H470.93050.26850.41450.088*
C480.8876 (6)0.4180 (8)0.4178 (5)0.050 (3)
H480.93150.44670.44080.060*
C490.9077 (5)0.6728 (7)0.4051 (4)0.035 (2)
C500.9137 (5)0.6541 (8)0.3536 (4)0.046 (3)
H500.87270.62180.32920.055*
C510.9787 (6)0.6825 (9)0.3386 (5)0.060 (3)
H510.98120.67170.30400.072*
C521.0406 (6)0.7272 (10)0.3749 (6)0.064 (4)
H521.08500.74640.36480.077*
C531.0370 (6)0.7433 (10)0.4253 (6)0.066 (4)
H531.07910.77310.44970.080*
C540.9703 (5)0.7153 (8)0.4410 (4)0.044 (2)
H540.96850.72560.47580.052*
Cl20.76737 (18)0.0282 (2)0.57483 (15)0.0695 (9)
O10.7460 (12)0.0716 (13)0.5943 (11)0.114 (11)0.52 (3)
O20.816 (2)0.010 (3)0.5403 (13)0.224 (17)0.52 (3)
O30.807 (2)0.0960 (19)0.6175 (9)0.209 (16)0.52 (3)
O40.6988 (10)0.0832 (18)0.5458 (12)0.148 (14)0.52 (3)
O1'0.7613 (15)0.044 (2)0.5317 (8)0.130 (13)0.48 (3)
O2'0.8273 (11)0.1048 (16)0.5780 (15)0.148 (14)0.48 (3)
O3'0.785 (2)0.034 (2)0.6229 (8)0.186 (15)0.48 (3)
O4'0.6955 (10)0.083 (2)0.5705 (13)0.170 (17)0.48 (3)
C550.8553 (9)0.3530 (12)0.2323 (13)0.135 (12)0.603 (6)
H55A0.83420.37420.19580.162*0.603 (6)
H55B0.82040.37860.25260.162*0.603 (6)
Cl30.9441 (8)0.4112 (10)0.2558 (5)0.218 (6)0.603 (6)
Cl40.8623 (9)0.2141 (10)0.2365 (6)0.228 (6)0.603 (6)
C560.6101 (16)0.3532 (16)0.1610 (7)0.088 (10)0.397 (6)
H56A0.63090.38050.13280.105*0.397 (6)
H56B0.55540.33880.14660.105*0.397 (6)
Cl50.6214 (8)0.4485 (11)0.2094 (6)0.149 (5)0.397 (6)
Cl60.6566 (11)0.2346 (12)0.1853 (8)0.199 (8)0.397 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pt10.02707 (18)0.0332 (2)0.0401 (2)0.00237 (16)0.01106 (13)0.00559 (19)
Cl10.0277 (12)0.0618 (17)0.080 (2)0.0082 (11)0.0077 (12)0.0288 (15)
P10.0347 (12)0.0296 (13)0.0467 (16)0.0026 (10)0.0136 (11)0.0039 (11)
P20.0254 (11)0.0348 (13)0.0418 (15)0.0041 (9)0.0104 (10)0.0035 (11)
P30.0232 (11)0.0267 (12)0.0445 (15)0.0013 (9)0.0137 (10)0.0028 (10)
C10.041 (5)0.043 (6)0.046 (6)0.001 (4)0.013 (5)0.009 (5)
C20.058 (7)0.061 (8)0.050 (7)0.010 (5)0.019 (5)0.003 (6)
C30.078 (9)0.090 (10)0.062 (9)0.001 (7)0.020 (7)0.026 (8)
C40.083 (10)0.127 (15)0.058 (9)0.005 (10)0.026 (7)0.029 (10)
C50.096 (11)0.103 (13)0.096 (13)0.009 (10)0.050 (9)0.034 (11)
C60.069 (8)0.071 (8)0.055 (8)0.001 (6)0.030 (6)0.013 (7)
C70.043 (6)0.032 (5)0.065 (8)0.006 (4)0.019 (5)0.002 (5)
C80.048 (6)0.049 (7)0.094 (10)0.004 (5)0.016 (6)0.015 (7)
C90.096 (12)0.058 (10)0.152 (18)0.016 (8)0.025 (11)0.031 (11)
C100.106 (14)0.071 (12)0.23 (3)0.040 (10)0.069 (17)0.009 (16)
C110.125 (15)0.105 (15)0.17 (2)0.030 (12)0.082 (15)0.020 (14)
C120.092 (10)0.086 (10)0.104 (12)0.049 (8)0.047 (9)0.009 (9)
C130.034 (5)0.025 (5)0.057 (7)0.001 (4)0.004 (5)0.004 (5)
C140.037 (6)0.053 (7)0.085 (9)0.009 (5)0.007 (6)0.016 (6)
C150.065 (9)0.079 (11)0.099 (13)0.010 (7)0.021 (8)0.024 (9)
C160.083 (11)0.047 (9)0.18 (2)0.017 (8)0.012 (13)0.048 (11)
C170.098 (11)0.046 (8)0.098 (12)0.001 (8)0.020 (9)0.014 (8)
C180.063 (7)0.049 (7)0.080 (10)0.007 (6)0.026 (7)0.004 (7)
C190.035 (5)0.034 (5)0.054 (6)0.003 (4)0.013 (4)0.002 (5)
C200.054 (7)0.057 (7)0.071 (8)0.011 (5)0.033 (6)0.019 (6)
C210.066 (8)0.064 (8)0.107 (12)0.013 (6)0.043 (8)0.029 (8)
C220.101 (10)0.037 (7)0.120 (13)0.001 (7)0.065 (9)0.018 (8)
C230.037 (6)0.068 (8)0.108 (11)0.016 (5)0.035 (6)0.006 (8)
C240.036 (5)0.056 (7)0.076 (8)0.008 (5)0.023 (5)0.011 (6)
C250.019 (4)0.030 (5)0.045 (6)0.000 (3)0.002 (4)0.004 (4)
C260.034 (5)0.055 (7)0.052 (7)0.005 (5)0.004 (5)0.006 (5)
C270.053 (7)0.085 (9)0.053 (8)0.005 (6)0.003 (6)0.005 (7)
C280.061 (8)0.056 (8)0.091 (12)0.001 (6)0.014 (7)0.010 (8)
C290.041 (6)0.044 (7)0.110 (12)0.002 (5)0.014 (7)0.010 (7)
C300.043 (6)0.049 (6)0.063 (8)0.004 (5)0.009 (5)0.002 (6)
C310.033 (5)0.035 (5)0.046 (6)0.003 (4)0.018 (4)0.005 (5)
C320.061 (7)0.058 (7)0.055 (8)0.008 (6)0.014 (6)0.005 (6)
C330.095 (10)0.082 (10)0.043 (8)0.006 (8)0.003 (7)0.015 (7)
C340.073 (9)0.082 (10)0.066 (10)0.004 (7)0.002 (7)0.032 (8)
C350.041 (6)0.043 (6)0.083 (10)0.008 (5)0.014 (6)0.027 (6)
C360.045 (6)0.053 (7)0.052 (7)0.015 (5)0.016 (5)0.004 (5)
C370.026 (4)0.031 (5)0.039 (5)0.003 (4)0.006 (4)0.004 (4)
C380.057 (6)0.042 (7)0.054 (7)0.001 (5)0.022 (5)0.001 (5)
C390.055 (7)0.050 (7)0.066 (8)0.003 (5)0.018 (6)0.015 (6)
C400.056 (7)0.083 (9)0.048 (7)0.001 (6)0.006 (6)0.002 (7)
C410.065 (8)0.070 (9)0.054 (8)0.009 (6)0.001 (6)0.024 (7)
C420.042 (6)0.041 (6)0.054 (7)0.006 (4)0.002 (5)0.009 (5)
C430.030 (5)0.033 (5)0.061 (7)0.003 (4)0.028 (5)0.006 (5)
C440.051 (6)0.047 (6)0.047 (7)0.011 (5)0.007 (5)0.011 (5)
C450.099 (10)0.057 (8)0.060 (8)0.032 (7)0.026 (7)0.022 (6)
C460.114 (12)0.032 (7)0.094 (12)0.011 (7)0.038 (9)0.003 (7)
C470.084 (9)0.047 (8)0.094 (11)0.015 (6)0.032 (8)0.011 (7)
C480.040 (6)0.039 (6)0.071 (8)0.005 (4)0.013 (5)0.004 (5)
C490.031 (5)0.031 (5)0.047 (6)0.005 (4)0.018 (4)0.008 (4)
C500.034 (5)0.047 (6)0.062 (7)0.011 (4)0.022 (5)0.011 (5)
C510.055 (7)0.068 (8)0.069 (8)0.014 (6)0.040 (6)0.003 (6)
C520.043 (7)0.067 (8)0.093 (10)0.005 (5)0.035 (7)0.022 (7)
C530.035 (6)0.064 (7)0.098 (11)0.012 (5)0.011 (6)0.012 (8)
C540.030 (5)0.049 (6)0.052 (6)0.001 (4)0.011 (4)0.002 (5)
Cl20.075 (2)0.0475 (18)0.095 (3)0.0003 (15)0.0363 (19)0.0004 (17)
O10.107 (17)0.092 (16)0.14 (3)0.009 (13)0.023 (16)0.049 (17)
O20.23 (4)0.23 (4)0.24 (4)0.00 (3)0.12 (3)0.02 (3)
O30.26 (3)0.21 (3)0.14 (3)0.12 (3)0.02 (2)0.00 (2)
O40.071 (16)0.094 (19)0.27 (4)0.030 (14)0.025 (17)0.03 (2)
O1'0.12 (2)0.14 (2)0.14 (2)0.020 (17)0.048 (17)0.082 (19)
O2'0.104 (18)0.13 (2)0.21 (4)0.051 (16)0.029 (19)0.04 (2)
O3'0.34 (4)0.13 (3)0.11 (2)0.02 (3)0.10 (3)0.04 (2)
O4'0.14 (3)0.14 (3)0.29 (4)0.03 (2)0.16 (3)0.00 (3)
C550.140 (14)0.142 (14)0.133 (14)0.009 (9)0.052 (10)0.004 (9)
Cl30.243 (9)0.213 (9)0.183 (9)0.001 (7)0.025 (7)0.020 (7)
Cl40.273 (10)0.242 (10)0.216 (10)0.009 (7)0.148 (8)0.006 (7)
C560.078 (13)0.102 (14)0.093 (14)0.030 (9)0.039 (9)0.007 (9)
Cl50.132 (8)0.180 (9)0.160 (9)0.051 (7)0.081 (7)0.019 (7)
Cl60.198 (11)0.235 (11)0.169 (11)0.027 (9)0.057 (8)0.001 (9)
Geometric parameters (Å, º) top
Pt1—P32.266 (2)C28—H280.9300
Pt1—P12.359 (2)C29—C301.404 (15)
Pt1—Cl12.360 (2)C29—H290.9300
Pt1—P22.368 (2)C30—H300.9300
P1—C11.796 (11)C31—C321.378 (14)
P1—C71.822 (10)C31—C361.382 (13)
P1—C131.831 (9)C32—C331.397 (16)
P2—C191.806 (10)C32—H320.9300
P2—C251.818 (9)C33—C341.388 (19)
P2—C311.829 (10)C33—H330.9300
P3—C371.815 (9)C34—C351.378 (18)
P3—C431.823 (9)C34—H340.9300
P3—C491.826 (9)C35—C361.401 (14)
C1—C61.375 (14)C35—H350.9300
C1—C21.380 (14)C36—H360.9300
C2—C31.424 (16)C37—C381.355 (13)
C2—H20.9300C37—C421.395 (12)
C3—C41.348 (19)C38—C391.397 (15)
C3—H30.9300C38—H380.9300
C4—C51.35 (2)C39—C401.354 (16)
C4—H40.9300C39—H390.9300
C5—C61.379 (19)C40—C411.402 (17)
C5—H50.9300C40—H400.9300
C6—H60.9300C41—C421.351 (15)
C7—C81.364 (15)C41—H410.9300
C7—C121.412 (17)C42—H420.9300
C8—C91.421 (19)C43—C441.397 (13)
C8—H80.9300C43—C481.420 (12)
C9—C101.36 (3)C44—C451.411 (15)
C9—H90.9300C44—H440.9300
C10—C111.35 (3)C45—C461.375 (19)
C10—H100.9300C45—H450.9300
C11—C121.376 (19)C46—C471.368 (19)
C11—H110.9300C46—H460.9300
C12—H120.9300C47—C481.376 (15)
C13—C141.351 (14)C47—H470.9300
C13—C181.378 (15)C48—H480.9300
C14—C151.383 (16)C49—C541.367 (13)
C14—H140.9300C49—C501.402 (14)
C15—C161.34 (2)C50—C511.366 (13)
C15—H150.9300C50—H500.9300
C16—C171.40 (2)C51—C521.376 (17)
C16—H160.9300C51—H510.9300
C17—C181.394 (16)C52—C531.353 (17)
C17—H170.9300C52—H520.9300
C18—H180.9300C53—C541.402 (14)
C19—C241.395 (12)C53—H530.9300
C19—C201.414 (14)C54—H540.9300
C20—C211.352 (15)Cl2—O2'1.415 (9)
C20—H200.9300Cl2—O11.420 (9)
C21—C221.403 (16)Cl2—O1'1.422 (9)
C21—H210.9300Cl2—O4'1.428 (10)
C22—C231.394 (18)Cl2—O31.430 (10)
C22—H220.9300Cl2—O21.431 (10)
C23—C241.399 (15)Cl2—O41.437 (9)
C23—H230.9300Cl2—O3'1.438 (10)
C24—H240.9300C55—Cl31.707 (10)
C25—C261.373 (14)C55—Cl41.719 (10)
C25—C301.381 (13)C55—H55A0.9700
C26—C271.391 (15)C55—H55B0.9700
C26—H260.9300C56—Cl51.701 (10)
C27—C281.369 (18)C56—Cl61.721 (10)
C27—H270.9300C56—H56A0.9700
C28—C291.389 (18)C56—H56B0.9700
P3—Pt1—P198.91 (8)C29—C30—H30119.0
P3—Pt1—Cl1169.58 (10)C32—C31—C36118.2 (10)
P1—Pt1—Cl183.77 (9)C32—C31—P2122.6 (8)
P3—Pt1—P295.87 (8)C36—C31—P2119.2 (8)
P1—Pt1—P2162.27 (8)C31—C32—C33121.6 (12)
Cl1—Pt1—P283.43 (9)C31—C32—H32119.2
C1—P1—C7108.6 (5)C33—C32—H32119.2
C1—P1—C13105.5 (5)C34—C33—C32118.6 (13)
C7—P1—C13100.2 (4)C34—C33—H33120.7
C1—P1—Pt1111.8 (3)C32—C33—H33120.7
C7—P1—Pt1108.3 (3)C35—C34—C33121.3 (12)
C13—P1—Pt1121.3 (3)C35—C34—H34119.4
C19—P2—C25108.2 (4)C33—C34—H34119.4
C19—P2—C31104.0 (5)C34—C35—C36118.3 (11)
C25—P2—C31100.9 (4)C34—C35—H35120.8
C19—P2—Pt1102.7 (3)C36—C35—H35120.8
C25—P2—Pt1117.1 (3)C31—C36—C35122.0 (11)
C31—P2—Pt1122.7 (3)C31—C36—H36119.0
C37—P3—C43109.7 (4)C35—C36—H36119.0
C37—P3—C49102.8 (4)C38—C37—C42118.3 (9)
C43—P3—C4999.5 (4)C38—C37—P3116.5 (7)
C37—P3—Pt1114.1 (3)C42—C37—P3125.1 (8)
C43—P3—Pt1110.3 (3)C37—C38—C39121.0 (10)
C49—P3—Pt1119.1 (3)C37—C38—H38119.5
C6—C1—C2118.4 (11)C39—C38—H38119.5
C6—C1—P1123.0 (9)C40—C39—C38120.3 (11)
C2—C1—P1118.6 (8)C40—C39—H39119.9
C1—C2—C3118.3 (11)C38—C39—H39119.9
C1—C2—H2120.9C39—C40—C41119.0 (11)
C3—C2—H2120.9C39—C40—H40120.5
C4—C3—C2122.9 (14)C41—C40—H40120.5
C4—C3—H3118.5C42—C41—C40120.1 (11)
C2—C3—H3118.5C42—C41—H41120.0
C5—C4—C3116.9 (15)C40—C41—H41120.0
C5—C4—H4121.6C41—C42—C37121.3 (10)
C3—C4—H4121.6C41—C42—H42119.4
C4—C5—C6123.0 (14)C37—C42—H42119.4
C4—C5—H5118.5C44—C43—C48117.9 (9)
C6—C5—H5118.5C44—C43—P3121.5 (7)
C1—C6—C5120.5 (13)C48—C43—P3120.3 (7)
C1—C6—H6119.8C43—C44—C45120.3 (11)
C5—C6—H6119.8C43—C44—H44119.8
C8—C7—C12119.5 (11)C45—C44—H44119.8
C8—C7—P1122.6 (9)C46—C45—C44119.4 (12)
C12—C7—P1117.8 (9)C46—C45—H45120.3
C7—C8—C9119.7 (14)C44—C45—H45120.3
C7—C8—H8120.2C47—C46—C45121.0 (11)
C9—C8—H8120.2C47—C46—H46119.5
C10—C9—C8117.7 (17)C45—C46—H46119.5
C10—C9—H9121.2C46—C47—C48120.7 (12)
C8—C9—H9121.2C46—C47—H47119.7
C11—C10—C9124.4 (18)C48—C47—H47119.7
C11—C10—H10117.8C47—C48—C43120.4 (11)
C9—C10—H10117.8C47—C48—H48119.8
C10—C11—C12118 (2)C43—C48—H48119.8
C10—C11—H11120.9C54—C49—C50118.3 (9)
C12—C11—H11120.9C54—C49—P3123.8 (8)
C11—C12—C7120.5 (16)C50—C49—P3117.5 (7)
C11—C12—H12119.8C51—C50—C49121.1 (10)
C7—C12—H12119.8C51—C50—H50119.5
C14—C13—C18118.1 (10)C49—C50—H50119.5
C14—C13—P1123.5 (9)C50—C51—C52119.8 (12)
C18—C13—P1118.3 (8)C50—C51—H51120.1
C13—C14—C15124.6 (13)C52—C51—H51120.1
C13—C14—H14117.7C53—C52—C51120.2 (10)
C15—C14—H14117.7C53—C52—H52119.9
C16—C15—C14116.3 (15)C51—C52—H52119.9
C16—C15—H15121.9C52—C53—C54120.5 (11)
C14—C15—H15121.9C52—C53—H53119.8
C15—C16—C17122.6 (15)C54—C53—H53119.8
C15—C16—H16118.7C49—C54—C53120.1 (11)
C17—C16—H16118.7C49—C54—H54120.0
C18—C17—C16118.5 (16)C53—C54—H54120.0
C18—C17—H17120.8O2'—Cl2—O1145.7 (14)
C16—C17—H17120.8O2'—Cl2—O1'111.6 (10)
C13—C18—C17119.9 (12)O1—Cl2—O1'76.6 (13)
C13—C18—H18120.1O2'—Cl2—O4'110.2 (10)
C17—C18—H18120.1O1—Cl2—O4'96.6 (17)
C24—C19—C20117.5 (9)O1'—Cl2—O4'110.4 (10)
C24—C19—P2123.8 (8)O2'—Cl2—O349.3 (12)
C20—C19—P2118.6 (7)O1—Cl2—O3110.5 (9)
C21—C20—C19121.0 (11)O1'—Cl2—O3155.4 (15)
C21—C20—H20119.5O4'—Cl2—O392.5 (18)
C19—C20—H20119.5O2'—Cl2—O264.0 (13)
C20—C21—C22121.5 (12)O1—Cl2—O2111.0 (10)
C20—C21—H21119.2O1'—Cl2—O248.3 (13)
C22—C21—H21119.2O4'—Cl2—O2135.1 (18)
C23—C22—C21118.8 (11)O3—Cl2—O2108.9 (10)
C23—C22—H22120.6O2'—Cl2—O4104.3 (16)
C21—C22—H22120.6O1—Cl2—O4109.1 (9)
C22—C23—C24119.5 (10)O1'—Cl2—O489.6 (17)
C22—C23—H23120.3O4'—Cl2—O426.9 (19)
C24—C23—H23120.3O3—Cl2—O4109.0 (10)
C19—C24—C23121.6 (10)O2—Cl2—O4108.4 (10)
C19—C24—H24119.2O2'—Cl2—O3'108.0 (10)
C23—C24—H24119.2O1—Cl2—O3'41.0 (13)
C26—C25—C30117.9 (9)O1'—Cl2—O3'108.5 (10)
C26—C25—P2123.3 (7)O4'—Cl2—O3'108.2 (10)
C30—C25—P2118.8 (8)O3—Cl2—O3'70.8 (14)
C25—C26—C27122.5 (11)O2—Cl2—O3'116.0 (18)
C25—C26—H26118.8O4—Cl2—O3'133.1 (18)
C27—C26—H26118.8Cl3—C55—Cl4110.5 (8)
C28—C27—C26118.0 (12)Cl3—C55—H55A109.6
C28—C27—H27121.0Cl4—C55—H55A109.6
C26—C27—H27121.0Cl3—C55—H55B109.6
C27—C28—C29122.4 (12)Cl4—C55—H55B109.6
C27—C28—H28118.8H55A—C55—H55B108.1
C29—C28—H28118.8Cl5—C56—Cl6110.9 (9)
C28—C29—C30117.2 (12)Cl5—C56—H56A109.5
C28—C29—H29121.4Cl6—C56—H56A109.5
C30—C29—H29121.4Cl5—C56—H56B109.5
C25—C30—C29122.0 (11)Cl6—C56—H56B109.5
C25—C30—H30119.0H56A—C56—H56B108.0
P3—Pt1—P1—C191.9 (3)C19—C20—C21—C221 (2)
Cl1—Pt1—P1—C177.9 (3)C20—C21—C22—C232 (2)
P2—Pt1—P1—C1121.9 (4)C21—C22—C23—C241 (2)
P3—Pt1—P1—C7148.4 (4)C20—C19—C24—C232.0 (17)
Cl1—Pt1—P1—C741.8 (4)P2—C19—C24—C23179.1 (10)
P2—Pt1—P1—C72.3 (5)C22—C23—C24—C191 (2)
P3—Pt1—P1—C1333.5 (4)C19—P2—C25—C26114.6 (8)
Cl1—Pt1—P1—C13156.6 (4)C31—P2—C25—C26136.6 (8)
P2—Pt1—P1—C13112.6 (5)Pt1—P2—C25—C260.8 (9)
P3—Pt1—P2—C19128.4 (3)C19—P2—C25—C3063.1 (8)
P1—Pt1—P2—C1918.0 (5)C31—P2—C25—C3045.8 (8)
Cl1—Pt1—P2—C1962.0 (3)Pt1—P2—C25—C30178.5 (6)
P3—Pt1—P2—C25113.2 (3)C30—C25—C26—C272.5 (15)
P1—Pt1—P2—C25100.4 (4)P2—C25—C26—C27179.8 (8)
Cl1—Pt1—P2—C2556.4 (3)C25—C26—C27—C283.7 (17)
P3—Pt1—P2—C3112.3 (4)C26—C27—C28—C292.5 (19)
P1—Pt1—P2—C31134.1 (4)C27—C28—C29—C300.3 (18)
Cl1—Pt1—P2—C31178.2 (4)C26—C25—C30—C290.1 (15)
P1—Pt1—P3—C37111.1 (3)P2—C25—C30—C29177.9 (8)
Cl1—Pt1—P3—C37144.7 (5)C28—C29—C30—C251.0 (16)
P2—Pt1—P3—C3759.1 (3)C19—P2—C31—C3217.0 (9)
P1—Pt1—P3—C43124.8 (3)C25—P2—C31—C32129.1 (8)
Cl1—Pt1—P3—C4320.7 (6)Pt1—P2—C31—C3298.5 (8)
P2—Pt1—P3—C4365.0 (3)C19—P2—C31—C36160.8 (7)
P1—Pt1—P3—C4910.8 (4)C25—P2—C31—C3648.7 (8)
Cl1—Pt1—P3—C4993.4 (6)Pt1—P2—C31—C3683.7 (8)
P2—Pt1—P3—C49179.1 (4)C36—C31—C32—C330.5 (15)
C7—P1—C1—C658.2 (10)P2—C31—C32—C33177.3 (9)
C13—P1—C1—C648.5 (10)C31—C32—C33—C340.4 (18)
Pt1—P1—C1—C6177.7 (8)C32—C33—C34—C350 (2)
C7—P1—C1—C2122.1 (8)C33—C34—C35—C360.3 (18)
C13—P1—C1—C2131.2 (8)C32—C31—C36—C350.5 (14)
Pt1—P1—C1—C22.6 (9)P2—C31—C36—C35177.4 (7)
C6—C1—C2—C31.6 (15)C34—C35—C36—C310.4 (15)
P1—C1—C2—C3178.1 (8)C43—P3—C37—C38173.7 (7)
C1—C2—C3—C40.6 (19)C49—P3—C37—C3881.1 (8)
C2—C3—C4—C51 (2)Pt1—P3—C37—C3849.3 (8)
C3—C4—C5—C62 (2)C43—P3—C37—C4210.6 (9)
C2—C1—C6—C52.8 (17)C49—P3—C37—C4294.6 (8)
P1—C1—C6—C5176.8 (10)Pt1—P3—C37—C42135.0 (7)
C4—C5—C6—C13 (2)C42—C37—C38—C392.1 (14)
C1—P1—C7—C810.8 (10)P3—C37—C38—C39174.0 (8)
C13—P1—C7—C899.5 (9)C37—C38—C39—C400.5 (17)
Pt1—P1—C7—C8132.4 (8)C38—C39—C40—C411.6 (17)
C1—P1—C7—C12173.7 (9)C39—C40—C41—C420.2 (18)
C13—P1—C7—C1276.0 (10)C40—C41—C42—C372.5 (17)
Pt1—P1—C7—C1252.0 (10)C38—C37—C42—C413.5 (14)
C12—C7—C8—C90.8 (17)P3—C37—C42—C41172.1 (8)
P1—C7—C8—C9176.2 (10)C37—P3—C43—C44133.3 (8)
C7—C8—C9—C103 (2)C49—P3—C43—C44119.3 (8)
C8—C9—C10—C112 (3)Pt1—P3—C43—C446.7 (9)
C9—C10—C11—C121 (3)C37—P3—C43—C4854.3 (9)
C10—C11—C12—C73 (3)C49—P3—C43—C4853.1 (9)
C8—C7—C12—C112 (2)Pt1—P3—C43—C48179.1 (7)
P1—C7—C12—C11173.3 (13)C48—C43—C44—C456.6 (15)
C1—P1—C13—C148.2 (10)P3—C43—C44—C45179.2 (9)
C7—P1—C13—C14121.0 (9)C43—C44—C45—C461.9 (18)
Pt1—P1—C13—C14120.1 (8)C44—C45—C46—C472 (2)
C1—P1—C13—C18168.0 (8)C45—C46—C47—C481 (2)
C7—P1—C13—C1855.3 (9)C46—C47—C48—C434 (2)
Pt1—P1—C13—C1863.7 (9)C44—C43—C48—C477.5 (16)
C18—C13—C14—C152.6 (17)P3—C43—C48—C47179.8 (10)
P1—C13—C14—C15173.6 (9)C37—P3—C49—C548.2 (9)
C13—C14—C15—C160 (2)C43—P3—C49—C54121.1 (8)
C14—C15—C16—C173 (2)Pt1—P3—C49—C54119.1 (7)
C15—C16—C17—C183 (2)C37—P3—C49—C50164.2 (7)
C14—C13—C18—C173.0 (16)C43—P3—C49—C5051.3 (8)
P1—C13—C18—C17173.5 (9)Pt1—P3—C49—C5068.5 (8)
C16—C17—C18—C130.6 (18)C54—C49—C50—C513.3 (14)
C25—P2—C19—C245.1 (10)P3—C49—C50—C51176.1 (8)
C31—P2—C19—C24101.5 (10)C49—C50—C51—C522.0 (16)
Pt1—P2—C19—C24129.6 (9)C50—C51—C52—C530.2 (18)
C25—P2—C19—C20176.0 (8)C51—C52—C53—C540.4 (18)
C31—P2—C19—C2077.3 (9)C50—C49—C54—C532.7 (14)
Pt1—P2—C19—C2051.5 (9)P3—C49—C54—C53175.1 (8)
C24—C19—C20—C211.0 (18)C52—C53—C54—C490.9 (17)
P2—C19—C20—C21179.9 (11)
 

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