Acta Cryst. (2006). E62, m563-m565  [ doi:10.1107/S1600536806005976 ]

Di--acetato-bis[-2-hydroxy-N,N'-bis(2-oxidobenzyl)propane-1,3-diamine]bis(N,N'-dimethylformamide)trinickel(II) N,N'-dimethylformamide disolvate

M. Sari, O. Atakol, I. Svoboda and H. Fuess

Abstract: The title compound, [Ni₃(C₁₇H₂₀N₂O₂)₂(C₂H₃O₂)₂(C₃H₇NO)₂]·2C₃H₇NO, is a centrosymmetric trinuclear nickel(II) complex. The central and terminal nickel(II) atoms have distorted octahedral coordination, the central Ni^II atom by six O atoms, and the terminal Ni^II atoms by four O atoms and two N atoms each. The average Ni-O and Ni-N distances for the terminal Ni ions are 2.062 (17) and 2.082 (2) Å, respectively. The NiNi distance is 3.035 (2) Å.

Online 22 February 2006

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