Acta Cryst. (2006). E62, m432-m433  [ doi:10.1107/S1600536806003576 ]

Pentacarbonyl[N,N-dimethyl-N'-(5-{2-[5-(4-pyridylethynyl)thiophen-2-yl]vinyl}thiophen-2-ylmethylene)benzene-1,4-diamine]tungsten(0)

P.-H. Huang, T.-H. Huang, J.-Y. Shen and Y.-S. Wen

Abstract: In the title compound, [W(C₂₆H₂₁N₃S₂)(CO)₅], the geometry at the W atom is approximately octahedral, with the cis bond angles in the range 86.45 (13)-94.99 (12)°. The bond to the trans carbonyl is quite short [W-C = 1.953 (4) Å] and the equatorial W-CO bonds lie in the range 2.010 (4)-2.059 (4) Å.

Online 3 February 2006

Copyright © International Union of Crystallography
IUCr Webmaster