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Acta Cryst. (2006). E62, m650-m652 [ doi:10.1107/S1600536806006453 ]
Abstract: A new type of ![[alpha]](/logos/entities/alpha_rmgif.gif)
-diketone palladium(II) complex containing a tertiary phosphine, namely the title compound, [Pd(C7H5O2)2(C18H33P)], crystallizes with a square-planar geometry about the palladium(II) metal centre. One tropolonate ligand is bonded in a bidentate chelating mode, while the second one is bonded through a single O atom to the palladium(II) metal centre. The Pd-O distances range from 1.9907 (13) to 2.0702 (12) Å, and the O-Pd-O bite angle for the bidentate tropolonate ligand is 80.30 (5)°.
Online 28 February 2006
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