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Acta Cryst. (2006). E62, m437-m439  [ doi:10.1107/S1600536806003229 ]

Di-[mu]-iodo-1:2[kappa]4I:I-diiodo-2[kappa]2I-tris(1,10-phenanthroline)-1[kappa]2N,N';2[kappa]2N,N'-bismuth(III)sodium(I)

F. Li, H. Yin and D. Wang

Abstract: The title compound, [BiNaI4(C12H8N2)3], contains a bimetallic neutral cluster, with the metal atoms bridged by two iodide ions. The NaN4I2 coordination is irregular and the BiN2I4 coordination is distorted octahedral. A number of [pi]-[pi] stacking interactions involving the phenanthroline rings help to establish the crystal packing.

Online 3 February 2006


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