Acta Cryst. (2006). E62, m454-m456  [ doi:10.1107/S1600536806003928 ]

Tetraethylammonium dichlorotris(2,6-dimethylphenylsulfanyl-S)ruthenium dichloromethane solvate

Y.-W. Song, Z. Yu and Q.-F. Zhang

Abstract: The title mononuclear ruthenium(IV) complex, (C₈H₂₀N)[Ru(C₈H₉S)₃Cl₂]·CH₂Cl₂, contains the trigonal {Ru(Sxylyl)₃} core (xylyl is 2,6-dimethylphenyl), with S-Ru-S angles in the range 118.07 (6)-123.45 (6)°. The coordination geometry of the central Ru atom is trigonal-bipyramidal, with two Cl atoms in the axial positions. The Ru-S and Ru-Cl bond lengths are 2.1918 (18)-2.2046 (19) and 2.378 (2)-2.385 (2) Å, respectively.

Online 8 February 2006

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