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Acta Cryst. (2006). E62, m513-m515  [ doi:10.1107/S160053680600420X ]

Aqua(dipicolinato-[kappa]3O,N,O')(1,10-phenanthroline-[kappa]2N,N')zinc(II) monohydrate

W. T. A. Harrison, P. Ramadevi and S. Kumaresan

Abstract: The title compound, [Zn(C7H3NO4)(C12H8N2)(H2O)]·H2O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO3N3 octahedral grouping. The crystal packing is consolidated by O-H...O hydrogen bonds and probable [pi]-[pi] stacking.

Online 15 February 2006


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