Acta Cryst. (2006). E62, m553-m554  [ doi:10.1107/S1600536806005149 ]

Di--chloro--(dimethyl sulfide)-bis[dichloro(dimethyl sulfide)niobium(III)]

M. Kakeya, T. Fujihara and A. Nagasawa

Abstract: The title compound, [Nb₂Cl₆(C₂H₆S)₃], contains an Nb^III=Nb^III double bond [2.6880 (3) Å]. Each Nb atom has a distorted octahedral coordination environment formed by two terminal and two bridging Cl^- ions, and one monodentate and one bridging Me₂S ligands.

Online 22 February 2006

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