Acta Cryst. (2006). E62, m685-m686  [ doi:10.1107/S160053680600626X ]

Aqua(2-chloronicotinato)triphenyltin(IV)

H.-L. Xu, H.-D. Yin and G. Li

Abstract: The title complex, [Sn(C₆H₅)₃(C₆H₃ClNO₂)(H₂O)], is five-coordinate with a distorted trigonal-bipyramidal geometry in the solid state. The O atom of the carboxylate group occupies one of the axial sites and the O atom of the water molecule occupies the other. Water H atoms are involved in an intermolecular hydrogen-bonded network with the uncoordinated carboxylate O atom and the pyridine N atom; the interactions lead to two types of rings.

Online 8 March 2006

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