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Acta Cryst. (2006). E62, m770-m772  [ doi:10.1107/S1600536806007896 ]

(1,4:8,11:15,18:22,25-Tetraethanotetrabenzo[b,g,l,q]porphyrinato)nickel(II) chloroform disolvate

H.-Y. Xu, X. Qin, Y.-Z. Li, N. Ono and Z. Shen

Abstract: In the title compound, [Ni(C44H36N4)]·2CHCl3, the porphyrin macrocycle adopts a ruffle conformation. The NiII atom is coordinated by four N atoms of the porphyrin in a slightly distorted square-planar geometry. The bicyclic groups show disorder of the single and double bonds. The porphyrin planes form two columnar arrays along the b-axis direction through [pi]-[pi] stacking interactions.

Online 15 March 2006


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