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Acta Cryst. (2006). E62, m674-m676 [ doi:10.1107/S1600536806006738 ]
-sulfido-tetrasulfidodecaantimonyAbstract: In the structure of the title compound, (C3H12N2)[Sb10S16], the SbS3 pyramids are interconnected to form a one-dimensional [Sb6S10]2- chain anion which contains 24-membered Sb12S12 rings that are interconnected. The structure-directing cations are located above and below this ring. Accepting Sb-S distances up to 3.2 Å, a three-dimensional thioantimonate(III) network results.
Online 3 March 2006
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