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Acta Cryst. (2006). E62, m682-m684  [ doi:10.1107/S1600536806006076 ]

trans-Bis(benzyldiphenylphosphine)carbonylchlororhodium(I)

R. Meijboom, A. Muller and A. Roodt

Abstract: In the title compound, trans-[RhCl(C19H17P)2(CO)], selected geometrical parameters are: Rh-P = 2.3204 (5) and 2.3365 (5) Å, Rh-Cl = 2.3687 (5) Å and Rh-C = 1.8007 (15) Å, and P-Rh-P = 179.005 (16)°, P-Rh-Cl = 88.807 (15)° and 90.529 (15)°, and Rh-C[triple bond]O = 176.43 (13)°. The effective cone angles for the phosphine ligands were calculated to be 156 and 160°.

Online 8 March 2006


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