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Acta Cryst. (2006). E62, m897-m899 [ doi:10.1107/S1600536806010580 ]
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2-chloro-bis[(benzyldiphenylphosphine)chloropalladium(II)]Abstract: The molecule of the title compound, [Pd2Cl4(C19H17P)2] or [Pd(2-Cl)Cl(PPh2Bz)]2, where Bz = CH2Ph, lies on an inversion centre. The Pd atom has a distorted square-planar coordination environment formed by a benzyldiphenylphosphine [Pd-P = 2.2218 (6) Å], a terminal chloride [Pd-Cl = 2.2729 (5) Å] and two bridging chloride ligands. The Pd-Cl bond in the position trans to the phosphine ligand [Pd-Cl = 2.4123 (5) Å] is considerably longer than the Pd-Cl bond in the position trans to the terminal chloride [Pd-Cl = 2.3155 (5) Å].
Online 31 March 2006
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