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Acta Cryst. (2006). E62, m875-m877  [ doi:10.1107/S1600536806010749 ]

Di-[mu]-2-sulfonatobenzoato-bis[aqua(1,10-phenanthroline)copper(II)] trihydrate

W.-B. Zhang, S.-D. Ruan, S.-J. Zhu, H.-P. Xiao and S.-Y. Ye

Abstract: In the title compound, [Cu2(C7H4O5S)2(C12H8N2)2(H2O)2]·3H2O, each copper(II) atom is coordinated by two N atoms from one 1,10-phenanthroline molecule, two carboxylate O atoms from two 2-sulfonatobenzoato dianions and one aqua O atom in a distorted square pyramidal geometry. The 2-sulfonatobenzoato dianions function as [mu]2-bridging ligands in the formation of a dinuclear complex. Intermolecular hydrogen-bond interactions link the dinuclear units into a two-dimensional network structure.

Online 29 March 2006


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